Relevant articles and documents
Kinetics of the synthesis of propyl and butyl acrylates in the presence of some heteropolyacids as catalysts
Skrzypek, Ierzy Witczak, Teresa Grzesik, MirosLaw Witczak, Mariusz
Esterification reactions of acrylic acid with n-propanol and n-butanol were carried out in the liquid phase in the presence of H3PW 12O40 or H3PMo12O40 as a catalyst, at various temperatures, molar ratios of the reactants, and concentrations of the catalyst. The kinetic equations had a nonelementary form.
Electrocatalytic Oxidation of Allylic Ethers, Dihydropyran and Phenol Using a Polypyridyl Complex of Ruthenium(IV)
Campos, Jose Luiz Giovani, Wagner F. De Romero, Jose Ricardo
An electrocatalytic procedure is described for the oxidation of allyl butyl ether, (E/Z)-2-butenyl butyl ether, dihydropyran and phenol using the ruthenium(IV) oxidant <(bpy)(trpy)RuO>2+.The resulting products were respectively, butyl acrylate (42percent), butyl (E/Z)-2-butenoate (53percent), 2,3-dihydro-4-pyranone (40percent) and o-benzoquinone (71percent).
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