benzoyl peroxide physicochemical properties
density 1.3±0.1 g/cm3
boiling point 349.7±25.0 °c at 760 mmhg
melting point 105 °c (lit.)
molecular formula c14h10o4
molecular weight 242.227
flash point 154.2±23.2 °c
exact quality 242.057907
psa 52.60000
logp 3.47
appearance traits white powder or transparent solution
vapor pressure 0.0±0.8 mmhg at 25°c
refractive index 1.585
storage conditions
storage precautions store water with a stabilizer, typically 30% water. the temperature should be kept at 2~25°c. should be stored separately with reducing agents, acids, alkalis, alcohols, avoid mixing. it should not be stored for a long time to avoid deterioration. explosion-proof lighting and ventilation facilities are used. it is forbidden to use mechanical equipment and tools that are prone to sparks. the storage area should be provided with suitable materials to contain spills. vibration, impact and friction are prohibited.
stability
1. irritating to the upper respiratory tract. it has a strong, irritating and sensitizing effect on the skin. into the eye can cause damage. flammable, explosive, strong irritant, allergenic.
2. stability is unstable
3. incompatible materials strong reducing agents, acids, bases, alcohols
4. conditions to avoid contact heat, light, friction, vibration
5. polymerization hazard does not polymerize
6. decomposition products carbon dioxide, benzoic acid, benzene, phenyl benzoate
water solubility insoluble
molecular structure
1, molar refractive index: 64.73
2. molar volume (cm3/mol): 193.1
3, isotonic capacity (90.2k): 512.5
4. surface tension (dyne/cm): 49.6
5. polarization rate (10-24cm3): 25.66
computing chemistry
1. hydrophobic parameter calculation reference value (xlogp): 3.5
2. number of hydrogen bond donors: 0
3. number of hydrogen bond acceptors: 4
4. number of rotatable chemical bonds: 5
5. number of tautomers: none
6. topological molecular polarity surface area 52.6
7. number of heavy atoms: 18
8. surface charge: 0
9. complexity: 258
10. number of isotope atoms: 0
11. determine the number of atomic stereocenters: 0
12. uncertainty of the number of atomic stereocenters: 0
13. determine the number of chemical bond stereocenters: 0
14. uncertain chemical bond number of stereocenters: 0
15. number of covalent bond units: 1
more
1. traits: white or light yellow fine particles, slightly bitter almond smell.
2. melting point (oc): 103~108
3. boiling point (oc): decomposition (explosion)
4. relative density (water = 1): 1.33
5. heat of combustion (kj/mol): -6855.2
6. critical pressure (mpa): 2.57
7. octanol / water partition coefficient: 3.46
8. flash point (oc): 80
9. ignition temperature (oc): 80
10. solubility: insoluble in water, slightly soluble in alcohol, soluble in acetone, benzene, carbon disulfide, chloroform, etc.
11. gas phase standard combustion heat (焓) (kj·mol-1): -6666.6
12. the gas phase standard claims heat (焓) (kj·mol-1): -271.7
13. crystal phase phase standard heat of combustion (焓) (kj·mol-1): -6568.7
14. the crystal phase standard claims heat (焓) (kj·mol-1): -369.6