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Chemical Reaction - Basic Chemical -

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  • Kolbe Electrolytic Synthesis
  • Kolbe Electrolytic Synthesis; Crum Brown-Walker Reaction H. Kolbe, Ann. 69, 257 (1849). Formation of symmetrical dimers by the electrolysis of carboxyla
  • Criegee Reaction
  • Criegee Reaction R. Criegee, Ber. 64, 260 (1931). Oxidative cleavage of vicinal glycols by lead tetraacetate: Rev
  • Craig Method
  • Craig Method L. C. Craig, J. Am. Chem. Soc. 56, 231 (1934). Introduction of a halogen into the α-position of aminos by treatment with sodium nitri
  • Friedel-Crafts Reaction
  • Friedel-Crafts Reaction C. Friedel, J. M. Crafts, Compt. Rend. 84, 1392, 1450 (1877). The alkylation or acylation of aromatic compounds catalyzed by alu
  • Perkin Rearrangement
  • Perkin Rearrangement (Coumarin-Benzofuran Ring Contraction) W. H. Perkin, J. Chem. Soc. 23, 368 (1870). Formation of benzofuran-2-carboxylic acids and b
  • Cornforth Rearrangement
  • Cornforth Rearrangement J. W. Cornforth, The Chemistry of (Princeton University Press, New Jersey, 1949) p 700. Thermal rearrangement of 4-carbonyl sub
  • Corey-Winter Olefin Synthesis
  • Corey-Winter Olefin Synthesis E. J. Corey, R. A. E. Winter, J. Am. Chem. Soc. 85, 2677 (1963). Synthesis of olefins from 1,2-diols and thiocarbonyldiimi
  • Corey-Kim Oxidation
  • Corey-Kim Oxidation E. J. Corey, C. U. Kim, J. Am. Chem. Soc. 94, 7586 (1972). Oxidation of primary and secondary alcohols via their alkoxysulfonium sal
  • Cope Rearrangement
  • Cope Rearrangement; Oxy-Cope Rearrangement A. C. Cope et al., J. Am. Chem. Soc. 62, 441 (1940). Highly stereoselective [3,3]-sigmatropic rearrangement o
  • Cope Elimination Reaction
  • Cope Elimination Reaction A. C. Cope et al., J. Am. Chem. Soc. 71, 3929 (1949); idem et al., ibid. 75, 3212 (1953). Formation of an olefin and a hydroxy
  • Sandmeyer Reaction
  • Sandmeyer Reaction; Gattermann Reaction; Körner-Contardi Reaction T. Sandmeyer, Ber. 17, 1633, 2650 (1884); L. Gattermann, Ber. 23, 1218 (1890); G. Körner, A. Co
  • Conrad-Limpach Cyclization
  • Conrad-Limpach Cyclization M. Conrad, L. Limpach, Ber. 20, 944 (1887); 24, 2990 (1891). Thermal condensation of arylamines with β-ketoesters follow
  • Combes Quinoline Synthesis
  • Combes Synthesis A. Combes, Bull. Soc. Chim. France 49, 89 (1888). Formation of quinolines by condensation of β-diketones with primary arylamines
  • Gabriel-Colman Rearrangement
  • Gabriel-Colman Rearrangement (Phthalimidoacetic Ester→ Rearrangement, Gabriel Isoquinoline Synthesis) S. Gabriel, J. Colman, Ber. 33, 980, 996, 2630 (1900); 35, 2421
  • Sarett Oxidation
  • Sarett Oxidation; Collins Oxidation G. I. Poos, G. E. Arth, R. E. Beyler, L. H. Sarett, J. Am. Chem. Soc. 75, 422 (1953). Oxidation of primary and secon
  • Clemmensen Reduction
  • Clemmensen Reduction E. Clemmensen, Ber. 46, 1837 (1913); 47, 51, 681 (1914). Reduction of carbonyl groups of aldehydes and ketones to methylene groups
  • Leuckart (Leukart) Reaction
  • Leuckart (Leukart) Reaction; Leuckart-Wallach Reaction; Eschweiler-Clarke Reaction R. Leuckart, Ber. 18, 2341 (1885). Reductive alkylation of ammonium (
  • Claisen-Schmidt Condensation
  • Claisen-Schmidt Condensation L. Claisen, A. Claparède, Ber. 14, 2460 (1881); J. G. Schmidt, ibid. 1459. Condensation of an aromatic aldehyde with
  • Claisen Rearrangement
  • Claisen Rearrangement; Eschenmoser-Claisen Rearrangement; Johnson-Claisen Rearrangement; Ireland-Claisen Rearrangement L. Claisen, Ber. 45, 3157 (1912); L. Claisen, E. Tie
  • Darzens Condensation
  • Darzens Condensation (Darzens-Claisen Reaction, Glycidic Ester Condensation) G. Darzens, Compt. Rend. 139, 1214 (1904); 141, 766 (1905); 142, 214 (1906).
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