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Cas Database

Name	4-Chlorothioanisole	EINECS	204-600-5
CAS No.	123-09-1	Density	1.22
PSA	25.30000	LogP	3.06190
Solubility	N/A	Melting Point	18-19 °C
Formula	C7H7 Cl S	Boiling Point	222.4°Cat760mmHg
Molecular Weight	158.652	Flash Point	90°C
Transport Information	N/A	Appearance	White crystalline power
Safety	Poison by ingestion. Mildly toxic by skin contact. An eye irritant. When heated to decomposition it emits very toxic fumes of Cl⁻ and SO_x. See also CHLORINATED HYDROCARBONS, AROMATIC; and SULFIDES.	Risk Codes	R22
Molecular Structure		Hazard Symbols
Synonyms	Sulfide,p-chlorophenyl methyl (6CI,7CI,8CI); 1-Chloro-4-(methylthio)benzene;4-Chlorophenyl methyl sulfide; 4-Chlorothioanisole;4-Methylthio-1-chlorobenzene; Methyl 4-chlorophenyl sulfide; Methylp-chlorophenyl sulfide; NSC 72090; p-(Methylthio)chlorobenzene; p-Chlorophenylmethyl sulfide; p-Chlorothioanisole	Article Data	90

4-Chlorothioanisole Chemical Properties

Molecular Formula: C₇H₇ClS
Molecular Weight: 158.65
EINECS: 204-600
Flash Point: 90 °C
Sensitive: Stench
Refractive index n20/D 1.598(lit.)
Density: 1.22 g/mL at 25 °C(lit.)
Boiling Point: 222.4 °C at 760 mmHg
Enthalpy of Vaporization: 44.02 kJ/mol
Vapour Pressure: 0.151 mmHg at 25°C
IUPAC Name: 1-chloro-4-methylsulfanylbenzene
Chemical Stability: Stable under normal temperatures and pressures
Appearance P-chlorophenyl methyl sulfide (123-09-1): clear colorless to light yellow liquid
Synonyms: Methyl 4-chlorophenyl sulfide;4-Chlorophenyl methyl sulfide;4-Chlorothioanisole;1-Chloro-4-(methylthio)benzene;P-chlorophenyl methyl sulfide;P-Chlorothioanisole;1-Chloro-4-(methylthio)-benzen;Methylp-chlorophenylsulfide
Following is the molecular structure of P-chlorophenyl methyl sulfide (123-09-1):

4-Chlorothioanisole Toxicity Data With Reference

1.	eye-rbt 100 mg MLD	NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD-A082-824 .
2.	orl-rat LD50:400 mg/kg	TOLED5 Toxicology Letters. 1000 (Sp Iss 1),(1980),32.
3.	skn-rat LDLo:5630 mg/kg	NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD-A082-824 .
4.	orl-mus LD50:672 mg/kg	NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD-A082-824 .

4-Chlorothioanisole Safety Profile

Poison by ingestion. Mildly toxic by skin contact. An eye irritant. When heated to decomposition it emits very toxic fumes of Cl⁻ and SO_x.

Safety Information P-chlorophenyl methyl sulfide (123-09-1):
Hazard Codes Xn,Xi
Xi: Irritant Xn: Harmful
Risk Statements: 22
22: Harmful if swallowed
Safety Statements: 23-26-36/37/39
23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
RIDADR: 2810
WGK Germany: 3
RTECS: WQ3840000
Hazard Note: Irritant/Stench
HazardClass: 6.1(b)
PackingGroup: III

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