Hofmann-Sand Reactions

K. A. Hofmann, J. Sand, Ber. 33, 1340, 1353 (1900).

Olefin mercuration with mercuric salts (halides, acetates, nitrates, or sulfates) in aqueous solution. In alcoholic solutions the accelerated reaction produces alkoxyalkyl compounds:



J. Sand, Ber. 34, 1385, 2906, 2910 (1901); Ann. 329, 135 (1903); J. Chatt, Chem. Rev. 48, 7 (1951); E. R. Rochow et al., Chemistry of Organometallic Compounds (New York, 1957) p 109; W. Kitching, Organomet. Chem. Rev. 3, 35 (1968); K. P. Geller, H. Straub, Houben-Weyl 13/2b, 130 (1974).