1.Identification
1.1 GHS Product identifier
Product name | propene |
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1.2 Other means of identification
Product number | - |
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Other names | 1-Propene |
1.3 Recommended use of the chemical and restrictions on use
Identified uses | For industry use only. Fuels and fuel additives,Functional fluids (closed systems),Intermediates,Laboratory chemicals |
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Uses advised against | no data available |
1.4 Supplier's details
1.5 Emergency phone number
Emergency phone number | - |
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Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
2.Hazard identification
2.1 Classification of the substance or mixture
Gases under pressure: Compressed gas
Flammable gases, Category 1
2.2 GHS label elements, including precautionary statements
Pictogram(s) | |
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Signal word | Danger |
Hazard statement(s) | H220 Extremely flammable gas |
Precautionary statement(s) | |
Prevention | P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. |
Response | P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381 In case of leakage, eliminate all ignition sources. |
Storage | P410+P403 Protect from sunlight. Store in a well-ventilated place. P403 Store in a well-ventilated place. |
Disposal | none |
2.3 Other hazards which do not result in classification
none
3.Composition/information on ingredients
3.1 Substances
Chemical name | Common names and synonyms | CAS number | EC number | Concentration |
---|---|---|---|---|
propene | propene | 115-07-1 | none | 100% |
4.First-aid measures
4.1 Description of necessary first-aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
In case of skin contact
ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention .
In case of eye contact
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms/effects, acute and delayed
Moderate concentration in air causes dizziness, drowsiness, and unconsciousness. Contact with liquefied propylene will cause ``freezing burn.'' (USCG, 1999)
4.3 Indication of immediate medical attention and special treatment needed, if necessary
If splashes of liquid propylene cause freezing of the skin, never rinse the affected area with hot or tepid water. If liquid propylene contacts the eyes flush eyes with water for 15 minutes.
5.Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Do not extinguish fire unless flow can be stopped. If possible use foam, carbon dioxide, or dry chemical to extinguish fire. If none of these compounds are available use water in flooding quantities as a fog, being sure to cool all affected containers. Apply water from as far a distance as possible, and do not use solid streams of water since they may be ineffective. Keep material out of water sources and sewers and build dikes as necessary to contain flow. Wear self contained breathing apparatus, boots, protective gloves and goggles and be sure to wash away any material which may have contacted the body with copious amounts of water or soap and water. Do not handle damaged packages without protective equipment. If fire becomes uncontrollable or a container is exposed to direct flame, evacuate for a radius of 2500 feet. If material leaking (and is not on fire), downwind evacuation must be considered.
5.2 Specific hazards arising from the chemical
Behavior in Fire: Containers may explode. Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back. (USCG, 1999)
5.3 Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
6.Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.
6.2 Environmental precautions
Evacuate danger area! Consult an expert! Ventilation. Remove all ignition sources. NEVER direct water jet on liquid. Personal protection: chemical protection suit including self-contained breathing apparatus.
6.3 Methods and materials for containment and cleaning up
Spills in Water: Contain contaminated water if possible by using natural barriers or oil spill control booms to limit spreading. A universal gelling agent may be applied to solidify trapped mass and to increase effectiveness of the booms. If solubilized, application of activated carbon at 10% spill amount over region occupied by 10 mg/L or greater concentrations is recommended. Spills on Land: Contain if possible by forming mechanical and/or chemical barriers to prevent spreading. Apply universal gelling agent to immobilize spill or use fly ash or cement powder to absorb the liquid. Leaking containers should be removed to an isolated well-ventilated area and if possible, the contents transferred to other suitable containers. Safety goggles, impervious clothing and positive pressure self-contained breathing apparatus should be worn. Plastic or neoprene-coated canvas gloves should be worn when liquid propylene is handled.
7.Handling and storage
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Fireproof. Cool.Protect cylinder against physical damage and from excessive temperature rise by storing away from sources of heat. No part of a cylinder should be subjected to a temperature above 52°C. Store cylinders in an upright position and firmly secured. Segregate full and empty cylinders. Isolate from oxygen and other oxidizers. Avoid exposure to areas where salt or other corrosive chemicals are present. Ground and bond all lines and equipment used with propylene. Do not use near sparking motors or other non explosion proof equipment.
8.Exposure controls/personal protection
8.1 Control parameters
Occupational Exposure limit values
no data available
Biological limit values
no data available
8.2 Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
8.3 Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Respiratory protection
Wear dust mask when handling large quantities.
