- Chlorine
- Chlorine azide
- Chlorine dioxide
- CHLORINE DIOXYGEN TRIFLUORIDE
- Chlorine nitrate
- Chlorine pentafluoride
- Chlorine perchlorate
- Chlorine trifluoride
- CHLORINE(1)TRIFLUOROMETHANE-SULFONATE
- Chlorine, atomic
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Cas Database |
| Name |
Chlorine perchlorate |
EINECS | N/A |
| CAS No. | 27218-16-2 | Density | g/cm3 |
| PSA | N/A | LogP | N/A |
| Solubility | N/A | Melting Point |
N/A |
| Formula | Cl2O4 | Boiling Point | °Cat760mmHg |
| Molecular Weight | 134.904 | Flash Point | °C |
| Transport Information | N/A | Appearance | N/A |
| Safety | A shock-sensitive explosive. Potentially explosive reaction with chlorotrifluoroethylene, perfluoroalkyl iodides (e.g., perfluoromethyl iodide, 1,2-diiodoperfluoroethane, 1,3-diiodoperfluoropropane). When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINE and PERCHLORATES. | Risk Codes | N/A |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Chlorineoxide (Cl2O4) (8CI);Chlorine chlorate oxide [Cl(ClO3)O];Chlorine perchlorate; |
Article Data | 3 |
Chlorine perchlorate Chemical Properties
IUPAC Name: Chloro perchlorate
Empirical Formula: Cl2O4
Molecular Weight: 134.9036g/mol
XLogP3-AA :3.6
H-Bond Donor: 0
H-Bond Acceptor: 4
Rotatable Bond Count: 0
Exact Mass: 133.917364
MonoIsotopic Mass: 133.917364
Topological Polar Surface Area: 60.4
Heavy Atom Count: 6
Formal Charge: 0
Complexity: 128
SMILES: ClOCl(=O)(=O)=O
InChI: InChI=1/Cl2O4/c1-6-2(3,4)5
InChIKey: JRONPIZRZBBOBR-UHFFFAOYAQ
Structure of Chlorine perchlorate (CAS NO.27218-16-2):
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Chlorine perchlorate Safety Profile
A shock-sensitive explosive. Potentially explosive reaction with chlorotrifluoroethylene, perfluoroalkyl iodides (e.g., perfluoromethyl iodide, 1,2-diiodoperfluoroethane, 1,3-diiodoperfluoropropane). When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINE and PERCHLORATES.
Chlorine perchlorate Specification
Chlorine perchlorate , its cas register number is 27218-16-2. It also can be called Chlorine perchlorate is the chemical compound with the formula Cl2O4. This chlorine oxide is an asymmetric oxide, with one chlorine atom in oxidation state +1 and the other +7, with proper formula ClOClO3.
2 ClO2 + UV(λ=436nm) → ClOClO3
Chlorine perchlorate reacts with metal chlorides forming anhydrous perchlorates:
CrO2Cl2 + 2ClOClO3 → 2Cl2 + CrO2(ClO4)2
TiCl4 + 4ClOClO3 → 4Cl2 + Ti(ClO4)4
Chlorine perchlorate (CAS NO.27218-16-2) is pale greenish liquid which decomposes at room temperature. When heated to decomposition it emits toxic fumes of Cl−.
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