USD $15.00-50.00 / Kilogram
USD $15.00-50.00 / Kilogram
USD $15.00-50.00 / Kilogram
USD $1.00-10.00 / Kilogram
USD $15.00-50.00 / Kilogram
USD $1.00-10.00 / Kilogram
USD $15.00-50.00 / Kilogram
USD $15.00-50.00 / Kilogram
USD $15.00-50.00 / Kilogram
high quality ,low price
1,4-dioxane basic information |
1,4-dioxane basic information |
1,4-dioxane chemical properties |
mp | 12 °c |
bp | 101 °c |
density | 1.500 g/ml at 25 °c |
vapor density | 3 (vs air) |
vapor pressure | 27 mm hg ( 20 °c) |
refractive index |
n |
fp | 54 °f |
storage temp. | flammables area |
water solubility | soluble |
sensitive | hygroscopic |
merck | 14,3300 |
brn | 102551 |
stability: | stable. incompatible with oxidizing agents, oxygen, halogens, reducing agents, moisture. highly flammable - note wide explosive range. may form explosive peroxides in storage (rate of formation increased by heating, evaporation or exposure to light). |
cas database reference | 123-91-1(cas database reference) |
nist chemistry reference | 1,4-dioxane(123-91-1) |
epa substance registry system | 1,4-dioxane(123-91-1) |
safety information |
hazard codes | xn,f,t |
risk statements | 45-46-11-36/38-48/23/24/25-65-66-40-36/37-19-41-37/38-39/23/24/25-23/24/25-48/20/22-38-22-36/37/38-10 |
safety statements | 9-16-36/37-46-45-53-7-62-26-24/25-23-s9-s46-s36/37-s16 |
ridadr | un 1993 3/pg 2 |
wgk germany | 3 |
rtecs | jg8225000 |
f | 8 |
hazardclass | 3 |
packinggroup | ii |
hazardous substances data | 123-91-1(hazardous substances data) |
msds information |
provider | language |
---|---|
sigmaaldrich | english |
acros | english |
alfa | english |
1,4-dioxane usage and synthesis |
chemical properties | colourless liquid |
usage | suitable for hplc, spectrophotometry, environmental testing |
general description | a clear colorless liquid with a faint ethereal odor. flash point 55°f. slightly denser than water and soluble in water. vapors heavier than air. susceptible to autooxidation to form peroxides. |
air & water reactions | highly flammable. when exposed to air 1,4-dioxane undergoes autooxidation with formation of peroxides. in the distillation process peroxides will concentrate causing violent explosion. water soluble. |
reactivity profile | 1,4-dioxane is a flammable liquid; when exposed to air 1,4-dioxane undergoes autooxidation with formation of peroxides. in the distillation process peroxides will concentrate causing violent explosion. the addition complex with sulfur trioxide (1:1) sometimes decomposes violently on storing at room temperature [sisler, h. h. et al., inorg. synth., 1947, 2, p. 174]. evaporation of boron trifluoride in aqueous 1,4-dioxane with nitric acid led to an explosion upon addition of perchloric acid [mca guide, 1972, p. 312]. explosive reaction with raney nickel catalyst above 210° c {mozingo r., org. synth., 1955, coll. vol. 3, p. 182]. |
health hazard | no significant irritation from brief exposure of skin; prolonged or repeated exposure may cause a rash or burn and absorption of toxic amounts leading to serious injury of liver and kidney. chemical has poor warning properties; illness may be delayed. moderately irritating to eyes; overexposure may cause corneal injury. |
1,4-dioxane preparation products and raw materials |