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Cas Database |
| Name |
4-Hydroxymethyl-5-methylimidazole |
EINECS | 249-740-8 |
| CAS No. | 29636-87-1 | Density | 1.231 g/cm3 |
| PSA | 48.91000 | LogP | 0.21040 |
| Solubility | almost transparency | Melting Point |
136°C |
| Formula | C5H8 N2 O | Boiling Point | 389.1 °C at 760 mmHg |
| Molecular Weight | 112.131 | Flash Point | 189.1 °C |
| Transport Information | N/A | Appearance | White and light brown Crystalsl Powder |
| Safety | 26-36/37/39 | Risk Codes | 36/37/38 |
| Molecular Structure |
|
Hazard Symbols | R36/37/38:Irritating to eyes, respiratory system and skin.; |
| Synonyms |
1H-Imidazole-4-methanol,5-methyl- (9CI); Imidazole-4(or 5)-methanol, 5(or 4)-methyl- (7CI);Imidazole-4-methanol, 5-methyl- (8CI); 4-(Hydroxymethyl)-5-methyl-1H-imidazole;4-(Hydroxymethyl)-5-methylimidazole; 4-Methyl-5-(hydroxymethyl)imidazole;4-Methyl-5-imidazolemethanol; 5-(Hydroxymethyl)-4-methylimidazole;5-Methyl-1H-imidazole-4-methanol; 5-Methyl-4-imidazolemethanol |
Article Data | 18 |
4-Hydroxymethyl-5-methylimidazole Synthetic route
- 51605-32-4
Ethyl 5-Methyl-4-imidazolecarboxylate
- 29636-87-1
4(5)-methyl-5(4)-hydroxymethylimidazole
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 4h; Reflux; | 89% |
| With lithium aluminium tetrahydride In tetrahydrofuran for 4h; Heating; | 55% |
- 50-00-0
formaldehyd
- 51605-32-4
Ethyl 5-Methyl-4-imidazolecarboxylate
- 29636-87-1
4(5)-methyl-5(4)-hydroxymethylimidazole
| Conditions | Yield |
|---|---|
| With sodium hydroxide In water for 0.5h; Heating; | 68% |
- 29636-87-1
4(5)-methyl-5(4)-hydroxymethylimidazole
| Conditions | Yield |
|---|---|
| With sodium hydroxide; formaldehyd In water | 65% |
| Conditions | Yield |
|---|---|
| In water at 40℃; |
- 51605-32-4
ethyl 4(5)-methylimidazole-5(4)-carboxylate
- 29636-87-1
4(5)-methyl-5(4)-hydroxymethylimidazole
| Conditions | Yield |
|---|---|
| With hydrogenchloride In tetrahydrofuran; ethanol |
- 29636-87-1
4(5)-methyl-5(4)-hydroxymethylimidazole
| Conditions | Yield |
|---|---|
| With acetic anhydride; sodium nitrite In methanol at 10 - 20℃; for 3.5h; | 92% |
- 29636-87-1
4(5)-methyl-5(4)-hydroxymethylimidazole
- 68282-53-1
5-methyl-4-formylimidazole
| Conditions | Yield |
|---|---|
| With manganese(IV) oxide In tetrahydrofuran for 3h; Oxidation; Heating; | 85% |
- 68-11-1
mercaptoacetic acid
- 29636-87-1
4(5)-methyl-5(4)-hydroxymethylimidazole
- 112528-37-7
[(5-methyl-1H-imidazol-4-yl)methylsulfanyl]acetic acid
| Conditions | Yield |
|---|---|
| In acetic acid for 24h; Reflux; | 82% |
- 67-56-1
methanol
- 29636-87-1
4(5)-methyl-5(4)-hydroxymethylimidazole
- 78892-68-9
5-methyl-4-imidazole carboxylic acid methyl ester
| Conditions | Yield |
|---|---|
| With manganese(IV) oxide; sodium cyanide at 20℃; for 20h; Oxidation; esterification; | 70% |
- 29636-87-1
4(5)-methyl-5(4)-hydroxymethylimidazole
- 51605-33-5
4-chloromethyl-5-methyl-imidazole hydrochloride
| Conditions | Yield |
|---|---|
| With hydrogenchloride at 100℃; for 0.5h; | 67% |
4-Hydroxymethyl-5-methylimidazole Chemical Properties
Molecular Structure: 
Appearance:white and light brown crystalsl powde.
Molecular Formula:C5H8N2O.
Molecular Weight:112.1298.
Density:1.231 g/cm3.
Melting Point:136℃.
Boiling Point:389.1 ℃ at 760 mmHg.
Flash Point:189.1 ℃.
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