dess-martin periodinane basic information
product name: dess-martin periodinane
synonyms: dess-martin;dess-martin periodinane;dess-martin reagent;desss-martin periodinane;1,1-dihydro-1,1,1-triacetoxy-1,2-benzoiodooxol-3(1h)-one;1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1h)-one;1,1,1-tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1h)-one;acetic acid 1,1-diacetoxy-3-oxo-1l5-ioda-2-oxa-indan-1-yl ester
cas: 87413-09-0
mf: c13h13io8
mw: 424.14
einecs: 200-009-0
product categories: hypervalent iodine compounds;oxidation;synthetic organic chemistry;fused ring systems;hypervalent iodine;synthetic reagents
mol file: 87413-09-0.mol
dess-martin periodinane structure
dess-martin periodinane chemical properties
melting point 130-133 °c(lit.)
boiling point 40 °c
density 1.369 g/ml at 25 °c
fp >221 °f
storage temp. 0-6°c
solubility soluble in chloroform, acetone, acetonitrile and methylene chloride. slightly soluble in ether and hexane.
form liquid
color colorless to light yellow
sensitive light sensitive
merck 14,2933
brn 4548207
inchikey nklcnnuwbjbick-uhfffaoysa-n
cas database reference 87413-09-0(cas database reference)
safety information
hazard codes xn,o,xi
risk statements 22-36/37/38-40-8-20/21/22-44
safety statements 26-36-36/37-24/25-23-17-45-36/37/39
ridadr un 1593 6.1/pg 3
wgk germany 3
hazard note harmful/light sensitive
hazardclass 5.1
packinggroup ⅲ
msds information
provider language
(1,1,1-triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1h)-one english
sigmaaldrich english
acros english
alfa english
dess-martin periodinane usage and synthesis
chemical properties white crystalline powder
uses dess-martin periodinaneis a very usefulreagent used in the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones.
uses oxidizing reagent.
dess-martin periodinane preparation products and raw materials
raw materials acetic acid glacial-->acetic anhydride-->p-toluenesulfonic acid-->potassium bromate -->2-iodobenzoic acid-->2-iodoxybenzoic acid
preparation products c-(3,4-dihydro-2h-benzo[1,4]oxazin-3-yl)-methylamine