MATERIAL SAFETY DATA SHEET

Date Printed: 3/19/2003
17679, 17680, 17038, 17681
Product Code:
HIGH SOLIDS AEROSOL LACQUE Product Name:
Manufactured Exclusively for:



By:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
800-510-8510
24-hour Emergency Phone:


1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

(SEE TOP OF
2. COMPOSITION/INFORMATION ON INGREDIENTS

COMPONENT/EXPOSURE LIMITS CAS#
-----------------------------------------------------------------------
----
CELLULOSE NITRATE 23 MIXTURE
AQUEOUS ISOPROPANOL: OSHA PEL 400 ppm
METHYL ETHYL KETONE 78-93-3
METHYL ETHYL KETONE: OSHA PEL 200ppm, 590mg/m3,ACGIH TLV 300ppm, 885mg/m3
PROPANE 74-98-6
TOLUENE 108-88-3
OSHA PEL: 200ppm
ACGIH TLV 50ppm
N. BUTANE 106-97-8
ROSIN BASED RESIN 25 68038-41-5
ISOBUTYL ACETATE 110-19-0
OSHA: PEL 150ppm-TWA
ACGIH TLV 150ppm-TWA

ISOPROPANOL 67-63-0
400ppm TWA8 ACGIH, 983 mg/m3 TWA8 ACGIH
980mg/m3 TWA8 OSHA, 500ppM STEL OSHA

NITROCELLULOSE 9004-70-0



PLASTICIZER 68515-42-4
ISOBUTYL ISOBUTYRATE 97-85-8
ACGIH TLV: NOT ESTABLISHE OSHA PEL: NOT ESTABLISHE ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2
ACGIH 25ppm TWA
OSHA 25ppm TWA
AROMATIC 100 64742-95-6




3. HAZARDS IDENTIFICATION
FLAMMABLE LIQUID UNDER PRESSURE
VAPOR CAUSES EYE BURNS AND SKIN IRRITATION

POTENTIAL HEALTH EFFECTS
SKIN:Widespread contact with skin for several hours can cause harmful amounts of material to be
absorbed.
 MATERIAL SAFETY DATA SHEET

Date Printed: 3/19/2003
17679, 17680, 17038, 17681
Product Code:
HIGH SOLIDS AEROSOL LACQUE Product Name:
Manufactured Exclusively for:



By:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
800-510-8510
24-hour Emergency Phone:


INGESTION:Excessive inhalation of vapors can cause nasal and respiratory irritation, dizziness,
weakness, fatigue,nausea, headache, possible unconsciousness and even asphyxiation.
INHALATION:High vapor concentrations or prolonged breathing of lower concentrations may result in
damage to the liver, kidneys, lungs and blood forming organs.

4. FIRST AID MEASURES
EYES:Flush with luke warm water for a minimum of 15 minutes. Seek medical attention immediately.
SKIN:Remove contaminated clothing, wash area immediately with soap and water. See physician if
irritation
persists.

INGESTION:Rinse mouth immediately. Drink 1 or 2 glasses of water to dilute. Do NOT induce
vomiting. Contact physican or poison control center immediately.
INHALATION:Remove exposed individual to fresh air and assist breathing if necessary. Seek
immediate medical
attention.

5. FIRE FIGHTING MEASURES
FLAMMABLE CLASSIFICATION: CLASS 1B
LOWEST FLASH POINT: 30F
METHOD: TCC

FLAMMABLE LIMITS:
LOWER FLAMMABLE LIMIT: .96
UPPER FLAMMABLE LIMIT: 12.7
EXTINGUISHING MEDIA: Alcohol Foam, CO2, Dry Chemical

UNUSUAL FIRE AND EXPLOSION HAZARDS

Burning may produce oxides of nitrogen and carbon. Do not puncture or incinerate container.
Exposure to heat or prolonged exposure to sun may cause container to burst. Do not expose to
heat or store at temperatures above 120 degrees F. Vapors are heavier than air and may travel
along the ground or may be moved by ventilation and ignited by pilot lights, sparks, heaters,
smoking, electrical motors or static discharge distant from handling point.

FIREFIGHTING INSTRUCTIONS:

6. ACCIDENTAL RELEASE MEASURES
Stay upwind and away from spill or leak unless wearing appropriate protective equipment.
Stop and/or contain discharge if it may be done safely. Keep all sources of ignition away.
Ventilate area of spill. Use non-sparking tools for clean up. Cover with inert material to reduce
fumes. Keep out of drains, sewer or waterways.
If large spill occurs, alert spill response teams. Contact fire
authorities. Notify local health and pollution control agencies.
 MATERIAL SAFETY DATA SHEET

Date Printed: 3/19/2003
17679, 17680, 17038, 17681
Product Code:
HIGH SOLIDS AEROSOL LACQUE Product Name:
Manufactured Exclusively for:



By:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
800-510-8510
24-hour Emergency Phone:


7. HANDLING AND STORAGE
HANDLING:Personnel should avoid inhalation of vapors. Personal contact with the product should be
avoided. Should contact be made, remove saturated clothing and flush affected skin areas with water.
Containers
of this material may be hazardous when emptied. Since emptied containers retain product residues
(vapor, liquid and/or solid), all hazard precautions given in this sheet must be observed.

