Allylboronic acid pinacol ester CAS NO.72824-04-5

product information

allylboronic acid pinacol ester basic information

product name:	allylboronic acid pinacol ester
synonyms:	pinacol allylboronate;2-allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;allylboronic acid, pinacol cyclic ester;allylboronic acid pinacol ester;akos brn-1082;allboronic acid,pinacol cyclic ester;allylboronic acid piracol ester;allylboronic acid pinacol ester, 98+%
cas:	72824-04-5
mf:	c9h17bo2
mw:	168.04
einecs:	-0
product categories:	olefin;organoborons;b (classes of boron compounds);boronic acids esters;chiral chemicals;alkyl boronate esters;boronate esters;boronic acids and derivatives;chemical synthesis;organometallic reagents
mol file:	72824-04-5.mol

allylboronic acid pinacol ester chemical properties

bp	50-53 °c5 mm hg(lit.)
density	0.896 g/ml at 25 °c(lit.)
refractive index	n20/d 1.4268(lit.)
fp	115 °f
storage temp.	refrigerator
brn	4244068
cas database reference	72824-04-5(cas database reference)

safety information

hazard codes	xi
risk statements	10-36/37/38
safety statements	26-36
ridadr	un 1993 3/pg 3
wgk germany	3
hazard note	irritant
hazardclass	3
packinggroup	iii
hs code	29310095

msds information

provider	language
2-allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane	english
sigmaaldrich	english
alfa	english

allylboronic acid pinacol ester usage and synthesis

chemical properties

clear corless liquid

usage

reagent used for• ;palladium-catalyzed suzuki-miyaura cross-coupling reactions and olefin metathesis1 • ;intermolecular radical additions2 • ;allylboration of aldehydes catalyzed by chiral spirobiindane diol (spinol) based phosphoric acids3 • ;cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes4 • ;nucleic acid-templated energy transfer leading to a photorelease reaction5 • ;stereoselective indium-catalyzed hosomi-sakurai reactions6 reagent used in preparation of• ;cyclic sulfone hydroxyethylamines as bace1 inhibitors for reduction o

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