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2-Methylbutane competitive product CAS NO.78-78-4

FOB Price:
USD 0.10-0.10 /Kilogram Get Latest Price
Min.Order Quantity:
1 Kilogram
Purity:
99%
Port:
Shanghai
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Quick Details

  • ProName: 2-Methylbutane competitive product
  • CasNo: 78-78-4
  • Molecular Formula: C5H12
  • Appearance: according to email quotation
  • Application: pharmaceutical raw materials
  • DeliveryTime: Within 3 days after payment
  • PackAge: foil aluminium bag/vacuum packing
  • Port: Shanghai
  • ProductionCapacity: 100 Kilogram/Week
  • Purity: 99%
  • Storage: Keep in dry and cool condition
  • Transportation: by air or by sea
  • LimitNum: 1 Kilogram
  • CAS No.: 78-78-4
  • Synonyms: 1,1,2-Trimethylethane;
  • Formula: C5H12
  • Molecular Weight: 72.15

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Details

2-Methylbutane Chemical Properties
Melting point -160 °C
Boiling point 30 °C(lit.)
density 0.62 g/mL at 25 °C(lit.)
vapor density 2.6 (vs air)
vapor pressure 11.17 psi ( 20 °C)
refractive index n20/D 1.354(lit.)
Fp −51 °C
storage temp. 2-8°C
solubility 0.048g/l
form Liquid
pka >14 (Schwarzenbach et al., 1993)
color Clear colorless
explosive limit 1.3-7.6%(V)
Water Solubility Miscible with water, hydrocarbons, oils, alcohol and ether.
λmax λ: 192 nm Amax: 1.00
λ: 210 nm Amax: 0.30
λ: 220 nm Amax: 0.07
λ: 240-400 nm Amax: 0.01
BRN 1730723
Henry's Law Constant (atm m3/mol): 1.24 at 25 °C (approximate - calculated from water solubility and vapor pressure)
Exposure limits ACGIH TLV: TWA 600 ppm (adopted).
Stability: Stable. Extremely flammable. Incompatible with strong oxidizing agents. Vapour-air mixtures explosive in certain proportions. Incompatible with rubber, various plastics. The vapour, being heavier than air, may roll over surfaces and collect in low points. Note low flash point.
CAS DataBase Reference 78-78-4(CAS DataBase Reference)
NIST Chemistry Reference Butane, 2-methyl-(78-78-4)
EPA Substance Registry System Butane, 2-methyl-(78-78-4)
Safety Information
Hazard Codes F+,Xn,N
Risk Statements 12-51/53-65-66-67
Safety Statements 9-16-29-33-61-62
RIDADR UN 1265 3/PG 1
WGK Germany 2
RTECS EK4430000
Autoignition Temperature 788 °F
TSCA Yes
HazardClass 3
PackingGroup I
HS Code 29011000
Hazardous Substances Data 78-78-4(Hazardous Substances Data)
MSDS Information
Provider Language
ACROS English
SigmaAldrich English
ALFA English
2-Methylbutane Usage And Synthesis
Chemical Properties colourless liquid with a characteristic smell
Physical properties Clear, colorless, watery, very flammable liquid with a pleasant odor. Evaporates quickly when spilled. An odor threshold concentration of 1.3 ppmv was reported by Nagata and Takeuchi (1990).
Uses Solvent, manufacture of chlorinated derivatives, blowing agent for polystyrene.
Definition ChEBI: An alkane that is butane substituted by a methyl group at position 2.
General Description Watery colorless liquid with a gasoline-like odor. Floats on water. Flammable, irritating vapor is produced. Boiling point is 82°F.
Air & Water Reactions Highly flammable. Insoluble in water.
Reactivity Profile 2-Methylbutane is a fire and explosion hazard when in contact with oxidizing agents. .
Hazard Highly flammable, dangerous fire risk.
Health Hazard Inhalation causes irritation of respiratory tract, cough, mild depression, irregular heartbeat. Aspiration causes severe lung irritation, coughing, pulmonary edema; excitement followed by depression. Ingestion causes nausea, vomiting, swelling of abdomen, headache, depression.
Fire Hazard Behavior in Fire: Highly volatile liquid. Vapors may explode when mixed with air.
Safety Profile Mddly toxic and narcotic by inhalation. See also PENTANE. Flammable liquid. A very dangerous fire and explosion hazard when exposed to heat, flame, or oxidzers. Keep away from sparks, heat, or open flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
Source A constituent in gasoline. Harley et al. (2000) analyzed the headspace vapors of three grades of unleaded gasoline where ethanol was added to replace methyl tert-butyl ether. The gasoline vapor concentrations of 2-methylbutane in the headspace were 24.1 wt % for regular grade, 24.8 wt % for mid-grade, and 26.0 wt % for premium grade.
Schauer et al. (2001) measured organic compound emission rates for volatile organic compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds from the residential (fireplace) combustion of pine, oak, and eucalyptus. The gas-phase emission rate of 2-methylbutane was 5.6 mg/kg of pine burned. Emission rates of 2-methylbutane were not measured during the combustion of oak and eucalyptus.
California Phase II reformulated gasoline contained 2-methylbutane at a concentration of 79.2g/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic converters were 3.69 and 148 μg/km, respectively (Schauer et al., 2002).
Environmental fate Photolytic. When synthetic air containing gaseous nitrous acid and 2-methylbutane was exposed to artificial sunlight (λ = 300–450 nm), acetone, acetaldehyde, methyl nitrate, peroxy-acetal nitrate, propyl nitrate, and pentyl nitrate were formed (Cox et al., 1980).
Based upon a photooxidation rate constant of 3.90 x 10-12 cm3/molecule sec with OH radicals in summer daylight, the atmospheric lifetime is 36 h (Altshuller, 1991). At atmospheric pressure and 300 K, Darnall et al. (1978) reported a rate constant of 3.78 x 10-12cm3/molecule sec for the same reaction.
Cox et al. (1980) reported a rate constant of 5.0 x 10-11 cm3/molecule sec for the reaction of gaseous 2-methylbutane with OH radicals based on a value of 8 x 10-12 cm3/molecule sec for the reaction of ethylene with OH radicals.
Chemical/Physical. Complete combustion in air produces carbon dioxide and water vapor.
2-Methylbutane will not hydrolyze because it does not contain a hydrolyzable functional group.
Purification Methods Stir isopentane for several hours in the cold with conc H2SO4 (to remove olefinic impurities), then wash it with H2O, aqueous Na2CO3 and H2O again. Dry it with MgSO4 and fractionally distil it using a Todd column packed with glass helices. Material transparent down to 180nm is obtained by distilling from sodium wire, and passing through a column of silica gel which had previously been dried in place at 350o for 12hours before use. [Potts J Phys Chem 20 809 1952, Beilstein 1 IV 320.]
2-Methylbutane Preparation Products And Raw materials
Preparation Products Isoprene-->Amobarbital-->CYCLOPENTANE
Raw materials Sodium-->Silica gel-->Pentane-->Naphthalene-->Dehydrolyzing agent
Tag:2-Methylbutane(78-78-4) Related Product Information

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