421-75-0Relevant articles and documents
Method and device for preparing 2,3,3,3-tetrafluoropropene
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Paragraph 0084; 0088-0090; 0094; 0098-0100, (2019/01/14)
The invention provides a method and a device for preparing 2,3,3,3-tetrafluoropropene. The device for preparing 2,3,3,3-tetrafluoropropene comprises a circulation flow reactor, a first rectifying tower, a first cooling tower, a second rectifying tower and a second cooling tower. The method provided by the invention adopts a continuous loop reactor technology to realize the technology of separatinghydrogen chloride by-products in real time under the reaction conditions, so that the selectivity of the reaction is greatly improved; since the continuous circulation operation of the raw materialsis realized, the total conversion rate of the reaction is very high. 2,3,3,3-tetrafluoropropene obtained by the method is low in cost; the production technology has the advantages of being few in by-products and wastes and suitable for industrial large-scale production.
PROCESS FOR PRODUCTION OF 2,3,3,3-TETRAFLUOROPROPENE
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Page/Page column 19, (2010/04/03)
The present invention provides a process for producing 2,3,3,3-tetrafluoropropene including the following reaction steps: (i) reducing a halogenated fluoropropane represented by formula (1): ACF2CF2CH2FyAz, wherein A is Cl, Br, or I; x is an integer from 0 to 2; y and z are each an integer from 0 to 3; and the total number of x, y, and z is 3, to produce a 1-halogenated-1,1,2,2-tetrafluoropropane represented by formula (2): ACF2CF2CH3; and (ii) contacting the 1-halogenated-1,1,2,2-tetrafluoropropane obtained in step (i) with a catalyst in a gas phase to produce 2,3,3,3-tetrafluoropropene. According to the invention, 2,3,3,3-tetrafluoropropene (HFO-1234yf) can be produced in a high yield, using inexpensive starting materials.