STORAGE:Keep product containers cool, dry and away from sources of ignition. Use and store this
product with
adequate ventilation. DO NOT SMOKE in or near storage areas

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
RESPIRATORY PROTECTION:Use local exhaust as required to control vapor concentrations. Avoid
prolonged or repeated breathing of vapors. If exposure exceeds TLV, use NIOSH-approved respirator to
prevent overexposure.
SKIN PROTECTION:Required for prolonged or repeated contact. Wear resistant gloves such as
natural rubber, neoprene, buna N or nitrile. An apron should be worn to avoid skin contact.
EYE PROTECTION:Wear splashproof goggles and face shield if there is a likelihood of contact with
eyes.
HYGENIC PRACTICES:Wash hands thoroughly before eating or using restroom. Remove contaminated
clothing immediately and do not wear again until it has been properly laundered.

9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT: 175.3F
MELTING POINT: N/A
VAPOR PRESSURE: N/A
VAPOR DENSITY: Heavier Than Air
SOLUBILITY IN WATER: N/A
SPECIFIC GRAVITY: .823
COATING VOC LB/GL: 1.7614 lb/gl
COATING VOC GM/LTR: 211 g/l
MATERIAL VOC LB/GL: 1.7614 lb/gl
MATERIAL VOC GM/LTR: 211 g/l
% VOLATILE BY VOLUME: 39.143%
EVAPORATION RATE: Faster than Butyl Acetate.
HAPS/GALLON: .
LBS HAPS/LBS SOLID: .
WEIGHT PER GALLON: 6.853 lb/gl
PH: N/A
ODOR: N/A
APPEARANCE: N/A
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY:Stable Conditions to Avoid: high heat, sparks, flames
 MATERIAL SAFETY DATA SHEET

Date Printed: 3/19/2003
17679, 17680, 17038, 17681
Product Code:
HIGH SOLIDS AEROSOL LACQUE Product Name:
Manufactured Exclusively for:



By:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
800-510-8510
24-hour Emergency Phone:


INCOMPATIBILITY Materials to Avoid: Strong oxidizing agents, strong alkalines, strong mineral
acids.
HAZARDOUS DECOMPOSITION PRODUCTS:Oxidation may produce carbon and nitrogen oxides.
HAZARDOUS POLYMERIZATION:Will not occur.
11. TOXICOLOGICAL INFORMATION
CANCER INFORMATION:This product contains no reported carcinogens or suspected carcinogens.
This product contains no reportable hazardous ingredients. This Material Safety Data Sheet contains
information on good industrial practice for safe handling of all industrial chemicals.
TERATOLOGY (BIRTH DEFECT) INFORMATION:This product contains no reported or suspected
teratogens.
REPRODUCTION INFORMATION:Toluene is a chemical known to the state of California to cause
birth defect or other reproductive harm.
12. ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION:


13. DISPOSAL CONSIDERATIONS
Dispose in accordance with local, state and federal regulations.
14. TRANSPORT INFORMATION
DOT NUMBER: UN1950
15. REGULATORY INFORMATION
HMIS HAZARD INDEX: 4=SEVERE, 3=SERIOUS, 2=MODERATE, 1=SLIGHT, 0=LEAST
HEALTH: 2
FLAMMABILITY: 4
REACTIVITY: 0
PERSONAL PROTECTION: I
SECTION 313:

% BY WT
* METHYL ETHYL KETONE 78-93-3 22
* TOLUENE 108-88-3 13
* ETHYLENE GLYCOL MONOBUTYL ETHER111-76-2 1
* AROMATIC 100 64742-95-6

16. DISCLAIMER:
The following supercedes any provision contained in the forms, letters and papers of your
company. This product is designed and intended for professional application only. All products
should be thoroughly tested under application conditions prior to use. The information contained
herin is believed to be reliable. HOWEVER, GEMINI MAKES NO WARRANTY CONCERNING THIS PRODUCT,
WHETHER EXPRESS OR IMPLIED. INCLUDING THE WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE.
UNDER NO CIRCUMSTANCES SHALL GEMINI BE LIABLE FOR SPECIAL, INCIDENTAL,CONSEQUENTIAL,OR ANY OTHE DAMAGES FROM ALLEGED NEGLIGENCE, BREACH OF WARRENTY, STRICT LIABILITY, OR ANY OTHER LEGAL THEORY,
ARISING OUT OF THE USE OR HANDLING OF THIS PRODUCT. THE SOLE REMEDY OF THE BUYER AND THE SOLE
LIABILITY OF GEMINI FOR ANY CLAIMS SHALL BE LIMITED TO THE BUYER'S PURCHASE PRICE OF THE PRODUCT
 MATERIAL SAFETY DATA SHEET

Date Printed: 3/19/2003
17679, 17680, 17038, 17681
Product Code:
HIGH SOLIDS AEROSOL LACQUE Product Name:
Manufactured Exclusively for:



By:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
800-510-8510
24-hour Emergency Phone:


WHICH IS THE SUBJECT OF THE CLAIM OR THE AMOUNT ACTUALLY PAID FOR SUCH PRODUCT, WHICHEVER IS
LESS.
TECHNICAL ADVICE FURNISHED BY GEMINI SHALL NOT CONSTITUTE AN EXPRESS WARRANTY, WHICH IS EXPRESSLY
DISCLAIMED. ALL TECHNICAL ADVICE GIVEN IS ACCEPTED AT THE RISK OF THE BUYER.
 MATERIAL SAFETY DATA SHEET

Date Printed: 3/19/2003
17679, 17680, 17038, 17681
Product Code:
HIGH SOLIDS AEROSOL LACQUE Product Name:
Manufactured Exclusively for:



By:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
800-510-8510
24-hour Emergency Phone:


1,2-Benzenedicarboxylic acid, di-C7-11-branched and linear alkyl esters