Enantioselective organocatalytic formal allylation of α-branched aldehydes
Heteroarylvinyl sulfone 1 has been successfully used as a new sulfonyl Michael acceptor in aminocatalytic reactions with branched aldehydes. Subsequent one-pot Julia-Kocienski olefination allows the challenging preparation of enantiomerically pure α-allylated aldehydes bearing C-α quaternary carbons.
Rodrigo, Eduardo,Morales, Sara,Duce, Sara,Ruano, Jose Luis Garcia,Cid, M. Belen
p. 11267 - 11269
(2011/12/05)
More Articles about upstream products of 1342313-08-9