58219-37-7Relevant articles and documents
REACTION OF AZINIUM CATIONS.5.* ADDITION OF WATER AND METHANOL TO 1,4-DIAZINIUM CATIONS IN THE PRESENCE OF BASES. EQUILIBRIUM CONSTANTS AND PMR SPECTRA OF THE MONO- AND DIADDUCTS
Charushin, V. N.,Kazantseva, I. V.,Ponizovskii, M. G.,Egorova, L.G.,Sidorov, E.O.,Chupakhin, O. N.
, p. 1118 - 1125 (2007/10/02)
The PKR* values and equilibrium constants for the addition of hydroxide ions to 1,4-diazinium ions were determined by spectrophotometry.The ratios 1:1 and 1:2 of the methoxyl adducts of the 1,4-diazinium ions in the sodium methoxide-methanol-D4 system and the equilibrium constants for the transformations of the monoadducts into the diaddition products were determined by PMR spectroscopy.