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CAS No.: | 10272-07-8 |
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Name: | 3,5-Dimethoxyaniline |
Article Data: | 36 |
Molecular Structure: | |
Formula: | C8H11NO2 |
Molecular Weight: | 153.181 |
Synonyms: | 3,5-Dimethoxy-phenylamine;3,5-Dimethoxybenzeneamine;Benzenamine, 3,5-dimethoxy-;3,5-dimethoxy aniline;5-Aminoresorcinol dimethylether; |
EINECS: | 233-616-5 |
Density: | 1.096 g/cm3 |
Melting Point: | 54-57 ºC |
Boiling Point: | 178 ºC (20 mmHg) |
Flash Point: | 135 ºC |
Solubility: | insoluble in water |
Appearance: | White crystal or Colorless liquid |
Hazard Symbols: | Xn,Xi |
Risk Codes: | 22-36/37/38-20/21/22 |
Safety: | 26-36-36/37/39-22 |
Transport Information: | UN 2811 |
PSA: | 44.48000 |
LogP: | 1.86720 |
1-azido-3,5-dimethoxybenzene
3,5-Dimethoxyaniline
Conditions | Yield |
---|---|
With sodium tetrahydroborate; palladium In water for 1.5h; Inert atmosphere; | 99% |
With sodium sulfide; water for 0.5h; Reflux; | 96% |
With ammonium hydroxide at 90℃; for 0.5h; | 90% |
With triethylamine; tris[tert-butyl]phosphonium tetrafluoroborate In tetrahydrofuran; water at 20℃; for 15h; Staudinger Azide Reduction; | 94 %Spectr. |
N-(3,5-dimethoxyphenyl)-2,2,2-trifluoroacetamide
3,5-Dimethoxyaniline
Conditions | Yield |
---|---|
With water; potassium carbonate In methanol for 20h; Ambient temperature; | 94% |
2-Trimethylsilanyl-ethanesulfonic acid (3,5-dimethoxy-phenyl)-amide
3,5-Dimethoxyaniline
Conditions | Yield |
---|---|
With cesium fluoride In N,N-dimethyl-formamide at 95℃; for 40h; | 93% |
1-chloro-3,5-dimethoxybenzene
3,5-Dimethoxyaniline
Conditions | Yield |
---|---|
With ammonium hydroxide; potassium phosphate In dimethyl sulfoxide at 80℃; UV-irradiation; | 93% |
With ammonium hydroxide; potassium phosphate; copper(l) iodide; N1,N2-bis(5-methyl-[1,1'-biphenyl]-2-yl)oxalamide In water; dimethyl sulfoxide at 110℃; for 24h; Inert atmosphere; | 88% |
With ammonium hydroxide; potassium phosphate; copper(l) iodide; N1,N2-bis(5-methyl-[1,1'-biphenyl]-2-yl)oxalamide In dimethyl sulfoxide at 120℃; for 24h; Inert atmosphere; Schlenk technique; | 88% |
N-(3,5-dimethoxy-phenyl)-acetamide
3,5-Dimethoxyaniline
Conditions | Yield |
---|---|
Stage #1: N-(3,5-dimethoxy-phenyl)-acetamide With Schwartz's reagent In tetrahydrofuran at 20℃; for 0.05h; Inert atmosphere; Stage #2: With water In tetrahydrofuran Inert atmosphere; chemoselective reaction; | 86% |
With alkaline solution |
3,5-dimethoxyphenylboronic acid
3,5-Dimethoxyaniline
Conditions | Yield |
---|---|
With sodium hydroxide; hydroxylamine-O-sulfonic acid In acetonitrile at 20℃; for 16h; | 82% |
1-bromo-3,5-dimethoxybenzene
3,5-Dimethoxyaniline
Conditions | Yield |
---|---|
Stage #1: 1-bromo-3,5-dimethoxybenzene With magnesium In tetrahydrofuran Inert atmosphere; Stage #2: With C10H17NO In tetrahydrofuran; toluene at -78℃; for 2h; Inert atmosphere; Stage #3: With ammonium chloride In tetrahydrofuran; water; toluene Inert atmosphere; | 78% |
With ammonium hydroxide; copper(l) iodide; N,N'-bis(3,5-dimethoxyphenyl)cyclopentane-1,1-dicarboxamide; caesium carbonate In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere; Sealed tube; | 68% |
With ammonia; sodium; ferric nitrate |
1-iodo-3,5-dimethoxybenzene
3,5-Dimethoxyaniline
Conditions | Yield |
---|---|
With ammonium hydroxide; copper(l) iodide; N,N'-bis(3,5-dimethoxyphenyl)cyclopentane-1,1-dicarboxamide; caesium carbonate In dimethyl sulfoxide at 20℃; for 24h; Inert atmosphere; Sealed tube; | 75% |
3,5-dimethoxyphenol
3,5-Dimethoxyaniline
Conditions | Yield |
---|---|
Stage #1: 3,5-dimethoxyphenol With Nonafluorobutanesulfonyl fluoride; tris(trimethylsilyl)amine; potassium hexamethylsilazane In tetrahydrofuran at 60℃; for 5h; Schlenk technique; Inert atmosphere; Stage #2: With hydrogenchloride In water at 20℃; for 0.0833333h; pH=3 - 4; Reagent/catalyst; Solvent; | 75% |
3,5-dimethoxybenzoic acid
3,5-Dimethoxyaniline
Conditions | Yield |
---|---|
Stage #1: 3,5-dimethoxybenzoic acid With diphenylphosphoranyl azide; triethylamine In toluene at 80℃; Stage #2: With sodium hydroxide In tetrahydrofuran; toluene at 20℃; for 2h; | 43% |
Stage #1: 3,5-dimethoxybenzoic acid With diphenylphosphoranyl azide; triethylamine In toluene at 80℃; Stage #2: With sodium hydroxide In tetrahydrofuran for 2h; | 43% |
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