cas 1266373-40-3, benzyl (S)-2-formyl-2-pentylaziridine-1-carboxylate

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Catalytic asymmetric aziridination of α,β-unsaturated aldehydes
The development, scope, and application of the highly enantioselective organocatalytic aziridination of α,β-unsaturated aldehydes is presented. The aminocatalytic azirdination of α,β-unsaturated aldehydes enables the asymmetric formation of β-formyl aziri
Deiana, Luca,Dziedzic, Pawel,Zhao, Gui-Ling,Vesely, Jan,Ibrahem, Ismail,Rios, Ramon,Sun, Junliang,Cordova, Armando
supporting information; experimental part
p. 7904 - 7917
(2011/08/05)

Organocatalytic enantioselective aziridination of α-substituted α,β-unsaturated aldehydes: Asymmetric synthesis of terminal aziridines
The first example of a highly enantioselective organocatalytic aziridination of α-substituted α,β-unsaturated aldehydes is presented. The reaction is catalyzed by simple chiral amines and gives access to highly functional terminal azirdines containing an
Deiana, Luca,Zhao, Gui-Ling,Lin, Shuangzheng,Dziedzic, Pawel,Zhang, Qiong,Leijonmarck, Hans,Cordova, Armando
supporting information; experimental part
p. 3201 - 3207
(2011/02/23)