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tert-BUTYL GLYCIDYL ETHER
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Name

tert-BUTYL GLYCIDYL ETHER

 EINECS N/A
CAS No. 7665-72-7 Density 0.944g/cm3
PSA 21.76000 LogP 1.20030
Solubility 90.3g/L at 20℃ Melting Point -70oC
Formula C7H14 O2 Boiling Point 152°Cat760mmHg
Molecular Weight 130.187 Flash Point 43.3°C
Transport Information N/A Appearance N/A
Safety Suspected carcinogen. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors. Risk Codes 10-19-22-36-43
Molecular Structure Molecular Structure of 7665-72-7 (TERT-BUTYL GLYCIDYL ETHER) Hazard Symbols Xn
Synonyms

Oxirane,[(1,1-dimethylethoxy)methyl]- (9CI); Propane, 1-tert-butoxy-2,3-epoxy-(6CI,7CI); (tert-Butoxymethyl)oxirane; (?à)-tert-Butylglycidyl ether; 1,1-Dimethylethyl glycidylether; 1-tert-Butoxy-2,3-epoxypropane; 2,3-Epoxypropyl-tert-butyl ether;2-(tert-Butoxymethyl)oxirane; 3-tert-Butoxy-1,2-epoxypropane; Glycidyltert-butyl ether; tert-Butyl 2,3-epoxypropyl ether; tert-Butyl glycidyl ether

Article Data 10

tert-BUTYL GLYCIDYL ETHER Synthetic route

22576-65-4

1-chloro-3-tert-butoxy-2-propanol

7665-72-7

t-butyl glycidyl ether

Conditions
ConditionsYield
With sodium hydroxide at 5℃; for 1h;70%
With sodium hydroxide In hexane at 60℃; for 2h;61.5%
106-89-8

epichlorohydrin

75-65-0

tert-butyl alcohol

7665-72-7

t-butyl glycidyl ether

Conditions
ConditionsYield
With diethyl ether; boron trifluoride Behandeln mit wss. Natronlauge;
With tin(IV) chloride at 90 - 100℃; for 0.333333h;
1471-04-1

allyl tert-butyl ether

7665-72-7

t-butyl glycidyl ether

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 45℃; for 48h;
3132-64-7

1,2-Epoxy-3-bromopropane

75-65-0

tert-butyl alcohol

7665-72-7

t-butyl glycidyl ether

Conditions
ConditionsYield
With boron trifluoride In diethyl ether at 50 - 55℃;
7665-72-7

t-butyl glycidyl ether

62-53-3

aniline

1-tert-butoxy-3-phenylamino-propan-2-ol

Conditions
ConditionsYield
With zirconium(IV) chloride at 20℃; for 0.25h;100%
With lithium bromide at 20℃; for 5h;100%
silica gel at 20℃; for 3h;100%
7665-72-7

t-butyl glycidyl ether

1030377-21-9

(S)-2-(hydroxymethyl)piperazine-1-carboxylic acid tert-butyl ester

(2S)-tert-butyl 4-(3-(tert-butoxy)-2-hydroxypropyl)-2-(hydroxymethyl)piperazine-1-carboxylate

Conditions
ConditionsYield
In ethanol at 120℃; for 0.5h; Microwave irradiation;100%
7665-72-7

t-butyl glycidyl ether

124-38-9

carbon dioxide

84137-72-4

4-[(1,1-dimethylethoxy)methyl]-1,3-dioxolan-2-one

Conditions
ConditionsYield
With tri-n-butyl(2-hydroxyethyl)ammonium iodide In neat (no solvent) at 45℃; under 7500.75 Torr; for 18h; Temperature; Pressure; Autoclave;99%
With 18-crown-6 ether; calcium iodide In neat (no solvent) at 23℃; under 760.051 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Temperature; Pressure;99%
With calcium iodide In neat (no solvent) at 25℃; under 7500.75 Torr; for 24h;99%
7665-72-7

t-butyl glycidyl ether

1-tert-butoxy-3-iodo-propan-2-ol

Conditions
ConditionsYield
With lithium iodide; 1-hexyl-3-methylimidazolium perchlorate at 25℃; for 1h;98%
With iodine; 5,15,10,20-tetraphenylporphyrin In dichloromethane at 20℃; for 5.8h; regioselective reaction;77%
7665-72-7

t-butyl glycidyl ether

67-64-1

acetone

122977-52-0

4-(tert-butoxymethyl)-2,2-dimethyl-1,3-dioxolane

Conditions
ConditionsYield
With Cr-pillared montmorillonite for 4h; Reflux;97%
With FeOx-pillared bentonite at 60℃; for 2h;63%
With FeOx-pillared bentonite at 60℃; for 2h;63 %Chromat.
7665-72-7

t-butyl glycidyl ether

540-63-6

ethane-1,2-dithiol

1-(tert-butoxy)-3-[(2-[3-(tert-butoxy)-2-hydroxypropyl]sulfanylethyl)sulfanyl]-2-propanol

Conditions
ConditionsYield
With potassium carbonate for 3h; Heating;96%
N-benzyl-trimethylammonium hydroxide
With potassium carbonate In water Reflux;

tert-BUTYL GLYCIDYL ETHER Chemical Properties

Synonyms: 1-TERT-BUTOXY-2,3-EPOXYPROPANE;(TERT-BUTOXYMETHYL)OXIRANE;TERT-BUTYL GLYCIDYL ETHER;TBGE;T-BUTYL GLYCIDYL ETHER;((1,1-dimethylethoxy)methyl)-oxiran;((1,1-Dimethylethoxy)methyl)oxirane;[(1,1-dimethylethoxy)methyl]-oxiran
EINECS: 231-640-0
Melting point: -70°C
Boiling point: 150-152 °C
Fp: 55°C
refractive index: n20/D 1.417(lit.)
density: 0.917 g/mL at 25 °C(lit.)

tert-BUTYL GLYCIDYL ETHER is the chemical compound with the formula C7H14O2 .Its molar mass  is 130.18 g/mol .

tert-BUTYL GLYCIDYL ETHER Toxicity Data With Reference

1.   

mmo-sat 333 µg/plate

   MUREAV    Mutation Research. 172 (1986),105.
2.   

bfa-mus:sat 500 mg/kg/5D-I

   ENMUDM    Environmental Mutagenesis. 2 (1980),284.
3.   

orl-rat LD50:2 g/kg

   38MKAJ    Pattys Industrial Hygiene and Toxicology 3rd rev. ed.,Clayton, G.D., andF.E. Clayton, eds.,New York, NY.: John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985 2A ,1981,2202.

tert-BUTYL GLYCIDYL ETHER Consensus Reports

tert-BUTYL GLYCIDYL ETHER is reported in EPA TSCA Inventory.

tert-BUTYL GLYCIDYL ETHER Safety Profile

Suspected carcinogen. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.

Risk Statements : 10:  Flammable  ;19:  May form explosive peroxides  ;22:  Harmful if swallowed  ;36:  Irritating to the eyes  ;43:  May cause sensitization by skin contact  
Safety Statements : 16:  Keep away from sources of ignition - No smoking  ;26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice ; 36/37:  Wear suitable protective clothing and gloves .
Hazard Codes : Xn
RIDADR : UN 3271 3/PG 3
WGK Germany : 3

tert-BUTYL GLYCIDYL ETHER Standards and Recommendations

DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
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