MATERIAL SAFETY DATA SHEET
EM SCIENCE
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufacturer.............: Preparation Date.: 8/14/95
EM SCIENCE
A Division of EM Industries Information Phone Number.: 856??423??6300
P.O. Box 70 Hours: Mon. to Fri. 8:30??5
480 Democrat Road Chemtrec Emergency Number: 800??424??9300
Gibbstown, N.J. 08027 Hours: 24 hrs a day
Catalog Number(s):
14661
Product Name:
Aquamerck (TM) Phosphorus Kit
Synonyms:
Reagent 1
Chemical Family:
Mixture
Formula:
Mixture
Molecular Weight.:
N/A
2. COMPOSITION / INFORMATION ON INGREDIENTS
Component CAS # Appr %
____________________________________________________________
Ammonium Molybdate
12054??85??2 0??10%
Sulfuric Acid
7664??93??9 0??20%
Water
7732??18??5 0??50%
1
Antimony Potassium Tartrate
6535??15??5 25??75%
Approx. % as wt/vol
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CAUSES BURNS.
HARMFUL IF INHALED OR SWALLOWED.
STRONG INORGANIC ACID MISTS CONTAINING SULFURIC ACI CAN CAUSE CANCER.
MAY CAUSE LIVER DAMAGE.
Appearance:
Liquid
POTENTIAL HEALTH EFFECTS (ACUTE AND CHRONIC)
Symptoms of Exposure:
Causes burns on contact. Harmful if inhaled or swallowed. May cause liver damage.
Medical Cond. Aggravated by Exposure:
Data not available
Routes of Entry:
Inhalation, ingestion or skin contact
Carcinogenicity:
Contains Sulfuric Acid.
STRONG INORGANIC ACID MISTS CONTAINING SULFURIC ACI CAN CAUSE CANCER.
4. FIRST AID MEASURES
Emergency First Aid:
GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE.
Skin: Immediately flush thoroughly with large amounts of water.
Eyes: Immediately flush thoroughly with water for at least 15
minutes.
Inhalation: Remove to fresh air; give artificial respiration if
breathing has stopped.
Ingestion: Do not induce vomiting; if conscious, give water
freely and get medical attention.
Remove contaminated clothing and wash before reuse.
2
5. FIRE FIGHTING MEASURES
Flash Point (F): Noncombustible
Flammable Limits LEL (%): N/A
Flammable Limits UEL (%): N/A
Extinguishing Media:
Use any suitable for adjacent material.
Fire Fighting Procedures:
Wear self?contained breathing apparatus and protective clothing.
Fire &Explosion Hazards:
Thermal decomposition produces toxic fumes.
6. ACCIDENTAL RELEASE MEASURES
Spill Response:
Evacuate the area of all unnecessary personnel. Wear suitable protective equipment listed under Exposure /
Personal Protection. Eliminate any ignition sources until the area is determined to be free from explosion or
fire hazards. Contain the release and eliminate its source, if this can be done without risk. Take up and
containerize for proper disposal as described under Disposal. Comply with Federal, State, and local
regulations on reporting releases. Refer to Regulatory Information for reportable quantity and other regulatory
data.
EM SCIENCE recommends SPILL?X neutralizers and absorbent agents for various types of spills. Additional
information on the SPILL?X products can be provided through the EM SCIENCE Technical Service
Department (856) 423??6300. The following EM SCIENCE SPILL?X neutralizer and absorbent is
recommended for this product:
SX0861 Spill?X?A Acid Spill Treatment Kit
7. HANDLING AND STORAGE
Handling &Storage:
Keep container closed. Do not breathe vapor. Do not get in eyes, on skin, or on clothing.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT:
Ventilation, Respiratory Protection, Protective Clothing, Eye Protection:
Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see
TLV/PEL), a NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental
control. OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type) under
3
specified conditions (see your safety equipment supplier). Engineering and/or administrative controls should
be implemented to reduce exposure. Material should be handled or transferred in an approved fume hood or
with adequate ventilation. Protective gloves must be worn to prevent skin contact (Neoprene or equivalent)
Safety glasses with side shields must be worn at all times. Impervious protective clothing should be worn to
prevent skin contact.
Work/Hygenic Practices:
Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily
available.
EXPOSURE GUIDELINES
OSHA ?? PEL:
TWA STEL CL
Component PPM MG/M3 PPM MG/M3 PPM MG/M3 Skin
____________________________________________________________
Ammonium Molybdate
Sulfuric Acid
1
Water
Antimony Potassium Tartrate
ACGIH ?? TLV:
TWA STEL CL
Component PPM MG/M3 PPM MG/M3 PPM MG/M3 Skin
____________________________________________________________
Ammonium Molybdate
Sulfuric Acid
1 3
Water
Antimony Potassium Tartrate
If there are no exposure limit numbers listed in the Exposure Guidelines chart, this indicates that no OSHA or
ACGIH exposure limts have been established.
