Iodoxybenzene (696-33-3) 's Synthetic route

Mechanism of racemization in the reaction of 4-methylcyclohexylidenemethyliodonium salt with sulfonate ions: Formation of intermediate cycloheptyne [1]

Fujita  Sakanishi  Okuyama

Microwave synthesis of charge-compensated dodecaborates bearing exohedral boron-phosphorus connectivities

Dopke, Joel A.  Lincoln, Zachary S.  Blazejewski, Jacob  Staples, Richard J.  Lee, Mark E.

Solution pyrolysis of arylphosphonium salts of B₁₂H₁₂^2?,1, utilizing microwave heating provided charge-compensated monophosphine dodecaborate derivatives of general formula B₁₂H₁₁(PPh_nR_3-n)^? (n = 1, R = Me; n = 2, R = Me, Et) in high yield. The resulting anions B₁₂H₁₁(PPh₂Me)^? (2), B₁₂H₁₁(PPhMe₂)^? (3), and B₁₂H₁₁(PPh₂Et)^? (4) were characterized by ¹¹B, ¹H, ¹³C, and ³¹P NMR spectroscopy, and by negative mode ESI-TOF mass spectrometry. A single-crystal X-ray diffraction study of [Ph₃PMe]2 confirmed an icosahedral boron cluster fragment appended by a PPh₂Me moiety through a P-B bond.