Product Name: C6R BL/REPL
This revision issued: February, 2008
Emergency Information: (02) 9466 2721 (Aust), (09) 414 0400 (NZ)

SECTION 1 - IDENTIFICATION OF CHEMICAL PRODUCT AND COMPANY
FUJIFILM Australia Pty Ltd ABN 80 000 064 433 FUJIFILM (NZ) Limited
114 Old Pittwater Rd Cnr William Pickering Dr & Bush Rd
Brookvale NSW 2100 Albany, Auckland
Phone: (02) 9466 2600 Fax: (02) 9938 1975 Phone (09) 414 0400
Emergency Information: (02) 9466 2721 (Aust), (09) 414 0400 (NZ) http://www.fujifilm.com.au/
Substance: Water solution of ingredients.
C6R BL/REPL
Trade Name:
Product Code: 390316 873372
Product Use: Photographic reagent.
Creation Date: February, 2008
Revision Date: February, 2008

SECTION 2 - HAZARDS IDENTIFICATION
Statement of Hazardous Nature
This product is classified as: Xi, Irritating. Hazardous according to the criteria of ASCC.
Dangerous according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R36/38. Irritating to eyes and skin.
Safety Phrases: S2, S36, S24/25. Keep out of reach of children. Wear suitable protective clothing. Avoid contact
with skin and eyes.
SUSDP Classification: None allocated.
ADG Classification: Class 8 (CORROSIVE LIQUID, N.O.S.)
UN Number: 1760
Emergency Overview
Physical Description & colour: Dark amber coloured liquid.
Odour: No odour.
Major Health Hazards: irritating to eyes and skin.
Potential Health Effects
Inhalation:
Short term exposure: Available data indicates that this product is not harmful. However product may be mildly
irritating, although unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data indicates that this product is a skin irritant. Symptoms may include itchiness
and reddening of contacted skin. Other symptoms may also become evident, but all should disappear once exposure
has ceased.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and
watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms
should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent
damage.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. However, this product is an oral
irritant. Symptoms may include burning sensation and reddening of skin in mouth and throat. Other symptoms may
also become evident, but all should disappear once exposure has ceased.
Long Term exposure: No data for health effects associated with long term ingestion.

MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: (02) 9466 2600
FUJIFILM (NZ) Limited Phone: (09) 414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
 Product Name: C6R BL/REPL
This revision issued: February, 2008
Emergency Information: (02) 9466 2721 (Aust), (09) 414 0400 (NZ)
Carcinogen Status:
ASCC: No significant ingredient is classified as carcinogenic by ASCC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
Potassium nitrate 7757-79-1 1-5 not set not set
Ammonium bromide 12124-97-9 10-20 not set not set
Ferric ammonium EDTA 68413-60-5 15-30 not set not set
Water 7732-18-5 to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The ASCC TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day
for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no
longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures
at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

SECTION 4 - FIRST AID MEASURES
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Wash gently and thoroughly with warm water (use non-abrasive soap if necessary) for 10-20 minutes
or until product is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g.
watchbands and belts) and completely decontaminate them before reuse or discard. If irritation persists, repeat
flushing and seek medical attention.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes or until
the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the
unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing
contact lenses.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.

SECTION 5 - FIRE FIGHTING MEASURES
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
Only small quantities of decomposition products are expected from this products at temperatures normally achieved in
a fire. This will only occur after heating to dryness.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. water fog. Water fog
or fine spray is the preferred medium for large fires. Ensure that no spillage enters drains or water courses.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point: Does not burn.
Upper Flammability Limit: Does not burn.
Lower Flammability Limit: Does not burn.
Not applicable - does not burn.
Autoignition temperature:
Flammability Class: Does not burn.

SECTION 6 - ACCIDENTAL RELEASE MEASURES
Accidental release: This product is sold in small packages, and the accidental release from one of these is not
usually a cause for concern. For minor spills, clean up, rinsing to sewer and put empty container in garbage. Wear


MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: (02) 9466 2600
FUJIFILM (NZ) Limited Phone: (09) 414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
 Product Name: C6R BL/REPL
This revision issued: February, 2008
Emergency Information: (02) 9466 2721 (Aust), (09) 414 0400 (NZ)
impermeable gloves when handling this product. In the event of a major spill, prevent spillage from entering drains or
water courses and call emergency services.

SECTION 7 - HANDLING AND STORAGE
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Store in a cool, well ventilated area. Check containers periodically for corrosion and leaks. Containers
should be kept closed in order to minimise contamination. Make sure that the product does not come into contact with
substances listed under "Incompatibilities" in Section 10. If you keep more than 10000kg or L of Dangerous Goods of
Packaging Group III, you may be required to license the premises or notify your Dangerous Goods authority. If you
have any doubts, we suggest you contact your Dangerous Goods authority in order to clarify your obligations. Check
packaging - there may be further storage instructions on the label.

SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
ASCC Exposure limits
Exposure limits have not been established by ASCC for any of the significant ingredients in this product.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect
your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where
this product is being used.
Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that
all skin areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being
used.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES:
Physical Description & colour: Dark amber coloured liquid.
Odour: No odour.
Boiling Point: Approximately 100?? at 100kPa.
C
Freezing/Melting Point: Approximately 0?? C.
Volatiles: Water component.
Vapour Pressure: 2.37 kPa at 20?? (water vapour pressure).
C
Vapour Density: No data.
Specific Gravity: No data.
Water Solubility: Completely soluble in water.
pH: 5.45
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: No data
Autoignition temp: Not applicable - does not burn.



MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: (02) 9466 2600
FUJIFILM (NZ) Limited Phone: (09) 414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
 Product Name: C6R BL/REPL
This revision issued: February, 2008
Emergency Information: (02) 9466 2721 (Aust), (09) 414 0400 (NZ)

SECTION 10 - STABILITY AND REACTIVITY
Reactivity: This product will react with reactive metals such as zinc, tin, aluminium and their alloys. This may result
in the liberation of hydrogen gas which forms explosive mixtures in air.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30??C. Keep containers tightly
closed.
Incompatibilities: bases, strong oxidising agents, zinc, tin, aluminium and their alloys.
Fire Decomposition: Only small quantities of decomposition products are expected from this products at
temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if
combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some
circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Water, potassium,
bromine and iron compounds. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness,
confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Local Effects:
Target Organs: There is no data to hand indicating any particular target organs.
Classification of Hazardous Ingredients
Ingredient Risk Phrases
No ingredient mentioned in the HSIS Database is present in this product at hazardous concentrations.

SECTION 12 - ECOLOGICAL INFORMATION
Insufficient data to be sure of status. However, considered unlikely to be an environmental threat.

SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal: This product may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for
its intended use. If it has been contaminated, it may be possible to separate the contamination in some way. Only if
neither of these options is suitable, consider landfill.

SECTION 14 - TRANSPORT INFORMATION
ADG Code: 1760, CORROSIVE LIQUID, N.O.S.
Hazchem Code: 2X
Special Provisions: 223, 274
Limited Quantities: ADG 7 specifies a limited quantity value of 5L for this class of product.
Dangerous Goods Class: Class 8, Corrosive Substances.
Packaging Group: III
Packaging Method: 3.8.8
Class 8 Corrosive Substances shall not be loaded in the same vehicle or packed in the same freight container with
Classes 1 (Explosives), 4.3 (Dangerous When Wet Substances), 5.1 (Oxidising Agents), 5.2 (Organic Peroxides), 6
(Toxic Substances where the Toxic Substances are cyanides and the Corrosives are acids), 7 (Radioactive
Substances), Foodstuffs and foodstuff empties. They may however be loaded in the same vehicle or packed in the
same freight container with Classes 2.1 (Flammable Gases), 2.2 (Non-Flammable, Non-Toxic Gases), 2.3 (Poisonous
Gases), 3 (Flammable liquids), 4.1 (Flammable Solids), 4.2 (Spontaneously Combustible Substances), 6 (Toxic
Substances except where the Toxic Substances are cyanides and the Corrosives are acids) and 9 (Miscellaneous
Dangerous Goods).

SECTION 15 - REGULATORY INFORMATION
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
SECTION 16 - OTHER INFORMATION
This MSDS contains only safety-related information. For other data see product literature.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: (02) 9466 2600
FUJIFILM (NZ) Limited Phone: (09) 414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
 Product Name: C6R BL/REPL
This revision issued: February, 2008
Emergency Information: (02) 9466 2721 (Aust), (09) 414 0400 (NZ)
A more recent version of this MSDS might be found at http://www.fujifilm.com.au/
Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
ASCC Office of the Australian Safety and Compensation Council
CAS number Chemical Abstracts Service Registry Number
Emergency action code of numbers and letters that provide information to
Hazchem Code
emergency services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
National Toxicology Program (USA)
NTP
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
United Nations Number
UN Number
THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AN HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF
HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,
THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT
TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.

Please read all labels carefully before using product.
This MSDS is prepared in accord with the ASCC document ??National Code of Practice for the Preparation
of Material Safety Data Sheets?? 2nd Edition [NOHSC:2011(2003)]
Copyright ? Kilford & Kilford Pty Ltd, February 2008.
http://www.kilford.com.au/ Phone (02) 9251 4532




MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: (02) 9466 2600
FUJIFILM (NZ) Limited Phone: (09) 414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)


diammonium [[N,N'-ethylenebis[N-(carboxymethyl)glycinato]](4-)-N,N',O,O',ON,ON']hydroxyferrate(2-)