1. introduction of 1,5-naphthalene diisocyanate
1,5-naphthalene diisocyanate is also called 1,5-naphthylene di-isocyanate ; 1,5-diisocyanatonaphthalene ; 1,5-naphthyl diisocyanate ; 1,5-naphthylene diisocyanate ; 4-13-00-00342 (beilstein handbook reference) ; brn 2212353 ; ccris 8920 ; einecs 221-641-4 ; nsc 240728 ; isocyanic acid, 1,5-naphthylene ester ; naphthalene, 1,5-diisocyanato- ; 1,5-naphthalene diisocyanate [diisocyanates]. the iupac name of 1,5-naphthalene diisocyanate is 1,5-diisocyanatonaphthalene.
2. properties of 1,5-naphthalene diisocyanate
melting point: 130°c
polar surface area: 58.86 å2
index of refraction: 1.618
molar refractivity: 60.56 cm3
molar volume: 172.7 cm3
surface tension: 49.8 dyne/cm
density: 1.21 g/cm3
flash point: 128.6 °c
enthalpy of vaporization: 55.59 kj/mol
boiling point: 314.7 °c at 760 mmhg
vapour pressure: 0.000459 mmhg at 25°c
classification code: tumor data
3. toxicity of 1,5-naphthalene diisocyanate
organism |
test type |
route |
reported dose (normalized dose) |
effect |
source |
rat |
lc50 |
inhalation |
270mg/m3/4h (270mg/m3) |
lungs, thorax, or respiration: dyspnea
lungs, thorax, or respiration: cyanosis |
national technical information service. vol. ots0572846, |
4. safety information of 1,5-naphthalene diisocyanate
a powerful allergen. an irritant. questionable carcinogen. when heated to decomposition it emits toxic fumes of nox. see also isocyanates.
hazard codes of 1,5-naphthalene diisocyanate (cas no.3173-72-6): xn
risk statements: 20-36/37/38-42-52/53
r20: harmful by inhalation.
r36/37/38: irritating to eyes, respiratory system and skin.
r42: may cause sensitization by inhalation.
r52/53: harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
safety statements: 26-28-38-45-61
s26: in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
s28: after contact with skin, wash immediately with plenty of soap-suds.
s38: in case of insufficient ventilation, wear suitable respiratory equipment.
s45: in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
s61: avoid release to the environment. refer to special instructions / safety data sheets.
ridadr: 2206
rtecs: nq9600000
hazardclass: 6.1(b)
packinggroup: iii
5. use of 1,5-naphthalene diisocyanate
1,5-naphthalene diisocyanate is used as intermediate.
6. other details of 1,5-naphthalene diisocyanate
1,5-naphthalene diisocyanate should be keep away from heat, sparks, and flame. keep away from sources of ignition. and stored in a cool, dry, well-ventilated area away from incompatible substances. store protected from moisture.