rhodium

Base Information

• Chemical Name: rhodium
• CAS No.: 378784-00-0
• Molecular Formula: Rh
• Molecular Weight: 102.906
• Mol file: 378784-00-0.mol

Synonyms:

Chemical Property of rhodium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of rhodium

There total 293 articles about rhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.8%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) → {rhodium(1,5-cyclooctadiene)H}4 + rhodium (378784-00-0,7440-16-6)

Guidance literature:

With lithium triethylborohydride; In tetrahydrofuran; slow addn. of THF soln. of LiB(C2H5)3H to soln. of Rh complex in THF cooled in ice bath, under dry N2; stirring at room temp. for 16 h;; removal of volatile components in vac.; extraction of residue with pentane; pentane extractant yields (RhH(C8H12))4; washing residue with THF; centrifugation yields Rh; heating in vac. at 400°C for 2 h; TEM; electron and X-ray diffraction;;

DOI:10.1006/jcat.1993.1044

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + tetra[μ-acetato-bis(methanol)]dirhodium → rhodium(III)chloride (10049-07-7) + rhodium (378784-00-0,7440-16-6)

Guidance literature:

DOI:10.1021/ic50163a042 DOI:10.1016/S0020-1693(00)89485-2

Reference yield:

rhodium{C6H3(CH2NMe2)2-o,o'}(norbornadiene) (115338-69-7) → norbornene (279-23-2) + 1,3-bis[(dimethylamino)methyl]benzene (19851-44-6) + rhodium (378784-00-0,7440-16-6)

Guidance literature:

With H₂; In benzene; H2 is bubbled through a soln. of Rh complex for 5 min.; identification of organic compounds in soln., evapn. of volatile substances yields mainly metallic Rh as residue;

DOI:10.1021/om00099a010

upstream raw materials:

sodium tetrahydroborate

hydrogen

rhodium(III)

magnesium

Downstream raw materials:

Carnosine

indole

rhenium disulfide

rhodium monosulfide

Refernces

• 1、 Yae, Shinji,Nasu, Noriaki,Matsumoto, Kohei,Hagihara, Taizo,Fukumuro, Naoki,Matsuda, Hitoshi. "Nucleation behavior in electroless displacement deposition of metals on silicon from hydrofluoric acid solutions". . p. 35 - 41. Retrieved 2007.
• 2、 Zhang, Y. C.,Kershaw, R.,Dwight, K.,Wold, A.. "Preparation and properties of the system Cr2-x RhxO3(2≥ x ≥ 0)". . p. 155 - 162. Retrieved 1988.
• 3、 Bowman, R. C. Jr.,Cantrell, J. S.,Samwer, K.,Tebbe, J.,Venturini, E. L.,Rush, J. J.. "". . . Retrieved 1988.
• 4、 Guenther, Anja,Ruck, Michael. "Hexatellurium rings in coordination polymers and molecular clusters: Synthesis and crystal structures of [M(Te6)]X3 (M = Rh, Ir; X = Cl, Br, I) and [Ru2(Te6)](TeBr3) 4(TeBr2)2". . p. 317 - 323. Retrieved 2012.
• 5、 Herzog, Frank,Thiele, Gerhard. "About RhSCl5 - A hexameric, molecular rhodium(III) complex with SCl2 ligands". . p. 1461 - 1464. Retrieved 2002.
• 6、 Banerjee, Aparna,Prasad,Venugopal. "Gibbs free energy of formation of calcium rhodite". . p. 59 - 65. Retrieved 2004.
• 7、 Zhao, Chen,Gan, Weijia,Fan, Xiaobing,Cai, Zhipeng,Dyson, Paul J.,Kou, Yuan. "Aqueous-phase biphasic dehydroaromatization of bio-derived limonene into p-cymene by soluble Pd nanocluster catalysts". . p. 244 - 250. Retrieved 2008.
• 8、 Skrobot,Ugolkov,Grebenshchikov,Gusarov. "Subsolidus phase relations in the system Tm2O 3-Rh2O3". . p. 1326 - 1329. Retrieved 2007.
• 9、 Zettsu, Nobuyuki,McLellan, Joseph M.,Wiley, Benjamin,Yin, Yadong,Li, Zhi-Yuan,Xia, Younan. "Synthesis, stability, and surface plasmonic properties of rhodium multipods, and their use as substrates for surface-enhanced raman scattering". . p. 1288 - 1292. Retrieved 2006.
• 10、 Zakharchenko. "Recovery with calcium oxide sorbent of conversion products of rhodium catalyst for ammonia oxidation". . p. 1594 - 1597. Retrieved 2002.