1-oxa-4-azacyclohexane basic information |
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1-oxa-4-azacyclohexane chemical properties |
mp |
-5 °c |
bp |
129 °c(lit.) |
density |
1.000 g/ml at 20 °c |
vapor density |
3 (vs air) |
vapor pressure |
31 mm hg ( 38 °c) |
refractive index |
n20/d 1.454(lit.) |
fp |
96 °f |
storage temp. |
store at r.t. |
water solubility |
miscible |
freezingpoint |
-4.9℃ |
sensitive |
hygroscopic |
merck |
14,6277 |
brn |
102549 |
stability: |
stable. flammable. incompatible with strong oxidizing agents, strong acids, acid chlorides, acid anhydrides. hygroscopic. |
cas database reference |
110-91-8(cas database reference) |
nist chemistry reference |
morpholine(110-91-8) |
epa substance registry system |
morpholine(110-91-8) |
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1-oxa-4-azacyclohexane usage and synthesis |
chemical properties |
yellow liquid |
general description |
an aqueous solution with a fishlike odor. corrosive to tissue and moderately toxic by ingestion and inhalation. |
air & water reactions |
highly flammable. water soluble. |
reactivity profile |
morpholine dissolved in water neutralizes acids in exothermic reactions to form salts plus water. may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. |
health hazard |
may cause toxic effects if inhaled or ingested/swallowed. contact with substance may cause severe burns to skin and eyes. fire will produce irritating, corrosive and/or toxic gases. vapors may cause dizziness or suffocation. runoff from fire control or dilution water may cause pollution. |
fire hazard |
flammable/combustible material. may be ignited by heat, sparks or flames. vapors may form explosive mixtures with air. vapors may travel to source of ignition and flash back. most vapors are heavier than air. they will spread along ground and collect in low or confined areas (sewers, basements, tanks). vapor explosion hazard indoors, outdoors or in sewers. runoff to sewer may create fire or explosion hazard. containers may explode when heated. many liquids are lighter than water. |
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1-oxa-4-azacyclohexane preparation products and raw materials |
raw materials |
sodium hydroxide-->sulfuric acid -->ammonia-->1,4-dioxane-->hydrogen-->4-chlorobenzaldehyde-->2,2'-iminodiethanol-->diethylene glycol |
preparation products |
3-morpholinobenzaldehyde-->3-morpholinophenol-->2-(chloromethyl)-5-methylthieno[2,3-d]pyrimidin-4(3h)-one-->morpholin-4-yl-acetic acid-->4-methylmorpholine n-oxide monohydrate-->4-morpholinophenylboronic acid-->4-(3-morpholinopropoxy)-3,5-dichlorobenzenamine-->1-[2-(morpholin-4-yl)-ethyl]-piperazine-->4-(morpholinomethyl)aniline-->morpholine-4-carbothioamide-->4-(morpholine-4-sulfonyl)-phenylamine-->2-(morpholinothio)benzothiazole-->ethyl 3-pyridylacetate-->2-morpholin-4-yl-pyrimidine-5-carbaldehyde-->2-morpholinobenzoic acid-->methyl 3-(morpholinomethyl)benzoate ,98%-->6-morpholinonicotinonitrile-->6-morpholinonicotinohydrazide-->4-(2-morpholinoethoxy)-3,5-dichlorobenzenamine-->4-bromophenethyl alcohol-->2-amino-6-methyl-4,5,6,7-tetrahydro-benzo[b]thiophene-3-carboxylic acid ethyl ester-->2-chloro-3-(4-morpholinyl)quinoxaline-->4-morpholinobenzylamine-->ethyl 2-amino-4-methylthiophene-3-carboxylate-->1-(4-amino-2,6-dichlorophenoxy)-3-morpholinopropan-2-ol-->(6-morpholino-3-pyridinyl)methanol-->3-amino-6-morpholinopyridine-->6-morpholinonicotinoyl chloride-->2-(morpholine-4-carbonyl)-benzoic acid-->2-amino-1-morpholin-4-yl-ethanone hcl-->5-bromo-2-(morpholin-4-yl)pyrimidine-->6-morpholinonicotinaldehyde-->4-(5-nitropyridin-2-yl)morpholine-->n-formylmorpholine-->6-morpholinonicotinic acid-->2-morpholin-4-yl-isonicotinic acid-->4-morpholinecarboxamidine-->adefovir dipivoxil-->4-acryloylmorpholine |
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