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tetraethyl orthosilicate basic information |
product name: | tetraethyl orthosilicate |
synonyms: | silicon tetraethoxide;teos;tetraethoxysilane;tetraethyl silicate;tetraethyl orthosilicate;orthosilicic acid tetraethyl ester;ethyl-o-silicate;ethyl orthosilicate |
cas: | 78-10-4 |
mf: | c8h20o4si |
mw: | 208.33 |
einecs: | 201-083-8 |
product categories: | si (classes of silicon compounds);si-o compounds;tetraalkoxysilanes;crosslinkers;crosslinking agents;orthosilicate;organosilicon compounds;14: silicon;cvd and ald precursors packaged for deposition systems;materials science;micro &;micro/nanoelectronics;nanoelectronics;new products for materials research and engineering;vapor deposition precursors;inorganic binder for refactory fillers |
mol file: | 78-10-4.mol |
tetraethyl orthosilicate chemical properties |
mp | -77 °c |
bp | 168 °c(lit.) |
density | 0.94 |
vapor density | 7.2 (vs air) |
vapor pressure | <1 mm hg ( 20 °c) |
refractive index |
n |
fp | 116 °f |
storage temp. | flammables area |
water solubility | hydrolysis |
freezingpoint | -77℃ |
sensitive | moisture sensitive |
merck | 14,3851 |
brn | 1422225 |
stability: | stable. flammable. incompatible with strong oxidizing agents, water, alkalies, mineral acids. |
cas database reference | 78-10-4(cas database reference) |
nist chemistry reference | silicic acid (h4sio4), tetraethyl ester(78-10-4) |
epa substance registry system | silicic acid (h4sio4), tetraethyl ester(78-10-4) |
safety information |
hazard codes | xn |
risk statements | 10-20-36/37-36/37/38 |
safety statements | 16-36/37/39-26 |
ridadr | un 1292 3/pg 3 |
wgk germany | 1 |
rtecs | vv9450000 |
tsca | yes |
hazardclass | 3 |
packinggroup | iii |
hazardous substances data | 78-10-4(hazardous substances data) |
msds information |
provider | language |
---|---|
acros | english |
sigmaaldrich | english |
alfa | english |
tetraethyl orthosilicate usage and synthesis |
chemical properties | colorless transparent liquid |
usage | commonly used as a precursor to prepare xerogel1,2 |
usage | tetraethyl orthosilicate is used in the preparation of antidreflective coatings on silicate glass via silicon dioxide. crosslinking reagent. |
general description | a clear colorless liquid with a faint odor. flash point 125°f. less dense than water. vapors are heavier than air. |
air & water reactions | flammable. practically insoluble in water. reacts slowly with water to form silica and ethyl alcohol [merck]. |
reactivity profile | tetraethyl orthosilicate reacts exothermically with acids strong oxidizing acids may cause a reaction that is sufficiently exothermic to ignite the reaction products. may generate with caustic solutions. may generate flammable hydrogen with alkali metals and hydrides. |
health hazard | inhalation of vapor causes eye and nose irritation, unsteadiness, tremors, salivation, respiratory difficulty, and unconsciousness. contact with liquid irritates eyes and may cause dryness, cracking, and inflammation of skin. ingestion may produce nausea, vomiting, and cramps. |
fire hazard | highly flammable: will be easily ignited by heat, sparks or flames. vapors may form explosive mixtures with air. vapors may travel to source of ignition and flash back. most vapors are heavier than air. they will spread along ground and collect in low or confined areas (sewers, basements, tanks). vapor explosion hazard indoors, outdoors or in sewers. runoff to sewer may create fire or explosion hazard. containers may explode when heated. many liquids are lighter than water. |
tetraethyl orthosilicate preparation products and raw materials |
raw materials | tetrachlorosilane |
preparation products | photosensitive polyimide/sio2 hybrid mate materials-->phenyltriethoxysilane-->methyl block rtv silicone rubber adhesive qd-200 sersies |
