Relevant articles and documents
Synthesis, characterization, crystal structures, Hirshfeld surface analysis, DFT computational studies and catalytic activity of novel oxovanadium and dioxomolybdenum complexes with ONO tridentate Schiff base ligand
Kargar, Hadi Bazrafshan, Maryam Fallah-Mehrjardi, Mehdi Behjatmanesh-Ardakani, Reza Rudbari, Hadi Amiri Munawar, Khurram Shahzad Ashfaq, Muhammad Tahir, Muhammad Nawaz
For the first time, two new oxovanadium and dioxomolybdenum Schiff base complexes, VOL(OMe) and MoO2L, were synthesized through the reaction of a ONO tridentate Schiff base ligand (H2L) derived from the condensation of 5-bromosalicyl
Silica functionalized Cu(II) catalysed selective oxidation of benzyl alcohols using TEMPO and molecular oxygen as an oxidant
Sharma, Pankaj Gupta, Monika Gupta, Rajive Gupta, Manjulla
A general scheme for the oxidation of benzyl alcohols catalyzed by silica functionalized copper (II) has been designed. TEMPO, a free radical, assists this oxidation that was initiated by molecular oxygen which converts it to a primary oxidant. This catalytic combination i.e. SiO2-Cu(II) in presence of TEMPO and oxygen provides excellent results in terms of yields and reaction time. SiO2-Cu(II) was very well characterized by different spectroscopic techniques such as FTIR, XRD, TGA, XPS, EDAX, SEM, TEM and AAS and is recyclable upto five times which makes it economically beneficial. [Figure not available: see fulltext.]
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