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Cas Database

Name	3-Chloropropiononitrile	EINECS	208-827-0
CAS No.	542-76-7	Density	1.144
PSA	N/A	LogP	N/A
Solubility	4.50 g/100 mL in water	Melting Point	-51 ºC
Formula	C3H4 Cl N	Boiling Point	174-174 ºC
Molecular Weight	89.5245	Flash Point	168 ºF
Transport Information	UN 3276	Appearance	N/A
Safety	Poison by ingestion, intravenous, and intraperitoneal routes. Flammable in its liquid form when exposed to heat or flame. To fight fire, use alcohol foam, water, foam, CO₂, or dry chemical. When heated to decomposition it emits very toxic fumes of Cl⁻, CN⁻, and NO_x. See also NITRILES.	Risk Codes	R23;R28
Molecular Structure		Hazard Symbols
Synonyms	Propionitrile,3-chloro- (6CI,8CI); 1-Chloro-2-cyanoethane; 2-Cyanoethyl chloride;3-Chloropropanenitrile; 3-Chloropropanonitrile; 3-Chloropropionitrile; NSC2588; b-Chloropropionitrile	Article Data	41

3-Chloropropiononitrile Chemical Properties

IUPAC Name: 3-Chloropropiononitrile
The MF of 3-Chloropropiononitrile (542-76-7) is C₃H₄ClN.

The MW of 3-Chloropropiononitrile (542-76-7) is 89.52.
Synonyms of 3-Chloropropiononitrile (542-76-7): 3-Chloropropanonitrile ; Propanenitrile, 3-chloro- ; 1-Chloro-2-cyanoethane ; 3-Chloropropiononitrile
Product Categories: Organics;C1 to C5;Cyanides/Nitriles;Nitrogen Compounds
Form: colorless liquid with a characteristic acrid odor
Index of Refraction: 1.414
EINECS: 208-827-0
Density: 1.08 g/ml
Flash Point: 75.6 °C
Boiling Point: 176.7 °C
Melting Point: -51 °C
Water Solubility: 4.50 g/100 mL
Merck: 14,2160
BRN: 1098454

3-Chloropropiononitrile Uses

3-Chloropropiononitrile (542-76-7) is used as drug and polymer synthesis, organic synthesis intermediate and raw materials.

3-Chloropropiononitrile Toxicity Data With Reference

1.	orl-rat LD50:100 mg/kg	14CYAT Industrial Hygiene and Toxicology. 2 (1962),2025.
2.	orl-mus LD50:9 mg/kg	14CYAT Industrial Hygiene and Toxicology. 2 (1962),2025.
3.	ipr-mus LD50:100 mg/kg	NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD277-689 .
4.	ivn-mus LD50:56 mg/kg	CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#01996 .

3-Chloropropiononitrile Consensus Reports

EPA Extremely Hazardous Substances List. Cyanide and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

3-Chloropropiononitrile Safety Profile

Poison by ingestion, intravenous, and intraperitoneal routes. Flammable in its liquid form when exposed to heat or flame. To fight fire, use alcohol foam, water, foam, CO₂, or dry
chemical. When heated to decomposition it emits very toxic fumes of Cl⁻, CN⁻, and NO_x. See also NITRILES.
Safety information of 3-Chloropropiononitrile (542-76-7):
Hazard Codes T+
Risk Statements
23 Toxic by inhalation
28 Very Toxic if swallowed
Safety Statements
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR UN 3276 6.1/PG 2
WGK Germany 3
RTECS UG1400000
HazardClass 6.1
PackingGroup II
HS Code 29269095

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