- Haloalkylation process
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A process for the haloalkylation of certain tin, phosphorus and germanium halides is disclosed. The process is carried out typically in a halocarbon solvent at temperatures of less than 0° C. using as the haloalkylating reagent an admixture of a haloalkyl halide and tris(lower alkylamino)phosphine.
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- DARSTELLUNG UND NMR-SPEKTROSKOPISCHE CHARAKTERISIERUNG EINIGER DI-n-ALKYL- UND n-ALKYLARYL-CHLOROPHOSPHANE
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A series of di-n-alkyl and n-alkylaryl chlorophosphines has been prepared by the reaction of tetraorganodiphosphines with chlorodiphenyl or dichlorophenyl phosphine and characterized by 31P and 13C NMR spectra.
- Wolfsberger, W
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p. 167 - 174
(2007/10/02)
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- Process for making tetramethyldiphosphinomethane
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Novel chemical compounds which comprise tetramethyldiphosphinomethane of the formula: and methyllithium-dimethylphosphine of the formula: the latter being an intermediate product. Methyllithium-dimethylphosphine is made by reacting a solution of trimethylphosphine with a solution of alkyllithium in an inert solvent with the exclusion of air and moisture, filtering the resulting white precipitate, washing it with the inert solvent, and drying the washed material. Tetramethyldiphosphinomethane is made by reacting, with agitation, a suspension of methyllithium-dimethylphosphine, or dilithiomethane of the formula Li(CH)2 or magnesiomethane of the formula MgCH2 in an organic solvent with dimethylchlorophosphine and distilling the resulting reaction mixture.
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