tetraethyl orthosilicate basic information |
product name: | tetraethyl orthosilicate |
synonyms: | silicon tetraethoxide;teos;tetraethoxysilane;tetraethyl silicate;tetraethyl orthosilicate;orthosilicic acid tetraethyl ester;ethyl-o-silicate;ethyl orthosilicate |
cas: | 78-10-4 |
mf: | c8h20o4si |
mw: | 208.33 |
einecs: | 201-083-8 |
product categories: | si (classes of silicon compounds);si-o compounds;tetraalkoxysilanes;crosslinkers;crosslinking agents;orthosilicate;organosilicon compounds;14: silicon;cvd and ald precursors packaged for deposition systems;materials science;micro &;micro/nanoelectronics;nanoelectronics;new products for materials research and engineering;vapor deposition precursors;inorganic binder for refactory fillers |
mol file: | 78-10-4.mol |
tetraethyl orthosilicate chemical properties |
mp | -77 °c |
bp | 168 °c(lit.) |
density | 0.94 |
vapor density | 7.2 (vs air) |
vapor pressure | <1 mm hg ( 20 °c) |
refractive index |
n |
fp | 116 °f |
storage temp. | flammables area |
water solubility | hydrolysis |
freezingpoint | -77℃ |
sensitive | moisture sensitive |
merck | 14,3851 |
brn | 1422225 |
stability: | stable. flammable. incompatible with strong oxidizing agents, water, alkalies, mineral acids. |
cas database reference | 78-10-4(cas database reference) |
nist chemistry reference | silicic acid (h4sio4), tetraethyl ester(78-10-4) |
epa substance registry system | silicic acid (h4sio4), tetraethyl ester(78-10-4) |
safety information |
hazard codes | xn |
risk statements | 10-20-36/37-36/37/38 |
safety statements | 16-36/37/39-26 |
ridadr | un 1292 3/pg 3 |
wgk germany | 1 |
rtecs | vv9450000 |
tsca | yes |
hazardclass | 3 |
packinggroup | iii |
hazardous substances data | 78-10-4(hazardous substances data) |
msds information |
provider | language |
---|---|
acros | english |
sigmaaldrich | english |
alfa | english |
tetraethyl orthosilicate usage and synthesis |
chemical properties | colorless transparent liquid |
usage | commonly used as a precursor to prepare xerogel1,2 |
usage | tetraethyl orthosilicate is used in the preparation of antidreflective coatings on silicate glass via silicon dioxide. crosslinking reagent. |
general description | a clear colorless liquid with a faint odor. flash point 125°f. less dense than water. vapors are heavier than air. |
air & water reactions | flammable. practically insoluble in water. reacts slowly with water to form silica and ethyl alcohol [merck]. |
reactivity profile | tetraethyl orthosilicate reacts exothermically with acids strong oxidizing acids may cause a reaction that is sufficiently exothermic to ignite the reaction products. may generate with caustic solutions. may generate flammable hydrogen with alkali metals and hydrides. |
health hazard | inhalation of vapor causes eye and nose irritation, unsteadiness, tremors, salivation, respiratory difficulty, and unconsciousness. contact with liquid irritates eyes and may cause dryness, cracking, and inflammation of skin. ingestion may produce nausea, vomiting, and cramps. |
fire hazard | highly flammable: will be easily ignited by heat, sparks or flames. vapors may form explosive mixtures with air. vapors may travel to source of ignition and flash back. most vapors are heavier than air. they will spread along ground and collect in low or confined areas (sewers, basements, tanks). vapor explosion hazard indoors, outdoors or in sewers. runoff to sewer may create fire or explosion hazard. containers may explode when heated. many liquids are lighter than water. |
tetraethyl orthosilicate preparation products and raw materials |
raw materials | tetrachlorosilane |
preparation products | photosensitive polyimide/sio2 hybrid mate materials-->phenyltriethoxysilane-->methyl block rtv silicone rubber adhesive qd-200 sersies |