2365379-82-2Relevant articles and documents
Assembly of a Porous Supramolecular Polyknot from Rigid Trigonal Prismatic Building Blocks
Li, Penghao,Chen, Zhijie,Ryder, Matthew R.,Stern, Charlotte L.,Guo, Qing-Hui,Wang, Xingjie,Farha, Omar K.,Stoddart, J. Fraser
supporting information, p. 12998 - 13002 (2019/08/20)
Herein we report a hydrogen-bonded three-dimensional porous supramolecular polyknot assembled from a rigid trigonal prismatic triptycene building block with six extended peripheral aryl-carboxyl groups. Within this superstructure, three arrays of undulate
Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks
Chen, Zhijie,Li, Penghao,Wang, Xingjie,Otake, Ken-Ichi,Zhang, Xuan,Robison, Lee,Atilgan, Ahmet,Islamoglu, Timur,Hall, Morgan G.,Peterson, Gregory W.,Stoddart, J. Fraser,Farha, Omar K.
supporting information, p. 12229 - 12235 (2019/08/27)
Zirconium-based metal-organic frameworks (Zr-MOFs) based on edge-transitive nets such as fcu, spn, she, csq, and ftw with diverse potential applications have been widely reported. Zr-MOFs based on the highly connected 6,12-connected alb net, however, remain absent on account of synthetic challenges. Herein we report the ligand-directed reticular syntheses and isoreticular expansion of a series of Zr-MOFs with the edge-transitive alb net from 12-connected hexagonal-prismatic Zr6 nodes and 6-connected trigonal-prismatic linkers, i.e., microporous NU-1600, mesoporous NU-1601, and mesoporous NU-1602. These Zr-MOFs exhibit remarkable activities toward the destruction of a nerve agent (soman) and a nerve agent simulant (DMNP).
