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CAS

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1719-83-1

Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride is a white to beige powder with unique chemical properties that make it suitable for various applications in different industries.

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  • Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride Manufacturer Factory CAS 1719-83-1

    Cas No: 1719-83-1

  • USD $ 3.5-5.0 / Kiloliter

  • 5 Kiloliter

  • 3000 Metric Ton/Month

  • Chemwill Asia Co., Ltd.
  • Contact Supplier
  • 1719-83-1 Structure

  • Basic information

    1. Product Name: Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride
    2. Synonyms: 4,8-Etheno-1H,3H-benzo[1,2-c:4,5-c']difuran-1,3,5,7-tetrone, 3a,4,4a,7a,8,8a-hexahydro-;TIMTEC-BB SBB007762;BICYCLO(2.2.2)OCT-7-ENE-2,3,5,6-TETRACARBOXYLIC ACID DIANHYDRIDE;BICYCLO[2.2.2]OCT-7-ENE-2,3,5,6-TETRACARBOXYLIC DIANHYDRIDE;BICYCLO[2.2.2]OCT-7-ENE-2,3,5,6-TETRACARBOZYLIC DIANHYDRIDE;BICYCLO[2.2.2]-7-OCTENE-2,3,5,6-TETRACARBOXYLIC DIANHYDRIDE;BTA;4,10-DIOXATETRACYCLO[5.5.2.0(2,6).0(8,12)]TETRADEC-13-ENE-3,5,9,11-TETRAONE
    3. CAS NO:1719-83-1
    4. Molecular Formula: C12H8O6
    5. Molecular Weight: 248.19
    6. EINECS: 217-009-2
    7. Product Categories: Fluorenes, etc. (reagent for high-performance polymer research);Functional Materials;Reagent for High-Performance Polymer Research;Anhydride Monomers;Monomers;Polymer Science
    8. Mol File: 1719-83-1.mol

  • Chemical Properties

    1. Melting Point: >300 °C(lit.)
    2. Boiling Point: 351.26°C (rough estimate)
    3. Flash Point: 250.7 °C
    4. Appearance: white to beige powder
    5. Density: 1.4501 (rough estimate)
    6. Vapor Pressure: 5.17E-12mmHg at 25°C
    7. Refractive Index: 1.6000 (estimate)
    8. Storage Temp.: Store below +30°C.
    9. Solubility: N/A
    10. Water Solubility: Soluble in water
    11. Sensitive: Moisture Sensitive
    12. BRN: 294213
    13. CAS DataBase Reference: Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride(CAS DataBase Reference)
    14. NIST Chemistry Reference: Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride(1719-83-1)
    15. EPA Substance Registry System: Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride(1719-83-1)

  • Safety Data

    1. Hazard Codes: Xi
    2. Statements: 36/37/38
    3. Safety Statements: 26-37/39
    4. WGK Germany: 3
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1719-83-1(Hazardous Substances Data)

1719-83-1 Usage

Uses

Used in Electronics Industry:
Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride is used as a precursor for the production of thermo-cured cycloaliphatic polyamic acid and photo-cured cycloaliphatic polyamic ester. These materials are then converted into cycloaliphatic polyimide films, which are known for their excellent thermal stability, mechanical properties, and chemical resistance. These films are widely used in the electronics industry for applications such as flexible printed circuit boards, insulating layers in multilayer structures, and as protective coatings for electronic components.
Used in Aerospace Industry:
In the aerospace industry, Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride is utilized for the development of high-performance materials with exceptional thermal and mechanical properties. The resulting cycloaliphatic polyimide films are employed in the fabrication of components that require high-temperature resistance, such as in aircraft engines, satellite components, and space exploration equipment.
Used in Automotive Industry:
The automotive industry also benefits from the use of Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride in the production of cycloaliphatic polyimide films. These films are used in the manufacturing of high-temperature resistant components, such as engine parts, electrical insulation, and heat shields, which are crucial for the performance and safety of vehicles.
Used in Medical Industry:
In the medical field, Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride can be used in the development of biocompatible materials for various applications, such as in the production of medical devices and implants that require high thermal stability and resistance to harsh chemical environments.
Overall, Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride is a versatile compound with a wide range of applications across different industries, primarily due to its unique chemical properties and the ability to produce high-performance materials like cycloaliphatic polyimide films.

