Host (Nanocavity of aluminium-incorporated mesoporous KIT-6)-guest (12-tungesto(molybdato) phosphoric acid) nanocomposite material: Efficient and reusable catalysts for the Hosomi-Sakurai three-component coupling reaction
The immobilization of heteropoly acids (HPAs) into the Al-functionalized KIT-6 mesoporous molecular sieve has been carried out to see the effect of Al-KIT-6 as a host matrix on the HPA activities. These modified mesoporous molecular sieves are effective c
Cesium salt of tungstosilicic acid fabricated by nano-casting strategy: An efficient catalyst for the three-component Hosomi-Sakurai reaction
We have used SBA-15 silicas as hard templates for the nano-fabrication of Cs1.8H2.2SiW12O40 (CsHSiW) salt nanocrystal. The elimination by HF (or NaOH 90 °C) in the silica matrix from the composites occurred by a
Fazaeli, Razieh,Aliyan, Hamid,Bagi, Mohammad Javad
experimental part
p. 677 - 688
(2012/06/18)
REGIOSPECIFIC ALLYLATION OF ACETALS WITH ALLYLSILANES CATALYZED BY IODOTRIMETHYLSILANE. SYNTHESIS OF HOMOALLYLETHERS
Allylation of acetals with allylsilanes is catalyzed by iodotrimethylsilane to give the corresponding homoallyl ethers, with regiospecific transposition of the allyl group.
Sakurai, Hideki,Sasaki, Koshi,Hosomi, Akira
p. 745 - 748
(2007/10/02)
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