- Action of (2-Benzothiazolyl) Methyllithium with Organic Polar Functions
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(2-Benzothiazolyl) methyllithium reacts quickly at low temprature (-78 deg C) with a variety of organic electrophiles like aldehydes, ketones, carboxylic esters, nitriles and acylchlorides.Such reactions lead to an easy introduction of alcohol, keto-enol
- Costa, Maria Virginia,Brembilla, Alain,Roizard, Denis,Lochon, Pierre
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p. 1541 - 1544
(2007/10/02)
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- Action of (2-Benzothiazolyl)methyllithium with Organic Polar Functions
-
(2-Benzothiazolyl)methyllithium reacts quickly at low temperature (-78 deg C) with a variety of organic electrophiles like aldehydes, ketones, carboxylic esters, nitriles and acyl chlorides.Such reactions lead to an easy introduction of alcohol, keto-enol or amine-enamine functional groups in extracyclic position with a stereoselective preference.These polyfunctional compounds whose synthesis is difficult by other pathways, are interesting, in particular, because of their ability to form intramolecular hydrogen bounds.
- Costa, Maria Virginia,Brembilla, Alain,Roizard, Denis,Lochon, Pierre
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p. 1933 - 1936
(2007/10/02)
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