- Method and device for preparing 2,3,3,3-tetrafluoropropene
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The invention provides a method and a device for preparing 2,3,3,3-tetrafluoropropene. The device for preparing 2,3,3,3-tetrafluoropropene comprises a circulation flow reactor, a first rectifying tower, a first cooling tower, a second rectifying tower and a second cooling tower. The method provided by the invention adopts a continuous loop reactor technology to realize the technology of separatinghydrogen chloride by-products in real time under the reaction conditions, so that the selectivity of the reaction is greatly improved; since the continuous circulation operation of the raw materialsis realized, the total conversion rate of the reaction is very high. 2,3,3,3-tetrafluoropropene obtained by the method is low in cost; the production technology has the advantages of being few in by-products and wastes and suitable for industrial large-scale production.
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Paragraph 0084; 0088-0090; 0094; 0098-0100
(2019/01/14)
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- PROCESS FOR PREPARING FLUORINE-CONTAINING PROPANE
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The present invention provides a process for preparing a fluorine-containing propane represented by the formula: CF2XCF2CH3 wherein X is F or Cl, the process including reacting tetrafluoroethylene and methyl chloride in the presence of an antimony halide represented by the formula: SbFxC5-x wherein x is a value of 0 to 5. According to the present invention, the fluorine-containing propane represented by the formula: CF2XCF2CH3 wherein X is F or Cl, which is useful as a starting material of 2,3,3,3-tetrafluoropropene (1234yf), can be obtained by a simple process, using relatively inexpensive starting materials.
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Page/Page column 8-9
(2010/12/17)
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- PROCESS FOR PRODUCTION OF 2,3,3,3-TETRAFLUOROPROPENE
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The present invention provides a process for producing 2,3,3,3-tetrafluoropropene including the following reaction steps: (i) reducing a halogenated fluoropropane represented by formula (1): ACF2CF2CH2FyAz, wherein A is Cl, Br, or I; x is an integer from 0 to 2; y and z are each an integer from 0 to 3; and the total number of x, y, and z is 3, to produce a 1-halogenated-1,1,2,2-tetrafluoropropane represented by formula (2): ACF2CF2CH3; and (ii) contacting the 1-halogenated-1,1,2,2-tetrafluoropropane obtained in step (i) with a catalyst in a gas phase to produce 2,3,3,3-tetrafluoropropene. According to the invention, 2,3,3,3-tetrafluoropropene (HFO-1234yf) can be produced in a high yield, using inexpensive starting materials.
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Page/Page column 19
(2010/04/03)
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- 19F nuclear magnetic resonance studies of halogenated propanes
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The relationship between 19F chemical shifts in halogenated propanes and their structures are elucidated using MNDO calculations to determine the population of rotamers.The pairs of atom gauche to a fluorine atom and van der Waals interaction between the two terminal substituents are responsible for the 19F chemical shifts.The differences among chemical shifts in diastereomers are also discussed in terms of the conformation of molecule.
- Tanuma, T.,Ohnishi, K.,Okamoto, H.,Miyajima, T.,Morikawa, S.
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p. 259 - 284
(2007/10/02)
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