3735 GREEN ROAD TELEPHONE: (216)292-5000 EMERGENCIES: (216)765-6727 8:30-5:00 EST
BEACHWOOD, OHIO 44122-8068 AFTER HOURS: CHEMTREC (800)424-9300
---------------- SECTION 1
---------------- Order Code: 254100 805
Product Name: DECKTITE 100 CP PRIME Chemical Family: Primer
Product Code: 254-100 Date Prepared: 03-SEP-96
MSDS Preparer: C.R.Bruno Replaces Date: 13-DEC-94
Section 2 - Molecular Composition
Common Name and Chemical Name Weight % CAS Number
Exposure Limits
XYLENES (DIMETHYLBENZENES) 30.0-40.0 1330-20-7
OSHA:TWA 100 ppm STEL 150 ppm
ACGIH:TWA 100 ppm STEL 150 ppm
POLYURETHANE POLYMER 25.0-35.0 Trade Secret
OSHA:TWA - STEL -
ACGIH:TWA - STEL -
PROPYLENE GLYCOL ETHER ACETATE 15.0-20.0 108-65-6
OSHA:TWA - STEL -
ACGIH:TWA - STEL -
CHLORINATED PARAFFIN WAX 5.0-10.0 68527-02-6
OSHA:TWA - STEL -
ACGIH:TWA - STEL -
ETHYL BENZENE 5.0-10.0 100-41-4
OSHA:TWA 100 ppm STEL 125 ppm
ACGIH:TWA 100 ppm STEL 125 ppm
ISOCYANATE 1.0-5.0 Trade Secret
OSHA:TWA - Ceil 0.010ppm
ACGIH:TWA 0.005ppm STEL -
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Section 3 - Hazards Identification
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Emergency Overview:
Amber liquid. Can cause headache, irritation, nausea, drowsiness, stupor,
coughing spell and allergic respiratory sensitization. If inhaled, leave to
breathe fresh air. Should be observed by physican immediately if
overexposure is severe.
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Potential Hlth Effect/Rte of Entry:
-----------------------------------
Inhalation:
Can cause headache, irritation, nausea, drowsiness, stupor, coughing spell
and allergic respiratory sensitization.
Eyes:
Can cause irritation, redness, tearing.
Ingestion:
May cause gastrointestinal irritation. Aspiration during swallowing or
vomiting may cause lung damage and can be fatal.
Skin:
Can cause irritation, sensitization, dermatitis.
Aggravated Medical Conditions:
Preexisting eye, skin, and respiratory disorders maybe aggravated by
exposure.
Acute Health Effects:
Allergy to isocyanates.
Chronic Health Effects:
Deliberate misuse by concentrating and inhaling the contents may
cause brain or nervous system damage, hearing loss, and maybe fatal.
Overexposure to isocyanate can cause a decrease in lung function. Skin and
respiratory sensitization is possible. Prolonged or repeated contact/exposure
467 130 2
Product 254-100 Order Code: 254100 805
to xylene and ethyl benzene may cause defatting, drying, and irritation of
the skin, dermatitis, CNS effects described above, heart muscle
sensitization and arrhythmia, hearing loss, and brain, liver, and kidney
damage. Etyl benzene may cause testes damage. Acetate compound(s) are mildly
narcotic. Extremely high exposures may cause narcotic effects, congestion
of liver and kidneys and adverse effects on blood. Overexposure to carbon
tetrachloride can cause labored breathing, muscle twitches, abdominal
pain, jaundice, detrimental effects on liver and kidney.
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Section 4 - First Aid Measures
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Inhalation:
Leave area to breathe fresh air. Should be observed by physician
immediately if overexposure is severe.
Eyes:
Flush immediately with running water for 15 minutes, lifting the upper and
lower lids occasionaly. Get medical attention immediately.
Ingestion:
Get medical attention immediately.
Skin:
Clean area of contact thoroughly using soap and water. If irritation, rash
or other disorders develop, get medical attention immediately.
Notes to Physician: N/A
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Section 5 - Fire Fighting Measures
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Flash Point: 80 F
Method: Seta
Lower Flammability Limit: Not Established
Upper Flammability Limit: Not Established
Autoignition Temperature: Not Established
Extinguishing Media:
Carbon dioxide, dry chemical, foam.
Fire and Explosion Hazards:
Never use welding or cutting torch on or near container (even empty).
Product, residue or vapor may ignite. See section IX for additional
precautions.
Special Fire Fighting Procedures:
During a fire, personnel at the scene are to prevent exposure to fumes
using accepted fire fighting techniques.
Fire Fighting Equipment: N/A
Other Precautions:
Hydrocyanic acid, oxides of nitrogen can form.
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Section 6 - Accidental Release Measures
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Release Response Overview:
Remove sources of ignition immediately. Ventilate to reduce the airborne
contaminant concentration below the exposure limit in Section II of the
MSDS. Absorb spill in sand, earth or other suitable material. Transfer to
appropriate container for disposal.
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Section 7 - Handling and Storage
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Handling and Storage Precautions:
Store in closed container below 80F. Keep product and vapor away from heat,
sparks and flame. Do not store in direct sunlight. Prevent inhalation of
vapor, ingestion, and contact with skin and eyes. Keep container closed
when not in use. Vapor may migrate to sources of ignition. Do not smoke,
weld, generate sparks, or use flame near container. Change soiled
workclothes frequently. Clean hands thoroughly after handling. To prevent
gases, vapors or fumes from migrating into occupied sections of the
building, close or cover all openings including windows, doors and air
intakes during and after application until gases, vapors or fumes
468 130 3
Product 254-100 Order Code: 254100 805
dissipate. To prevent generation of static discharges, use
bonding/grounding connection when pouring liquid. Extinguish all ignition
sources including pilot lights, non-explosion proof motors and electrical
equipment until vapors dissipate. Precautions also apply to emptied
containers.
