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Conditions | Yield |
---|---|
With Tris(3,6-dioxaheptyl)amine; sodium nitrite; tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos In tert-butyl alcohol at 130℃; for 24h; Product distribution / selectivity; Inert atmosphere; | 97% |
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; tris(3,5-dioxaheptyl)amine; sodium nitrite In tert-butyl alcohol at 130℃; for 24h; regioselective reaction; | 97% |
quinolin-6-yl triflate
6-nitroquinoline
Conditions | Yield |
---|---|
With Tris(3,6-dioxaheptyl)amine; sodium nitrite; tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos In tert-butyl alcohol at 130℃; for 24h; Product distribution / selectivity; Inert atmosphere; | 94% |
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; tris(3,5-dioxaheptyl)amine; sodium nitrite In tert-butyl alcohol at 130℃; for 24h; regioselective reaction; | 94% |
6-nitro-1,2,3,4-tetrahydroquinoline
6-nitroquinoline
Conditions | Yield |
---|---|
With perylene diimide covalent immobilized to SiO2 nanospheres; air In N,N-dimethyl acetamide at 20℃; UV-irradiation; | 91% |
With iron oxide surrounded by nitrogen doped graphene shell immobilized on carbon support In acetonitrile at 100℃; under 11251.1 Torr; for 24h; Autoclave; | 89% |
With hexagonal boron carbon nitride In water at 25℃; for 12h; Schlenk technique; Inert atmosphere; Irradiation; | 89% |
Conditions | Yield |
---|---|
With potassium nitrite; copper(II) bis(trifluoromethanesulfonate) In dimethyl sulfoxide at 130℃; for 48h; Inert atmosphere; Sealed tube; regioselective reaction; | 82% |
With potassium nitrite; basolite C300 In dimethyl sulfoxide at 130℃; for 48h; Inert atmosphere; | 78% |
6-nitroquinoline-N-oxide
6-nitroquinoline
Conditions | Yield |
---|---|
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; di-tert-butyl 1,4-dihydro-2,6-dimethyl-3,5-pyridine-dicarboxylate In acetonitrile at 20℃; for 0.0833333h; Inert atmosphere; Irradiation; chemoselective reaction; | 73% |
4-nitro-N-2-propynylbenzenamine
6-nitroquinoline
Conditions | Yield |
---|---|
In 1,2-dichloro-ethane at 70℃; for 72h; Sealed tube; | 57% |
Conditions | Yield |
---|---|
With arsenic(III) trioxide Skraup reaction; | 47% |
Conditions | Yield |
---|---|
With sulfuric acid; iodine at 160 - 170℃; for 2h; Cycloaddition; Aromatization; | 18.3% |
With sulfuric acid; nitrobenzene | |
With sulfuric acid; orthoarsenic acid | |
With sulfuric acid; vanadia; sodium 3-nitrobenzenesulfonate at 145℃; | |
With sulfuric acid In water at 36 - 200℃; for 0.25h; Microwave irradiation; Green chemistry; |
6-azidoquinoline
A
6-nitroquinoline
B
3-nitrosoindolizine-8-carbaldehyde
C
C18H12N4O4
Conditions | Yield |
---|---|
With oxygen In acetonitrile at 20℃; Irradiation; | A 14% B n/a C n/a |
With oxygen In acetonitrile at 19.84℃; Irradiation; | A 14% B n/a C n/a |
Conditions | Yield |
---|---|
With sulfuric acid; dihydrogen peroxide; acetic acid und Natriumnitrit; |
IUPAC Name: 6-Nitroquinoline
Synonyms: 6-Nitroquinoline ; 6-Nitro-quinolin ; Quinoline,6-nitro- ; 6-Nitroquinoline98% ; 6-Nitrochinolin ; 6-Nitro Quinoline - 50g
Product Categories: Nitroquinolines;Quinolines;Building Blocks;Heterocyclic Building Blocks
Molecular Structure of 6-Nitroquinoline (CAS NO.613-50-3) :
Molecular Formula of 6-Nitroquinoline (CAS NO.613-50-3) : C9H6N2O2
Molecular Weight of 6-Nitroquinoline (CAS NO.613-50-3) : 174.16
CAS NO: 613-50-3
EINECS: 210-346-6
BRN : 136138
Index of Refraction: 1.682
Surface Tension: 61.8 dyne/cm
Density: 1.354 g/cm3
Flash Point: 156.7 °C
Enthalpy of Vaporization: 55.56 kJ/mol
Boiling Point: 335.4 °C at 760 mmHg
Vapour Pressure: 0.000233 mmHg at 25°C
Melting point 151-153 ºC
Appearance:beige to light brown powder
6-Nitroquinoline (CAS NO.613-50-3) is used in organic synthesis.
With P-Nitroaniline as raw materials, condensation with Acrolein, after cyclization,obtainedof 6-Nitroquinoline (CAS NO.613-50-3), or cyclization with the glycerol,obtained of 6-Nitroquinoline (CAS NO.613-50-3).
1. | mma-sat 100 µmol/plate | MUREAV Mutation Research. 58 (1978),11. | ||
2. | mmo-esc 5700 nmol/L | ENMUDM Environmental Mutagenesis. 3 (1981),11. |
Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also 2-NITROQUINOLINE; 5-NITROQUINOLINE; 8-NITROQUINOLINE; 4-NITROQUINOLINE-N-OXIDE.
Hazard Codes Xn
Risk Statements 20/21/22-40
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
R40:Limited evidence of a carcinogenic effect.
Safety Statements 7-22-36-45
S7:Keep container tightly closed.
S22:Do not breathe dust.
S36:Wear suitable protective clothing.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
WGK Germany 3
RTECS VC1900000