Relevant articles and documents
Octacarbonyl dicobalt-catalyzed selective transformation of ethyl diazoacetate into organic products containing the ethoxycarbonyl carbene building block
Tuba, Robert Ungváry, Ferenc
In the presence of 1 mol% octacarbonyl dicobalt ethyl diazoacetate can be transformed at room temperature and carbon monoxide pressure selectively into diethyl 2-diazo-3-oxo-pentanedicarboxylate or in the presence of an alcohol (methanol, ethanol, tert-bu
Indium as a reducing agent. Chemoselective reduction of α-halocarbonyl compounds and benzyl halides by indium metal in water under sonication
Ranu, Brindaban C. Dutta, Pinak Sarkar, Arunkanti
Indium metal in water reduces a-halocarbonyl compounds and benzyl iodides to the corresponding dehalogenated products in excellent yields under sonication although simple alkyl and aryl iodides remained inert under these conditions.
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