MATERIAL SAFETY DATA SHEET
PRODUCT NAME: LANASOL RED 5B
MSDS CODE : C0185459AO
VERSION : 3
UPDATED : October 2003

Hazardous according to criteria of NOHSC Australia
:
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COMPANY DETAILS
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CIBA SPECIALTY CHEMICALS
235 Settlement Road Unit 10, 43-51 College Street
THOMASTOWN VIC 3074 GLADESVILLE NSW 2111
Phone: (03) 9282 0600 Phone: (02) 9879 2500
Fax: (03) 9465 0031 Fax: (02) 9879 2501
Emergency All Hours; AUS:1800 033 111 NZL:0800 734 607
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Attn:
CHEMICAL SAFETY OFFICE or
EMERGENCY RESPONSE SERVICES
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IDENTIFICATION
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PRODUCT NAME ..: LANASOL RED 5B
Other name(s)..: AZO DYE PREPARATION
Correct Shipping name: NOT APPLICABLE
UN Number . . . . . : FREE
Dangerous Goods Class Packaging
and Subsidiary Risk : NOT APPLICABLE group . . : NOT APPLICABLE
HAZCHEM Code . . . . : NOT APPLICABLE
Poison Schedule . . : NON ALLOCATE USE:
TEXTILE DYE
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Appearance. . . . . . : RED, POWDER WITH NO ODOU Boiling/Melting point : NOT AVAILABLE
Vapour pressure . . . : NOT APPLICABLE
Density . . . . . . . : 0.68 g/ml (g/cc @ 20 deg.C)
Flash Point . . . . . : NOT APPLICABLE
Flammability Limits . : not applicable
Solubility in water . : 30 g/l at 30 oC (g/L @ 20 deg.C)
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pH : 5.0-6.5
Thermal Decomposition : >200 oC
IGNITION TEMPERATURE : 460 oC
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Chemical Entity CAS No. Proportion
Sodium 5-((4-((2-Bromo-1-oxo-2-propenyl) 70210-39-8 70-80%
amino)-2-sulfophenyl)azo)-4-hydroxy-6-(m
ethylamino)-2-naphthylsulfonate
NON HAZARDOUS COMPONENTS To 100 %
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HEALTH HAZARD INFORMATION
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Swallowed : SLIGHT (Oral,Rat LD50) >5000 mg/kg
Eye . . . : NON IRRITANT - RABBIT
Skin . . : NON IRRITANT - RABBIT
SENSITIZING - GUINEA PIG. OECD 406
Inhaled . : MAY CAUSE SENSITIZATION BY INHALATION.
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CASES OF RESPIRATORY SENSITISATION HAVE BEEN OBSERVED WITH THIS DYE
AND CARE SHOULD BE TAKEN TO AVOID INHALATION.
SKIN SENSITISATION: EXPOSURE OF SKIN TO A SENSITISING AGENT TENDS TO
RESULT IN RESPONSES SUCH AS HIVES OR EXZEMA. SHOULD AN INDIVIDUAL
BECOME SENSITISED, A DOCTOR SHOULD BE CONSULTED AND ALL CONTACT WITH
THE SENSITISING PRODUCT MUST CEASE IMMEDIATELY.
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Swallowed : WASH OUT MOUTH WITH WATER, DRINK PLENTY OF WATE SEEK MEDICAL ADVICE.
Eye . . . : RINSE IMMEDIATELY WITH COOL, CLEAN RUNNING WATE FOR AT LEAST 15 MINUTES.
Skin . . : CLEAN CONTAMINATED AREAS WITH SOAP AND PLENTY OF
RUNNING WATER. REMOVE CONTAMINATED CLOTHING. SEEK
MEDICAL ATTENTION.
Inhaled . : REMOVE PATIENT TO FRESH AIR, REST. IF SYMPTOMS OF
ASTHMA OR BREATHING DIFFICULTIES OCCUR, SEEK
MEDICAL ATTENTION. ASSIST BREATHING (OXY-VIVA
EQUIP) UNTIL HELP ARRIVES.
First aid facility: DELUGE SAFETY SHOWER SHOULD BE LOCATED NEAR WORK
AREA.
Advice to Doctor .: TREAT SYMPTOMATICALLY, NO SPECIFIC ANTIDOTE KNOWN.
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PRECAUTIONS FOR USE
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AVOID EXPOSURE BY USE OF VENTILATION AND/OR PERSONAL PROTECTION.
AVOID DUST FORMATION
FOLLOW GOOD WORKING PRACTICE : HANDLE WITH CARE, AVOID INGESTION,
INHALATION, EYE OR SKIN CONTACT.
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WHEREVER POSSIBLE, THE WORKPLACE MUST BE VENTILATED SUFFICIENTLY TO
ENSURE THAT THE LPL OF EXPOSURE IS ATTAINED. ANY STATE REGULATIONS ON
SPEED AND DIRECTION OF AIRFLOW AWAY FROM OPERATORS MUST BE OBSERVED.
HAZARDOUS POWDERS: THE USE OF LOCAL EXHAUST EXTRACTION DEVICE IN
ADDITION TO ROOM VENTILATION IS REQUIRED WITH THIS PRODUCT. LOCAL
EXHAUST EXTRACTION CAN BE A SLOT OR HOOD LOCATED AT DISPENSING POINT
OR A DOWNDRAUGHT WEIGHING BOOTH WITH HEPA AIR CLEANER.
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GLOVES (PVC, LONG IMPERVIOUS), OVERALLS AND GLASSES/FACE SHIELD MUST
BE WORN WITH THIS PRODUCT.
