1224879-40-6Relevant articles and documents
A highly active and general catalyst for the stille coupling reaction of unreactive aryl, heteroaryl, and vinyl chlorides under mild conditions
Lee, Dong-Hwan,Qian, Yingjie,Park, Ji-Hoon,Lee, Jong-Suk,Shim, Sang-Eun,Jin, Myung-Jong
, p. 1729 - 1735 (2013/07/19)
A β-diketiminatophosphane-palladium complex was found to act as an efficient and general catalyst in the Stille coupling reaction of various aryl and heteroaryl chlorides with organostannanes. The results show that this catalytic system allows for the use of less reactive substrates such as deactivated or sterically hindered aryl chlorides. A catalyst loading of 0.5 mol% was sufficient to achieve excellent performance under relatively mild reaction conditions. Furthermore, the scope of catalyst was extended to the coupling of vinyl chlorides. Copyright
General and highly active catalyst for mono and double Hiyama coupling reactions of unreactive aryl chlorides in water
Lee, Dong-Hwan,Jung, Ji-Young,Jin, Myung-Jong
, p. 9046 - 9048 (2011/02/17)
A new β-diketiminatophosphane Pd catalyst was found to be highly effective in the mono and double Hiyama coupling reactions of unactivated aryl chlorides in water.