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methyl formate basic information |
product name: | methyl formate |
synonyms: | formiate de methyle;formiatedemethyle;formiatedemethyle(french);hcooch3;methyl ester of formic acid;methyle(formiatede);methyle(formiatede)(french);methylester kyseliny mravenci |
cas: | 107-31-3 |
mf: | c2h4o2 |
mw: | 60.05 |
einecs: | 203-481-7 |
product categories: | refrigerants;organics;analytical chemistry;solvents for hplc & spectrophotometry;solvents for spectrophotometry;fatty acid methyl esters (gc standard);standard materials for gc;anhydrous solvents;solvent bottles;solvent by application;solvent packaging options;solvents;sure/seal bottles;amber glass bottles;nmr;spectrophotometric grade;spectrophotometric solvents;spectroscopy solvents (ir;uv/vis);building blocks;c2 to c5;carbonyl compounds;chemical synthesis;esters;organic building blocks;acs and reagent grade solvents;carbon steel cans with npt threads;reagent;reagent grade solvents;semi-bulk solvents;pharm intermediate |
mol file: | 107-31-3.mol |
methyl formate chemical properties |
mp | -100 °c |
bp | 32-34 °c(lit.) |
density | 0.974 g/ml at 20 °c(lit.) |
vapor density | 2.1 (vs air) |
vapor pressure | 32.91 psi ( 55 °c) |
refractive index |
n |
fp | −16 °f |
storage temp. | flammables area |
water solubility | 300 g/l (20 ºc) |
merck | 14,6077 |
brn | 1734623 |
stability: | stable. extremely flammable. readily forms explosive mixtures with air. note low flash point and very wide explosion limits. incompatible with oxidizing agents. |
cas database reference | 107-31-3(cas database reference) |
nist chemistry reference | methyl formate(107-31-3) |
epa substance registry system | formic acid, methyl ester(107-31-3) |
safety information |
hazard codes | f+,xn |
risk statements | 12-20/22-36/37 |
safety statements | 9-16-24-26-33 |
ridadr | un 1243 3/pg 1 |
wgk germany | 1 |
rtecs | lq8925000 |
hazardclass | 3 |
packinggroup | i |
hazardous substances data | 107-31-3(hazardous substances data) |
msds information |
provider | language |
---|---|
sigmaaldrich | english |
acros | english |
alfa | english |
methyl formate usage and synthesis |
chemical properties | colourless liquid |
general description | a clear colorless liquid with an agreeable odor. flash point -27°f. less dense than water vapors heavier than air. |
air & water reactions | highly flammable. water soluble. reacts slowly with water to give formic acid, a corrosive material, and methanol, a flammable liquid. both products are dissolved in the water. |
reactivity profile | methyl formate reacts with acids to liberate heat along with alcohols and acids. strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. heat is also generated with caustic solutions. flammable hydrogen is generated by mixing with alkali metals and hydrides. |
health hazard | inhalation causes irritation of mucous membranes. prolonged inhalation can produce narcosis and central nervous symptoms, including some temporary visual disturbance. contact with liquid irritates eyes and may irritate skin if allowed to remain. ingestion causes irritation of mouth and stomach and central nervous system depression, including visual disturbances. |
fire hazard | behavior in fire: vapor is heavier than air and may travel considerable distance to a source of ignition and flash back. |
methyl formate preparation products and raw materials |
methyl formate basic information |
product name: | methyl formate |
synonyms: | formiate de methyle;formiatedemethyle;formiatedemethyle(french);hcooch3;methyl ester of formic acid;methyle(formiatede);methyle(formiatede)(french);methylester kyseliny mravenci |
cas: | 107-31-3 |
mf: | c2h4o2 |
mw: | 60.05 |
einecs: | 203-481-7 |
product categories: | refrigerants;organics;analytical chemistry;solvents for hplc & spectrophotometry;solvents for spectrophotometry;fatty acid methyl esters (gc standard);standard materials for gc;anhydrous solvents;solvent bottles;solvent by application;solvent packaging options;solvents;sure/seal bottles;amber glass bottles;nmr;spectrophotometric grade;spectrophotometric solvents;spectroscopy solvents (ir;uv/vis);building blocks;c2 to c5;carbonyl compounds;chemical synthesis;esters;organic building blocks;acs and reagent grade solvents;carbon steel cans with npt threads;reagent;reagent grade solvents;semi-bulk solvents;pharm intermediate |
mol file: | 107-31-3.mol |
methyl formate chemical properties |
mp | -100 °c |
bp | 32-34 °c(lit.) |
density | 0.974 g/ml at 20 °c(lit.) |
vapor density | 2.1 (vs air) |
vapor pressure | 32.91 psi ( 55 °c) |
refractive index |
n |
fp | −16 °f |
storage temp. | flammables area |
water solubility | 300 g/l (20 ºc) |
merck | 14,6077 |
brn | 1734623 |
stability: | stable. extremely flammable. readily forms explosive mixtures with air. note low flash point and very wide explosion limits. incompatible with oxidizing agents. |
cas database reference | 107-31-3(cas database reference) |
nist chemistry reference | methyl formate(107-31-3) |
epa substance registry system | formic acid, methyl ester(107-31-3) |
safety information |
hazard codes | f+,xn |
risk statements | 12-20/22-36/37 |
safety statements | 9-16-24-26-33 |
ridadr | un 1243 3/pg 1 |
wgk germany | 1 |
rtecs | lq8925000 |
hazardclass | 3 |
packinggroup | i |
hazardous substances data | 107-31-3(hazardous substances data) |
msds information |
provider | language |
---|---|
sigmaaldrich | english |
acros | english |
alfa | english |
methyl formate usage and synthesis |
chemical properties | colourless liquid |
general description | a clear colorless liquid with an agreeable odor. flash point -27°f. less dense than water vapors heavier than air. |
air & water reactions | highly flammable. water soluble. reacts slowly with water to give formic acid, a corrosive material, and methanol, a flammable liquid. both products are dissolved in the water. |
reactivity profile | methyl formate reacts with acids to liberate heat along with alcohols and acids. strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. heat is also generated with caustic solutions. flammable hydrogen is generated by mixing with alkali metals and hydrides. |
health hazard | inhalation causes irritation of mucous membranes. prolonged inhalation can produce narcosis and central nervous symptoms, including some temporary visual disturbance. contact with liquid irritates eyes and may irritate skin if allowed to remain. ingestion causes irritation of mouth and stomach and central nervous system depression, including visual disturbances. |
fire hazard | behavior in fire: vapor is heavier than air and may travel considerable distance to a source of ignition and flash back. |
methyl formate preparation products and raw materials |