9. PHYSICAL AND CHEMCIAL PROPERTIES
Boiling Point (C 760 mmHg) : N/A
Melting Point (C) : N/A
Specific Gravity (H20 = 1) : N/A
Vapor Pressure (mm Hg) : N/A
Percent Volatile by vol (%): N/A
Vapor Density (Air = 1) : N/A
Evaporation Rate (BuAc = 1): N/A
4
Solubility in Water (%) : Soluble
Appearance :
Liquid
10. STABILITY AND REACTIVITY
Stability: Yes
Hazardous Polymerization:
Does not occur
Hazardous Decomposition:
COx, SOx
Conditions to Avoid:
Extreme heat
Materials To Avoid:
() Water
() Acids
() Bases
() Corrosives
() Oxidizers
(X) Other: none indicated
11. TOXICOLOGICAL INFORMATION
Toxicity Data
None established
Toxicological Findings:
None
Cited in Registry of Toxic Effects of Chemical Substances (RTECS)
12. DISPOSAL CONSIDERATIONS
EPA Waste Numbers: D002
Treatment:
Specified Technology ?? Neutralize to pH 6??9. Contact your local permitted waste disposal site (TSD) for
permissible treatment sites.
ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH
5
ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS.
13. TRANSPORT INFORMATION
DOT Proper Shipping Name:
Corrosive Liquid, Acidic, Inorganic, N.O.S. (Contains
Sulfuric Acid) for the kit
DOT ID Number :
UN3264 (for the kit)
14. REGULATORY INFORMATION
TSCA Statement:
This product is a "Mixture". The CAS numbers of all components
are listed on the TSCA Inventory.
SARA SARA CERCLA
Component EHS EHS TPQ RQ
(302) (lbs) (lbs)
____________________________________________________________
Ammonium Molybdate
Sulfuric Acid
Y 1000 1000
Water
Antimony Potassium Tartrate
OSHA SARA
DeMinimis
Component Floor List 313
for SARA 313
(%)
____________________________________________________________
Ammonium Molybdate
Sulfuric Acid
Y Y 1.0
Water
Antimony Potassium Tartrate
If there is no information listed on the regulatory information chart, this indicates that the chemical is not
covered by the specific regulation listed.
15. OTHER INFORMATION
Comments:
6
None
NFPA Hazard Ratings:
Health :1
Flammability :0
Reactivity :0
Special Hazards :
Revision History: 8/14/95
| = Revised Section
N/A = Not Available
N/E = None Established
The statements contained herein are offered for informational purposes only and are based upon technical data
that EM Science believes to be accurate. It is intended for use only by persons having the necessary technical
skill and at their own discretion and risk. Since conditions and manner of use are outside our control, we make
NO WARRANTY, EXPRESS OR IMPLIED, OR MERCHANTABILITY, FITNESS OR OTHERWISE.
MATERIAL SAFETY DATA SHEET
EM SCIENCE
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufacturer.............: Preparation Date.: 8/14/95
EM SCIENCE
A Division of EM Industries Information Phone Number.: 856??423??6300
P.O. Box 70 Hours: Mon. to Fri. 8:30??5
480 Democrat Road Chemtrec Emergency Number: 800??424??9300
Gibbstown, N.J. 08027 Hours: 24 hrs a day
Catalog Number(s):
14661
7
Product Name:
Aquamerck (TM) Phosphorus Kit
Synonyms:
Reagent 2
Chemical Family:
Vitamin
Formula:
C6H8O6
Molecular Weight.:
176.13
2. COMPOSITION / INFORMATION ON INGREDIENTS
Component CAS # Appr %
____________________________________________________________
L(+) Ascorbic Acid
50??81??7 100%
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Handling care generally in keeping with safe laboratory practices is
recommended.
Appearance:
White granular, powder or crystals
POTENTIAL HEALTH EFFECTS (ACUTE AND CHRONIC)
Symptoms of Exposure:
Contact with skin or eyes may cause irritation. Dust inhalation may be irritating to respiratory tract. Repeated
ingestion of large doses may cause gastrointestinal, bladder and kidney disturbances.
Medical Cond. Aggravated by Exposure:
Data not available.
Routes of Entry:
Inhalation, ingestion or skin contact.
Carcinogenicity:
The material is not listed (IARC, NTP, OSHA) as cancer causing
agent.
8
4. FIRST AID MEASURES
Emergency First Aid:
GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE.
Skin: Immediately flush thoroughly with large amounts of water.
Eyes: Immediately flush thoroughly with water for at least 15
minutes.
Inhalation: Remove to fresh air; give artificial respiration if
breathing has stopped.
Ingestion: Get immediate medical attention; if conscious, give
water freely.