PARTICULATE FILTER CLASS P1 (DUST MASK) IS REQUIRED TO BE WORN WHEN
POSITIVE LOCAL VENTILATION IN OPERATION, OTHERWISE THE FOLLOWING
AS1716 RESPIRATORY PROTECTION MUST BE WORN.
HALF FACE MASK: "YES" CANNISTER TYPE: NOT APPLICABLE
CARTRIDGE CLASS: "CLASS P2" FOR POWDERS, AND "CLASS A2" FOR LIQUIDS.
PRE FILTER: RECOMMENDED. FULL FACE MASK: "SUITABLE". AI SUPPLIED: "YES, AIR-LINE". COMBINATION ORGANIC VAPOUR PARTICULATE
TYPE A2-P2 CARTRIDGE. (MEDIUM CAPACITY/EFFICIENCY FILTER IS SUITABLE.
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KEEP AWAY FROM SOURCES OF IGNITION? - NOT APPLICABLE, NOT FLAMMABLE.
DUST CLOUDS FROM FINELY PARTICULATED PRODUCT MAY BE HAZARDOUS (DUST
EXPLOSION RISK). EQUIPMENT SHOULD BE ADEQUATELY GROUNDED.
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SAFE HANDLING INFORMATION
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General . . . . . . : STORE IN A COOL, DRY AREA WITH ADEQUATE
Storage . . . . . . : VENTILATION. KEEP CONTAINERS CLOSED.
UN Number . . . . . : FREE
Dangerous Goods Class Packaging
and Subsidiary Risk : NOT APPLICABLE group . . : NOT APPLICABLE
HAZCHEM Code . . . . : NOT APPLICABLE
IATA Class . . . . . : FREE
IMDG Reference . . . : FREE
Minimum temperature : NOT APPLICABLE
Maximum temperature : NOT APPLICABLE
Incompatible DG Classes : NONE KNOWN
Incompatible Receptacle : NONE KNOWN
Incompatible Substances : NONE KNOWN
Emergency Procedure Guide Date: NOT APPLICABLE
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IN CASE OF SPILL, WEAR PERSONAL PROTECTION AS INDICATED ABOVE. DAMPEN
DOWN FIRST, 'AVOID DUST', SCOOP UP THEN WASH DOWN FINAL RESIDUE WITH
DETERGENT AND WATER.
DISPOSE OF ALL WASTE ACCORDING TO STATE REGULATIONS: LAND FILL: "NO"
SECURE LAND FILL: "NO" INCINERATION: "YES" HIGH
TEMPERATURE INCINERATION: "SUITABLE" - CONTAMINATED, EMPTY
CONTAINERS MUST BE DISPOSED OF AS CHEMICAL WASTE. NOTE: IF IN DOUBT,
CONTACT CIBA SPECIALTY CHEMICALS TELEPHONE NUMBER ON =--------------------------------------------------------------------=
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Extinguishing Media : WATERSPRAY, CO2, FOAM, DRY POWDER - NO
RESTRICTIONS.
Hazardous combustion products:
VAPOURS OF CARBON, NITROGEN AND SULFUR OXIDES POSSIBLE IN A FIRE.
SELF CONTAINED BREATHING APPARATUS MUST BE WORN IN CASE OF FIRE.
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OTHER INFORMATION
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BOD 5 . . . . . . . . . . . : 65 mg02/g
COD . . . . . . . . . . . . : 695 mg02/g
TOC . . . . . . . . . . . . : 29%
Fish toxicity . . . . . . . : SPECIES : RAINBOW TROUT, 48HR, OECD 203
LCo : > 1000 mg/l
LC50 : > 1000 mg/l
NITROGEN CONTENT: 6.4 %
Toxicity to Bacteria . . . : BST : > 300 mg/l
OECD Biological degredation : 60-70%, TOC ANALYSIS, OECD 303A (MOD)
Organo-halogen content. . . : <0.1% BROMO
Heavy-metal content . . . . : METAL CONTENT UNDER THE ETAD REC. LIMITS
Phosphorous content . . . . : N/AP %
NOTE: PREVENT SPILLAGE FROM ENTERING WATERWAYS OR DRAINS.
NOT TOXIC OR HARMFUL TO AQUATIC ORGANISMS.
BEHAVIOUR IN TREATMENT PLANTS: NO INHIBITION. NO NITRIFICATION
INHIBITION KNOWN.
PARTIALLY ELIMINATED BY ADSORPTION ON EFFLUENT TREATMENT SLUDGE.
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EEC classification/labelling: * Xn * HARMFUL
R-phrase: R42/43: May cause sensitisation by inhalation and
skin contact.
S-phrase: S22: DO NOT BREATHE DUST.
S24: AVOID CONTACT WITH SKIN.
SINCE WE CANNOT ANTICIPATE OR CONTROL THE MANY DIFFERENT CONDITIONS
UNDER WHICH THIS INFORMATION AND OUR PRODUCTS MAY BE USED, EACH USE SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE
INTENDED APPLICATION AND CONFIRM THAT THEY ARE APPROPRIATE.
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CONTACT POINT
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Contact the Product Safety Manager:
MR GRAHAM DICKINSON on 03-9282-0609 or 0408 023 891
or MR EFKAN KOCH on 03-9282-0673
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Authorised by: KOCHEF1 Date: 16 October 03
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disodium 5-[[4-[(2-bromo-1-oxoallyl)amino]-2-sulphonatophenyl]azo]-4-hydroxy-6-(methylamino)naphthalene-2-sulphonate