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Section 8 - Exposure Controls/Personal Protection
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Respiratory:
Wear appropriate, properly fitted NIOSH/MSHA approved respirator when
airborne contaminant level(s) exceed exposure limits indicated in Section
II. Select positive pressure supplied air respirator (TC19C or equivalent)
for isocyanates.
Skin:
Protect hands with impervious rubber gloves and wear rubber apron and
overshoes. Prevent contact with skin.
Eyes:
Chemical splash goggles.
Face:
Face shield is recommended.
Engineering:
Use local exhaust when the general ventilation is not sufficient to keep
the airborne contaminant concentration below the exposure limit in Section
II of the MSDS.
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Section 9 - Physical and Chemical Properties
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Odor/Appearance: SOLVENT/AMBER LIQUI Color: AMBE Physical State: Liquid
pH: N/A
Vapor Pressure: Not established
Vapor Density: >1
Boiling Point: N/A
Melting Point: N/A
Freezing Point: N/A
Solubility in Water: Negligible
Specific Gravity: 0.9724
% Volatile Weight: 60.0
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Section 10 - Reactivity/Stability
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Stability:
Stable
Incompatible Products:
Avoid contact with water, amines, bases, oxidizers, alcohols.
Conditions to Avoid Polymerization:
Hazardous polymerization will not occur.
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Section 11 - Toxicological Information
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Eyes: SEE SECTION 3
Ingestion: " " "
Inhalation: " " "
Skin: " " "
Subchronic: " " "
Chronic: " " "
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Section 12 - Ecological Information
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Ecotoxicological Data: N/A
Chemical Fate: N/A
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Section 13 - Disposal Considerations
469 130 4
Product 254-100 Order Code: 254100 805
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RCRA Class:
D001 - IGNITABLE LIQUID OR SOLID WASTE (RQ = 100.0 LB)
D018 - HAZARDOUS WASTE CONTAINING BENZENE (RQ = 10.0 LB)
Disposal Method:
Subject to hazardous waste treatment, storage, and disposal requirements
under RCRA. Incinerate at EPA approved facility or dispose of in compliance
with federal, state and local regulations.
EPA Reportable Quantities
-------------------------
N/A
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Section 14 - Transportation Data
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DOT Shipping Name: COATING SOLUTION, CLASS 3, UN1139, PG III
DOT Hazard Class: FLAMMABLE LIQUI DOT Label: HAZARDOUS
UN/NA Number: UN1139
Packing Group: III
Special Provisions:
Packaging
---------
Exceptions: 49CFR173.13
Non-Bulk:
Bulk:
Quantity Limitations
--------------------
Passenger Aircraft or Railcar:
Cargo Aircraft:
Vessel Stowage Requirements
---------------------------
Vessel Stowage:
Other Stowage:
Transportation Notes: N/A
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Section 15 - Regulatory Information
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TSCA Status: On the TSCA Inventory
OSHA Status: Considered hazardous based on the following criteria:
Irritant
Sensitizer
Target Organs
-------------
Liver
Kidney
Central Nervous System
Blood
Reproductive
Lung
Skin
Eye
Heart
Spleen
Ear
OSHA Hazardous Components CAS Number
---------------------------------------------- ------------
CHLORINATED PARAFFIN WAX 68527-02-6
ETHYL BENZENE 100-41-4
XYLENES (DIMETHYLBENZENES) 1330-20-7
ISOCYANATE Trade Secret
470 130 5
Product 254-100 Order Code: 254100 805
* CARBON TETRACHLORIDE 56-23-5
* CHEMICAL IS LISTED AS AN IARC, NTP, OSHA, or ACGIH CARCINOGEN
Compliance Quantites
--------------------
Source Type Threshold Unit of Measure
RCRA(D018) REPORTABLE QUANTITY 10.0 POUNDS
SARA 311 Ratings
----------------
Immediate Health Hazard: Y
Delayed Health Hazard: Y
Fire Hazard: Y
Reactivity Hazard: N
Sudden Release of Pressure Hazard: N
SARA 313 Ingredients CAS Number
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CHLORINATED PARAFFIN WAX 68527-02-6
ETHYL BENZENE 100-41-4
XYLENES (DIMETHYLBENZENES) 1330-20-7
ISOCYANATE Trade Secret
CARBON TETRACHLORIDE 56-23-5
Proposition 65 Ingredients
--------------------------
Chemicals known to the State of California to cause cancer,
birth defects and/or other reproductive harm. CAS Number
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CARBON TETRACHLORIDE(<0.004%) 56-23-5
BENZENE(<0.0002%) 71-43-2
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Section 16 - Other Information
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FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF CHILDREN.
THE HAZARD INFORMATIOM HEREIN IS OFFERED SOLELY FOR THE CONSIDERATION
OF THE USER, SUBJECT TO HIS OWN INVESTIGATION OF COMPLIANCE WITH APPLICABLE
REGULATIONS, INCLUDING THE SAFE USE OF THE PRODUCT UNDER EVERY FORESEEABLE
CONDITION.
471 130 6
Product 254-100