5. FIRE FIGHTING MEASURES
Flash Point (F): N/A
Flammable Limits LEL (%): N/A
Flammable Limits UEL (%): N/A
Extinguishing Media:
Water spray, foam, CO2
Fire Fighting Procedures:
Wear self?contained breathing apparatus.
Fire &Explosion Hazards:
Thermal decomposition produces acrid fumes.
6. ACCIDENTAL RELEASE MEASURES
Spill Response:
Evacuate the area of all unnecessary personnel. Wear suitable protective equipment listed under Exposure /
Personal Protection. Eliminate any ignition sources until the area is determined to be free from explosion or
fire hazards. Contain the release and eliminate its source, if this can be done without risk. Take up and
containerize for proper disposal as described under Disposal. Comply with Federal, State, and local
regulations on reporting releases. Refer to Regulatory Information for reportable quantity and other regulatory
data.
7. HANDLING AND STORAGE
Handling &Storage:
Keep container closed. Store at controlled room temperature. Do not breathe dust. Do not get in eyes. Avoid
skin contact.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
9
ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT:
Ventilation, Respiratory Protection, Protective Clothing, Eye Protection:
Material should be handled or transferred in an approved fume hood or with adequate ventilation. Protective
gloves (Natural rubber, Neoprene, PVC or equivalent) should be worn to prevent skin contact. Safety glasses
with side shields should be worn at all times.
Work/Hygenic Practices:
Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily
available.
EXPOSURE GUIDELINES
OSHA ?? PEL:
TWA STEL CL
Component PPM MG/M3 PPM MG/M3 PPM MG/M3 Skin
____________________________________________________________
L(+) Ascorbic Acid
ACGIH ?? TLV:
TWA STEL CL
Component PPM MG/M3 PPM MG/M3 PPM MG/M3 Skin
____________________________________________________________
L(+) Ascorbic Acid
If there are no exposure limit numbers listed in the Exposure Guidelines chart, this indicates that no OSHA or
ACGIH exposure limts have been established.
9. PHYSICAL AND CHEMCIAL PROPERTIES
Boiling Point (C 760 mmHg) : N/A
Melting Point (C) : 192C Decomposes
Specific Gravity (H20 = 1) : 1.65
Vapor Pressure (mm Hg) : N/A
Percent Volatile by vol (%): N/A
Vapor Density (Air = 1) : N/A
Evaporation Rate (BuAc = 1): N/A
Solubility in Water (%) : 25%
Appearance :
White granular, powder or crystals
10. STABILITY AND REACTIVITY
Stability: Yes
10
Hazardous Polymerization:
Does not occur
Hazardous Decomposition:
COx
Conditions to Avoid:
Keep container tightly closed to avoid oxidation by air.
Materials To Avoid:
() Water
() Acids
() Bases
() Corrosives
(X) Oxidizers
() Other:
11. TOXICOLOGICAL INFORMATION
Toxicity Data
orl?rat LD50: 11,900 mg/kg
Toxicological Findings:
Test on laboratory animals indicate material may produce adverse
mutagenic and reproductive effects.
Cited in Registry of Toxic Effects of Chemical Substances (RTECS)
12. DISPOSAL CONSIDERATIONS
EPA Waste Numbers:
Treatment:
Material does not have an EPA Waste number and is not a listed waste, however consultation with a permitted
waste disposal site (TSD) should be accomplished.
ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH
ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS.
13. TRANSPORT INFORMATION
DOT Proper Shipping Name:
11
Corrosive Liquid, Acidic, Inorganic, N.O.S. (Contains
Sulfuric Acid) for the kit
DOT ID Number :
UN3264 (for the kit)
14. REGULATORY INFORMATION
TSCA Statement:
The CAS number of this product is listed on the TSCA Inventory.
SARA SARA CERCLA
Component EHS EHS TPQ RQ
(302) (lbs) (lbs)
____________________________________________________________
L(+) Ascorbic Acid
OSHA SARA
DeMinimis
Component Floor List 313
for SARA 313
(%)
____________________________________________________________
L(+) Ascorbic Acid
If there is no information listed on the regulatory information chart, this indicates that the chemical is not
covered by the specific regulation listed.
15. OTHER INFORMATION
Comments:
None
NFPA Hazard Ratings:
Health :0
Flammability :1
Reactivity :0
Special Hazards :
Revision History: 8/14/95
| = Revised Section
12
N/A = Not Available
N/E = None Established
The statements contained herein are offered for informational purposes only and are based upon technical data
that EM Science believes to be accurate. It is intended for use only by persons having the necessary technical
skill and at their own discretion and risk. Since conditions and manner of use are outside our control, we make
NO WARRANTY, EXPRESS OR IMPLIED, OR MERCHANTABILITY, FITNESS OR OTHERWISE.
13