Material Safety Data Sheet
Date Printed: 03/03/2005
Date Updated: 04/06/2004
Version 1.20

Section 1 - Product and Company Information

Product Name CALCION - 50MG
Product Number R750344
Brand Aldrich Chemical

Company Sigma-Aldrich
Street Address 3050 Spruce Street
City, State, Zip, Country SAINT LOUIS, MO 63103 US
Technical Phone: 314 771 5765
Fax: 800 325 5052 Emergency Phone: 414 273 3850 Ext. 5996

Section 2 - Composition/Information on Ingredient

Substance Name CAS # SARA 313 EC no Annex I Index
Number
CALCION 3810-39-7 No 223-283-4


Formula C30H20N4O22S6.6Na
Synonyms



Section 3 - Hazards Identification

Emergency Overview
Irritant.
Irritating to eyes, respiratory system and skin.

For additional information on toxicity, please refer to Section 11.

Section 4 - First Aid Measures

Oral Exposure
If swallowed, wash out mouth with water provided person is conscious. Call a physician.

Inhalation Exposure
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.

Dermal Exposure
In case of contact, immediately wash skin with soap and copious amounts of water.

Eye Exposure
In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.

Section 5 - Fire Fighting Measures

Autoignition Temp: N/A
Extinguishing Media
Suitable
Water spray. Carbon dioxide, dry chemical powder, or appropriate foam.

Firefighting
Protective Equipment
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s)
Emits toxic fumes under fire conditions.

Exposure Hazard(s)
Material
Irritant.


Section 6 - Accidental Release Measures

Procedure(s) of Personal Precaution(s)
Wear respirator, chemical safety goggles, rubber boots, and heavy rubber gloves.

Methods for Cleaning Up
Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is
complete.

Section 7 - Handling and Storage

Handling
User Exposure
Do not breathe dust. Avoid contact with eyes, skin, and clothing.

Storage
Suitable
Keep tightly closed. Store in a cool dry place.



Section 8 - Exposure Controls / PPE

Engineering Controls
Safety shower and eye bath. Mechanical exhaust required.

Personal Protective Equipment
Respiratory
Government approved respirator.
Hand
Compatible chemical-resistant gloves.
Eye
Chemical safety goggles.

General Hygiene Measures
Wash contaminated clothing before reuse. Wash thoroughly after handling.



Section 9 - Physical/Chemical Properties

Appearance

Molecular Weight: 1,112.78 AMU

N/A
pH
N/A
BP/BP Range
N/A
MP/MP Range

Aldrich Chemical - R750344 Sigma-Aldrich Corporation
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 Freezing Point N/A
Vapor Pressure N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
SG/Density N/A
Bulk Density N/A
Odor Threshold N/A
Volatile% N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Partition Coefficient N/A
Decomposition Temp. N/A
Flash Point ??F N/A
Flash Point ??C N/A
Explosion Limits N/A

Flammability N/A
Autoignition Temp N/A
Solubility N/A

N/A = not available

Section 10 - Stability and Reactivity

Stability
Materials to Avoid
Strong oxidizing agents.

Hazardous Decomposition Products
Hazardous Decomposition Products
Carbon monoxide, Carbon dioxide, Nitrogen oxides, Sulfur oxides .


Section 11 - Toxicological Information

Route of Exposure
Inhalation
Material is irritating to mucous membranes and upper respiratory tract.
Multiple Routes
May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation.

Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

RTECS Number: N/A

Section 12 - Ecological Information

No data available.

Section 13 - Disposal Considerations

Appropriate Method of Disposal of Substance or Preparation
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Observe all federal, state, and local environmental regulations.




Aldrich Chemical - R750344 Sigma-Aldrich Corporation
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Section 14 - Transport Information

DOT
Proper Shipping Name: None
Non-Hazardous for Transport: This substance is considered to be non-hazardous for transport.

IATA
Non-Hazardous for Air Transport: Non-hazardous for air transport.

Section 15 - Regulatory Information

EU Additional Classification
Symbol of Danger: Xi
Indication of Danger
Irritant.
Risk Statements R: 36/37/38
Irritating to eyes, respiratory system and skin.
Safety Statements S: 26 36
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

US Classification and Label Text
Indication of Danger
Irritant.
Risk Statements
Irritating to eyes, respiratory system and skin.
Safety Statements
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing.

United States Regulatory Information
SARA Listed: No

Canada Regulatory Information
WHMIS Classification
This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the information
required by the CPR.
DSL: No
NDSL: Yes

Section 16 - Other Information

Disclaimer
For R&D use only. Not for drug, household or other uses.

Warranty
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate
safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Inc., shall not be held liable for
any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional
terms and conditions of sale. Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited paper copies for internal use only.




Aldrich Chemical - R750344 Sigma-Aldrich Corporation
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CALCICHROME