Thermal hazards
no data available
9.Physical and chemical properties
Physical state | colourless gas |
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Colour | Colorless gas |
Odour | Aromatic |
Melting point/ freezing point | -185oC(lit.) |
Boiling point or initial boiling point and boiling range | -47.7oC(lit.) |
Flammability | Extremely flammable. |
Lower and upper explosion limit / flammability limit | Lower 2.4%, Upper 10.3% by volume in air. |
Flash point | -108oC |
Auto-ignition temperature | 455°C (USCG, 1999) |
Decomposition temperature | no data available |
pH | no data available |
Kinematic viscosity | 83.4 micropoises at 16.7°C |
Solubility | 44.6 mL/100 mL |
Partition coefficient n-octanol/water (log value) | log Kow = 1.77 |
Vapour pressure | 15.4 atm ( 37.7 °C) |
Density and/or relative density | 1.49 |
Relative vapour density | 1.48 (vs air) |
Particle characteristics | no data available |
10.Stability and reactivity
10.1 Reactivity
no data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
DANGEROUS FIRE RISK.The gas is heavier than air and may travel along the ground; distant ignition possible. The gas is heavier than air and may accumulate in lowered spaces causing a deficiency of oxygen. As a result of flow, agitation, etc., electrostatic charges can be generated.During an experiment to produce lactic acid by oxidizing PROPYLENE with nitrogen peroxide, a violent explosion occurred. These mixtures (olefins and nitrogen peroxide) form extremely unstable nitrosates or nitrosites (Comp. Rend. 116:756 1893). Contact of very cold liquid propylene with water may result in vigorous or violent boiling of the product and extremely rapid vaporization due to the large temperature differences involved. If the water is hot, there is the possibility that a liquid "superheat" explosion may occur. Pressures may build to dangerous levels if liquid propylene contacts water in a closed container.
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
Propylene reacts vigorously with oxidizing materials and with nitrogen dioxide (NO2), dinitrogen tetraoxide (N2O4), and dinitrogen oxide (N2O). Furthermore, liquid propylene will explode on contact with water at 42-75°C.
10.6 Hazardous decomposition products
Combustion products of propylene ... include carbon dioxide and carbon monoxide.
11.Toxicological information
Acute toxicity
- Oral: no data available
- Inhalation: LC50 Rat inhalation 570,000 ppm/15 min /Conditions of bioassay not specified in source examined/
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
Evaluation: There is inadequate evidence in humans for the carcinogenicity of propylene. There is inadequate evidence in experimental animals for the carcinogenicity of propylene. Overall evaluation: Propylene is not classifiable as to its carcinogenicity to humans (Group 3).
Reproductive toxicity
no data available
STOT-single exposure
no data available
STOT-repeated exposure
no data available
Aspiration hazard
no data available
12.Ecological information
12.1 Toxicity
- Toxicity to fish: no data available
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
12.2 Persistence and degradability
In water bodies, propylene is readily degraded by microorganisms and is therefore not expected to bioaccumulate or bioconcentrate in organisms and food chains.
12.3 Bioaccumulative potential
An estimated BCF of 5 was calculated for propylene(SRC), using a log Kow of 1.77(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).
12.4 Mobility in soil
The Koc of propylene is estimated as 220(SRC), using a log Kow of 1.77(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that propylene is expected to have moderate mobility in soil.
12.5 Other adverse effects
no data available
13.Disposal considerations
13.1 Disposal methods
Product
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
14.Transport information
14.1 UN Number
ADR/RID: UN1077 | IMDG: UN1077 | IATA: UN1077 |
14.2 UN Proper Shipping Name
ADR/RID: PROPYLENE |
IMDG: PROPYLENE |
IATA: PROPYLENE |
14.3 Transport hazard class(es)
ADR/RID: 2 | IMDG: 2 | IATA: 2 |
14.4 Packing group, if applicable
ADR/RID: unknown | IMDG: unknown | IATA: unknown |
14.5 Environmental hazards
ADR/RID: no | IMDG: no | IATA: no |
14.6 Special precautions for user
no data available
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
no data available
15.Regulatory information
15.1 Safety, health and environmental regulations specific for the product in question
Chemical name | Common names and synonyms | CAS number | EC number |
---|---|---|---|
propene | propene | 115-07-1 | none |
European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed. | ||
EC Inventory | Listed. | ||
United States Toxic Substances Control Act (TSCA) Inventory | Listed. | ||
China Catalog of Hazardous chemicals 2015 | Listed. | ||
New Zealand Inventory of Chemicals (NZIoC) | Listed. | ||
Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Listed. | ||
Vietnam National Chemical Inventory | Listed. | ||
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Listed. |
16.Other information
Information on revision
Creation Date | Aug 19, 2017 |
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Revision Date | Aug 19, 2017 |
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/