Check Digit Verification of cas no

The CAS Registry Mumber 1719-83-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,7,1 and 9 respectively; the second part has 2 digits, 8 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 1719-83:
(6*1)+(5*7)+(4*1)+(3*9)+(2*8)+(1*3)=91
91 % 10 = 1
So 1719-83-1 is a valid CAS Registry Number.
InChI:InChI=1/C12H8O6/c13-9-5-3-1-2-4(7(5)11(15)17-9)8-6(3)10(14)18-12(8)16/h1-8H

1719-83-1 Well-known Company Product Price

  • Brand
  • (Code)Product description
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  • Detail

  • TCI America

  • (B1317)  Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic Dianhydride  >98.0%(T)

  • 1719-83-1

  • 25g

  • 420.00CNY

  • Detail

  • TCI America

  • (B1317)  Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic Dianhydride  >98.0%(T)

  • 1719-83-1

  • 100g

  • 1,170.00CNY

  • Detail

  • TCI America

  • (B1317)  Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic Dianhydride  >98.0%(T)

  • 1719-83-1

  • 500g

  • 3,940.00CNY

  • Detail

  • TCI America

  • (B4261)  Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic Dianhydride (purified by sublimation)  >98.0%(GC)(T)

  • 1719-83-1

  • 5g

  • 790.00CNY

  • Detail

  • TCI America

  • (B4261)  Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic Dianhydride (purified by sublimation)  >98.0%(GC)(T)

  • 1719-83-1

  • 25g

  • 2,450.00CNY

  • Detail

  • Alfa Aesar

  • (A19632)  Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride, 97%   

  • 1719-83-1

  • 25g

  • 431.0CNY

  • Detail

  • Alfa Aesar

  • (A19632)  Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride, 97%   

  • 1719-83-1

  • 100g

  • 1266.0CNY

  • Detail

  • Aldrich

  • (178586)  Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylicdianhydride  99%

  • 1719-83-1

  • 178586-25G

  • 844.74CNY

  • Detail

  • Aldrich

  • (178586)  Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylicdianhydride  99%

  • 1719-83-1

  • 178586-100G

  • 2,516.67CNY

  • Detail

1719-83-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride

1.2 Other means of identification

Product number -
Other names 4,4a,8,8a-Tetrahydro-4,8-ethenobenzo[1,2-c:4,5-c']difuran-1,3,5,7(3aH,7aH)-tetraone

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1719-83-1 SDS

1719-83-1Relevant articles and documents

Preparation method of bicyclo-tetracarboxylic dianhydride

-

Paragraph 0010; 0020-0029; 0030-0039; 0040-0049, (2018/06/04)

The invention discloses a preparation method of bicyclo-tetracarboxylic dianhydride, and belongs to the field of a preparation method of fine chemicals. In the technical scheme, the preparation methodis mainly characterized in that with cheap phthalic acid being initial raw materials, 3,5-cyclopentadiene-1,2-dicarboxylic acid is generated through electrolytic reduction; then the 3,5- cyclopentadiene-1,2-dicarboxylic acid reacts with maleic anhydride, acetic anhydride or propionic anhydride is used as solvent and a dehydrating agent, and bicyclo-tetracarboxylic dianhydride is generated under 1,4-addition reaction and dehydrating ring-closure reaction. In the scheme, the preparation method has the advantages of being low in manufacturing cost, high in utilization rate of atoms, high in yield, mild in reaction condition, environmentally friendly and the like.

Method for preparing bicyclic structure tetracarboxylic dianhydride

-

Paragraph 0032; 0036; 0045; 0058, (2018/11/26)

The invention discloses a method for preparing bicyclic structure tetracarboxylic dianhydride and belongs to the field of fine chemical preparation methods. The main technical scheme is that phthalicacid serves as a starting raw material, bicyclic tetracarboxylic dianhydride with a full-exterior structure is synthesized by reaction of five steps including electrolytic reduction, 1,4-addition, methyl esterification, hydrogenation reduction, transesterification and dehydration ring closure. According to the scheme, compared with a traditional preparation process, the method has the advantages of fewer operation steps, mild reaction conditions and high yield, and the method is suitable for large-scale industrial production.

N-cyanoimides

-

, (2008/06/13)

Polyfunctional N-cyanoimides and their precursors and derivatives are disclosed along with methods for their preparation and interconversion. Also disclosed are curable compositions comprising the N-cyanoimides or poly(amide-cyanoamides) and reactive diluents as well as novel dianhydrides, polyimides, and poly(amide-cyanoamides) and methods for making them.

Diels-Alder Reactions with 2H-Pyran-2-ones: Reactivity and Selectivity

Effenberger, Franz,Ziegler, Thomas

, p. 1339 - 1346 (2007/10/02)

2H-Pyran-2-ones 1 react with maleic anhydride (2) in a double Diels-Alder reaction to give bicyclooct-2-ene-5,6:7,8-tetracarboxylic dianhydrides 5; the syn/syn structure was established.As expected, the reactivity of 1 was increased by electron donor substituents (OR, alkyl) and diminished by electron withdrawing substituents (CO2R).The steric influence of substituents at C-6 also decrease the reactivity of 1. - Methyl propiolate (6) and phenylacetylene (9) react with 1 to form the Diels-Alder products 7 which suffer CO2 elimination to yield methyl benzoates 8 with low and biphenyls 10 with high regioselectivity, respectively.

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