1342313-08-9Relevant articles and documents
Enantioselective organocatalytic formal allylation of α-branched aldehydes
Rodrigo, Eduardo,Morales, Sara,Duce, Sara,Ruano, Jose Luis Garcia,Cid, M. Belen
, p. 11267 - 11269 (2011/12/05)
Heteroarylvinyl sulfone 1 has been successfully used as a new sulfonyl Michael acceptor in aminocatalytic reactions with branched aldehydes. Subsequent one-pot Julia-Kocienski olefination allows the challenging preparation of enantiomerically pure α-allylated aldehydes bearing C-α quaternary carbons.