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Bicyclo(2,2,2)-2-octene

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Name

Bicyclo(2,2,2)-2-octene

EINECS N/A
CAS No. 931-64-6 Density 0.93 g/cm3
PSA 0.00000 LogP 2.36260
Solubility N/A Melting Point 111.4°C
Formula C8H12 Boiling Point 138.3 °C at 760 mmHg
Molecular Weight 108.183 Flash Point 18.5 °C
Transport Information N/A Appearance N/A
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 931-64-6 (2,2,2-BICYCLO-2-OCTENE) Hazard Symbols N/A
Synonyms

BICYCLO(2.2.2)OCT-2-ENE;bicyclo[2.2.2]oct-2-ene;3,6-Endoethylenecyclohexene;

Article Data 39

Bicyclo(2,2,2)-2-octene Synthetic route

94064-42-3

Bicyclo[2.2.2]octanon-(2)-p-toluolsulfonylhydrazonn

931-64-6

norbornene

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; methyllithium99%
With N,N,N,N,-tetramethylethylenediamine; methyllithium In diethyl ether cooling;99 % Chromat.

endo-bicyclo<2.2.2>oct-5-en-2-ol mesylate

931-64-6

norbornene

Conditions
ConditionsYield
With lithium triethylborohydride In tetrahydrofuran at 60℃; for 4h;83%
77550-13-1

5-(phenylsulfonyl)bicyclo<2.2.2>oct-2-ene

931-64-6

norbornene

Conditions
ConditionsYield
With disodium hydrogenphosphate; sodium amalgam In tetrahydrofuran; methanol for 3.5h;78.5%
With sodium amalgam; Na2HPO4 buffer In methanol at -20℃;78%
7131-66-0

Bicyclo<2.2.2>octane-2,3-di-exo-carboxylic anhydride

931-64-6

norbornene

Conditions
ConditionsYield
With lead dioxide at 250℃;
51677-42-0

acetic acid bicyclo[2.2.2]oct-2-yl ester

931-64-6

norbornene

Conditions
ConditionsYield
at 400℃;
2220-40-8

bicyclo[2.2.2]oct-5-en-2-one

931-64-6

norbornene

Conditions
ConditionsYield
With hydrazine hydrate anschliessend Erhitzen mit Kaliumhydroxid und Diaethylenglykol auf 220grad;
74-85-1

ethene

1165952-91-9

cyclohexa-1,3-diene

931-64-6

norbornene

Conditions
ConditionsYield
at 250℃;
at 280℃;
74-85-1

ethene

1165952-91-9

cyclohexa-1,3-diene

123-31-9

hydroquinone

931-64-6

norbornene

Conditions
ConditionsYield
at 250℃; under 58840.6 Torr;
90893-09-7

1-phenyl-3-(bicyclo<2.2.2>octan-2-yl)triazene

A

931-64-6

norbornene

C

285-43-8

tricyclo<3.2.1.02,7>octane

D

51677-42-0

bicyclo<2.2.2>oct-2-yl-acetate

93638-25-6, 93638-27-8

N-(endo-bicyclo<3.2.1>)oct-2-yl-aniline

Conditions
ConditionsYield
With sodium acetate; acetic acid Product distribution; Mechanism; deamination reactions of amine via triazene;
90893-13-3

ethyl N-nitroso-N-(bicyclo<3.2.1>octan-2-yl)carbamate

A

931-64-6

norbornene

823-02-9, 61617-43-4, 84235-38-1

Bicyclo<3.2.1>oct-2-ene

C

93638-23-4

N-(bicyclo<2.2.2>octyl)aniline

D

285-43-8

tricyclo<3.2.1.02,7>octane

E

93638-31-4

(1R,3R,5S)-Bicyclo[3.2.1]oct-3-yl-phenyl-amine

93638-25-6, 93638-27-8

N-(exo-bicyclo<3.2.1>oct-2-yl)aniline

Conditions
ConditionsYield
With ethanol Product distribution; Mechanism; deamination reactions of amine via nitrosocarbamate;

Bicyclo(2,2,2)-2-octene Specification

The Bicyclo(2,2,2)-2-octene is an organic compound with the formula C8H12. The IUPAC name of this chemical is bicyclo[2.2.2]oct-2-ene. With the CAS registry number 931-64-6, it is also named as 2,2,2-Bicyclo-2-octene.

Physical properties about Bicyclo(2,2,2)-2-octene are: (1)ACD/LogP: 3.31; (2)ACD/LogD (pH 5.5): 3.31; (3)ACD/LogD (pH 7.4): 3.31; (4)ACD/BCF (pH 5.5): 194.03; (5)ACD/BCF (pH 7.4): 194.03; (6)ACD/KOC (pH 5.5): 1511.03; (7)ACD/KOC (pH 7.4): 1511.03; (8)Index of Refraction: 1.506; (9)Molar Refractivity: 34.54 cm3; (10)Molar Volume: 116.2 cm3; (11)Polarizability: 13.69×10-24cm3; (12)Surface Tension: 33.8 dyne/cm; (13)Density: 0.93 g/cm3; (14)Flash Point: 18.5 °C; (15)Enthalpy of Vaporization: 36.01 kJ/mol; (16)Boiling Point: 138.3 °C at 760 mmHg; (17)Vapour Pressure: 8.41 mmHg at 25°C.

Preparation: this chemical can be prepared by 5-benzenesulfonyl-bicyclo[2.2.2]oct-2-ene. This reaction will need reagent 6 percent sodium amalgam, Na2HPO4 and solvent tetrahydrofuran, methanol. The reaction time is 3.5 hours. The yield is about 78.5%.

Uses of Bicyclo(2,2,2)-2-octene: it can be used to produce bicyclo[2.2.2]octane. It will need reagent Raney nickel.

You can still convert the following datas into molecular structure:
(1)SMILES: C\1=C\C2CCC/1CC2
(2)InChI: InChI=1/C8H12/c1-2-8-5-3-7(1)4-6-8/h1-2,7-8H,3-6H2
(3)InChIKey: VIQRCOQXIHFJND-UHFFFAOYAH
(4)Std. InChI: InChI=1S/C8H12/c1-2-8-5-3-7(1)4-6-8/h1-2,7-8H,3-6H2
(5)Std. InChIKey: VIQRCOQXIHFJND-UHFFFAOYSA-N

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