Material Safety Data Sheet
acc. to OSHA and ANSI

1 Identification of substance:
Product details:
Product name: 4-Aminobutyraldehyde dimethyl acetal
2 Composition/Data on components:
Chemical characterization:
Description: (CAS#)
4-Aminobutyraldehyde dimethyl acetal
(CAS# 19060-15-2): 100%
Identification number(s):
EINECS Number: 407-690-6
EU Number: 612-174-00-0


3 Hazards identification
Hazard description:


C Corrosive


Information pertaining to particular dangers for man and environment
R 22 Harmful if swallowed.
R 34 Causes burns.
R 43 May cause sensitization by skin contact.
R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects
in the aquatic environment
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH 2 Health (acute effects) = 2
Flammability = 1
FIRE 1
Reactivity = 1
REACTIVITY 1




4 First aid measures
General information
Immediately remove any clothing soiled by the product.
After inhalation
Supply fresh air and to be sure call for a doctor.




 Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: 4-Aminobutyraldehyde dimethyl acetal

Supply fresh air. If required, provide artificial respiration. Keep
patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a
doctor.
After swallowing Seek immediate medical advice.

5 Fire fighting measures
Suitable extinguishing agents
Carbon dioxide, extinguishing powder or water spray. Fight larger fires
with water spray or alcohol resistant foam.
Special hazards caused by the material, its products of combustion or
resulting gases:
In case of fire, the following can be released:
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


6 Accidental release measures
Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Measures for environmental protection:
Do not allow material to be released to the environment without proper
governmental permits.
Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders,
universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Additional information:
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage
Handling
Information for safe handling:
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
Keep ignition sources away.
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.




 Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: 4-Aminobutyraldehyde dimethyl acetal

Information about storage in one common storage facility:
Store away from oxidizing agents.
Do not store together with acids.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.

8 Exposure controls and personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals
and having an average face velocity of at least 100 feet per minute.
Components with limit values that require monitoring at the workplace:
Not required.
Additional information: No data
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be
followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
Material of gloves
The selection of suitable gloves not only depends on the material, but
also on quality. Quality will vary from manufacturer to manufacturer.
Eye protection:
Safety glasses
Tightly sealed goggles
Full face protection
Body protection: Protective work clothing.


9 Physical and chemical properties:
General Information
Form: Liquid
Odor: Not determined
Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flash point: Not determined
Ignition temperature: Not determined
Decomposition temperature: Not determined




 Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: 4-Aminobutyraldehyde dimethyl acetal

Danger of explosion: Product does not present an
explosion hazard.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not determined
Density: Not determined
Solubility in / Miscibility with
Water: Not determined


10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to
specifications.
Materials to be avoided:
Oxidizing agents
Acids
Dangerous reactions No dangerous reactions known
Dangerous products of decomposition:
Carbon monoxide and carbon dioxide
Nitrogen oxides

11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin:
Corrosive effect on skin and mucous membranes.
Irritant to skin and mucous membranes.
on the eye:
Strong corrosive effect.
Irritating effect.
Sensitization: Sensitization possible through skin contact.
Subacute to chronic toxicity:
Corrosive materials are acutely destructive to the respiratory tract,
eyes, skin and digestive tract. Eye contact may result in permanent
damage and complete vision loss. Inhalation may result in respiratory
effects such as inflammation, edema, and chemical pneumonitis. May cause
coughing, wheezing, laryngitis, shortness of breath, headache, nausea and
vomiting. Ingestion may cause damage to the mouth, throat and esophagus.
May cause skin burns or irritation depending on the severity of the
exposure.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this
substance is not fully known.
Swallowing will lead to a strong corrosive effect on mouth and throat and
to the danger of perforation of esophagus and stomach.
No classification data on carcinogenic properties of this material is
available from the EPA, IARC, NTP, OSHA or ACGIH.




 Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: 4-Aminobutyraldehyde dimethyl acetal


12 Ecological information:
Ecotoxical effects:
Remark: Harmful to fish
General notes:
Do not allow material to be released to the environment without proper
governmental permits.
Harmful to aquatic organisms

13 Disposal considerations
Product:
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


14 Transport information
DOT regulations:




Hazard class: 8
Identification number: UN2735
Packing group: III
Proper shipping name (technical
name): AMINES, LIQUID, CORROSIVE, N.O.S. (4-
Aminobutyraldehyde dimethyl acetal)
Label 8
Land transport ADR/RID (cross-border)




ADR/RID class: 8 (C7) Corrosive substances
Danger code (Kemler): 80
UN-Number: 2735
Packaging group: III
Description of goods: 2735 AMINES, LIQUID, CORROSIVE, N.O.S.
(4-Aminobutyraldehyde dimethyl acetal)
Maritime transport IMDG:




IMDG Class: 8
UN Number: 2735
Label 8
Packaging group: III




 Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: 4-Aminobutyraldehyde dimethyl acetal

Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (4-
Aminobutyraldehyde dimethyl acetal)
Air transport ICAO-TI and IATA-DGR:




ICAO/IATA Class: 8
UN/ID Number: 2735
Label 8
Packaging group: III
Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (4-
Aminobutyraldehyde dimethyl acetal)


15 Regulations
Product related hazard informations:
Hazard symbols:
C Corrosive
Risk phrases:
22 Harmful if swallowed.
34 Causes burns.
43 May cause sensitization by skin contact.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects
in the aquatic environment
Safety phrases:
26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
36/37/39 Wear suitable protective clothing, gloves and eye/face
protection.
45 In case of accident or if you feel unwell, seek medical advice
immediately.
61 Avoid release to the environment. Refer to special instructions/
Safety data sheets
National regulations
All components of this product are listed in the U.S. Environmental
Protection Agency Toxic Substances Control Act Chemical substance
Inventory.
All components of this product are listed on the Canadian Non-Domestic
Substances List (NDSL).
Information about limitation of use:
For use only by technically qualified individuals.



4-AMINOBUTYRALDEHYDE DIMETHYL ACETAL