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Chemical Reaction - Basic Chemical -

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  • Beckmann Rearrangement
  • Beckmann Rearrangement; Beckmann Fragmentation E. Beckmann, Ber. 19, 988 (1886). Acid-mediated isomerization of oximes to amides. Oximes of cyclic keton
  • Béchamp Reduction
  • Béchamp Reduction A. J. Béchamp, Ann. Chim. Phys. 42(3), 186, (1854). Reduction of aromatic nitro compounds to the corresponding amines by
  • Baylis-Hillman Reaction
  • Baylis-Hillman Reaction A. B. Baylis, M. E. D. Hillman, DE 2155113; eidem, US 3743669 (1972, 1973 both to Celanese). Coupling of activated vinyl systems
  • Schotten-Baumann Reaction
  • Schotten-Baumann Reaction C. Schotten, Ber. 17, 2544 (1884); E. Baumann, ibid. 19, 3218 (1886). Acylation of alcohols or amines with acid chlorides in a
  • Haller-Bauer Reaction
  • Haller-Bauer Reaction A. Haller, E. Bauer, Compt. Rend. 148, 70, 127 (1909); 149, 5 (1909). Cleavage of non-enolizable ketones with sodium amide; freque
  • Baudisch Reaction
  • Baudisch Reaction O. Baudisch et al., Naturwiss. 27, 768, 769 (1939); Science 92, 336 (1940); J. Am. Chem. Soc. 63, 622 (1941). Synthesis of o-nitrosoph
  • Barton-Zard Reaction
  • Barton-Zard Reaction D. H. R. Barton et al., Tetrahedron 46, 7587 (1990). Formation of a pyrrole by condensation of a substituted nitroso-alkene with an
  • Barton Reaction
  • Barton Reaction D. H. R. Barton et al., J. Am. Chem. Soc. 82, 2640 (1960); 83, 4076 (1961). Conversion of a nitrite ester to a γ-oximino alcohol b
  • Barton Olefin Synthesis
  • Barton Olefin Synthesis (Barton-Kellogg Reaction) D. H. R. Barton et al., Chem. Commun. 1970, 1226; R. M. Kellogg, S. Wassenaar, Tetrahedron Letters 1970, 1987; R. M. Kell
  • Barton Deoxygenation
  • Barton Deoxygenation (Barton-McCombie Reaction) D. H. R. Barton, S. W. McCombie, Perkin Trans. I 1975, 1574. Deoxygenation of alcohols via their thiocar
  • Barton Decarboxylation
  • Barton Decarboxylation D. H. R. Barton et al., Chem. Commun. 1983, 939; eidem, Tetrahedron 41, 3901 (1985). Radical decarboxylation of organic acids to
  • Bart Reaction
  • Bart Reaction; Scheller Modification H. Bart, DE 250264 (1910); DE 254092 (1910); DE 264924 (1910); DE 268172 (1912); Ann. 429, 55 (1922); E. Scheller, GB 261026; A. W. Ru
  • Barbier-Wieland Degradation
  • Barbier-Wieland Degradation H. Wieland, Ber. 45, 484 (1912); P. Barbier, R. Locquin, Compt. Rend. 156, 1443 (1913). Stepwise carboxylic acid degradation
  • Barbier(-type) Reaction
  • Barbier(-type) Reaction P. Barbier, C. R. Acad. Sci. 128, 110 (1899). One-step procedure for the preparation of alcohols from organic halides and aldehy
  • Bamford-Stevens Reaction
  • Bamford-Stevens Reaction; Shapiro Reaction W. R. Bamford, T. S. Stevens, J. Chem. Soc. 1952, 4735. Formation of olefins by base-promoted decomposition o
  • Bamberger Rearrangement
  • Bamberger Rearrangement E. Bamberger, Ber. 27, 1347, 1548 (1894). Intermolecular rearrangement of N-phenylhydroxylamines in aqueous acid to give the cor
  • Schiemann Reaction
  • Schiemann Reaction (Balz-Schiemann Reaction) G. Balz, G. Schiemann, Ber. 60, 1186 (1927). Formation of diazonium fluoroborates by diazotization of aroma
  • Corey-Bakshi-Shibata Reduction
  • Corey-Bakshi-Shibata Reduction (CBS) E. J. Corey et al., J. Am. Chem. Soc. 109, 5551 (1987). Enantioselective borane reduction of ketones catalyzed by c
  • Baker-Venkataraman Rearrangement
  • Baker-Venkataraman Rearrangement W. Baker, J. Chem. Soc. 1933, 1381; H. S. Mahal, K. Venkataraman, ibid. 1934, 1767. Base-catalyzed rearrangement of o-a
  • Baeyer-Villiger Reaction
  • Baeyer-Villiger Reaction A. Baeyer, V. Villiger, Ber. 32, 3625 (1899); 33, 858 (1900). The oxidation of ketones to esters or lactones by peracids:
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