REACTION OF AZINIUM CATIONS.5.* ADDITION OF WATER AND METHANOL TO 1,4-DIAZINIUM CATIONS IN THE PRESENCE OF BASES. EQUILIBRIUM CONSTANTS AND PMR SPECTRA OF THE MONO- AND DIADDUCTS
The PKR* values and equilibrium constants for the addition of hydroxide ions to 1,4-diazinium ions were determined by spectrophotometry.The ratios 1:1 and 1:2 of the methoxyl adducts of the 1,4-diazinium ions in the sodium methoxide-methanol-D4 system and the equilibrium constants for the transformations of the monoadducts into the diaddition products were determined by PMR spectroscopy.
Charushin, V. N.,Kazantseva, I. V.,Ponizovskii, M. G.,Egorova, L.G.,Sidorov, E.O.,Chupakhin, O. N.
p. 1118 - 1125
(2007/10/02)
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