Relevant articles and documents
A convenient synthesis of derivatives of 1,3,2-dioxaphosphocane-2-sulfide with bioacitivity via Lawesson's reagent
Luo, Yanping He, Liangnian Ding, Mingwu Yang, Guangfu Luo, Aihong Liu, Xiaopeng Wu, Tianjie
Lawesson's reagent, 2,4-bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane-2,4-disufide, reacted with the substituted 1,5-bisphenol 1to afford derivatives of 1,3,2-dioxaphosphocane-2-sulfide 2, which were found to possess selective herbicidal activity against rape.
PHOTOINDUCED REACTIONS OF ORGANIC COMPOUNDS WITH TRANSITION METAL COMPLEXES. II. REACTION OF PtCl62- WITH ACETONE TO GIVE A ?-ACETONYL COMPLEX OF PLATINUM(IV). DETECTION OF PLATINUM(III) COMPOUNDS BY ESR
Nizova, G. V. Serdobov, M. V. Nikitaev, A. T. Shul'Pin, G. B.
Light irradiation of a PtCl62- solution in acetone affords a ?-acetonyl complex of platinum(IV), a platinum(III) complex and CH3COCH2-radical are detected in the ESR spectrum of the frozen solution of PtCl62- in acetone irradiated at 77 K.The proposed mechanism of the reaction involves electron transfer from the enol tautomer of acetone to PtCl62-.
Japan | Contact:sir
India | Contact:N. A. Shah