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Chromium hydroxide sulfate

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Name

Chromium hydroxide sulfate

EINECS 235-595-8
CAS No. 12336-95-7 Density 1.57 g/cm3
PSA 111.70000 LogP -0.43400
Solubility 1000g/L Melting Point >900oC
Formula CrHO5S Boiling Point 102oC
Molecular Weight 165.07 Flash Point N/A
Transport Information N/A Appearance dark green liquid
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 12336-95-7 (Chromium sulfate,basic,solid) Hazard Symbols N/A
Synonyms

Chromiumsulfate (Cr(OH)SO4) (6CI);Actan CRM 1;Basic chromic sulfate;Basic chromiumsulfate;Chromedol;Monobasic chromium sulfate;Neochrome (tanningagent);Neochrome R;Peachrome;Sulfuric acid, chromium salt, basic;Chromium hydroxidesulfate (Cr(OH)(SO4));

 

Chromium hydroxide sulfate Consensus Reports

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 49 , 1990,p. 49.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 49 , 1990,p. 49.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 49 , 1990,p. 49.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Chromium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Chromium hydroxide sulfate Standards and Recommendations

OSHA PEL: TWA 0.5 mg(Cr)/m3
ACGIH TLV: TWA 0.5 mg(Cr)/m3; Not Classifiable as a carcinogen

Chromium hydroxide sulfate Specification

The Chromium hydroxide sulfate, with the CAS registry number 12336-95-7, is also known as Monobasic chromium sulfate. It belongs to the product category of Inorganics. Its EINECS registry number is 235-595-8. This chemical's molecular formula is CrHO5S and molecular weight is 165.06604. Its IUPAC name is called chromium(3+) hydroxide sulfate. This chemical's classification codes are Human Data; Mutation data; Skin / Eye Irritant; Tumor data. It should be stored in a cool, ventilated, dry coffers. Its Containers should be sealed from moisture. It is dark green liquid.

Physical properties of Chromium hydroxide sulfate: (1)H-Bond Donor: 1; (2)H-Bond Acceptor: 5; (3)Rotatable Bond Count: 0; (4)#H bond acceptors: 5; (5)#H bond donors: 3; (6)#Freely Rotating Bonds: 0; (7)Polar Surface Area: 88.64 Å2.

Preparation: this chemical can be prepared by sodium dichromate liquor and sodium bisulfate. This reaction will need reducing agent sucrose. Then obtained solid products of basic chromium sulphate.

8Na2Cr2O7+48NaHSO4+C12H22Ol1→16Cr(OH)SO4+32Na2SO4+43H2O+12CO2
8Na2Cr2O7+24H2SO4+C12H22O11→16Cr(OH)SO4+8Na2SO4+27H2O+12CO2

Uses of Chromium hydroxide sulfate: It mainly used for tanning leather. In addition, it is also the materials of producting hydrogen chromium. This chemical also can be used for the production of reactive black dye in dye industry. What's more, it is used as a mordant in printing and dyeing industry.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: [OH-].[O-]S(=O)(=O)[O-].[Cr+3]
(2)InChI: InChI=1S/Cr.H2O4S.H2O/c;1-5(2,3)4;/h;(H2,1,2,3,4);1H2/q+3;;/p-3
(3)InChIKey: DSHWASKZZBZKOE-UHFFFAOYSA-K

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 2900mg/kg (2900mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA

BEHAVIORAL: IRRITABILITY
Toksikologicheskii Vestnik. Vol. (2), Pg. 34, 1998.
rat LD50 oral 7760mg/kg (7760mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA

BEHAVIORAL: IRRITABILITY
Toksikologicheskii Vestnik. Vol. (2), Pg. 34, 1998.
women LDLo oral 960mg/kg (960mg/kg) CARDIAC: OTHER CHANGES

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF ENDOCRINE PANCREAS

GASTROINTESTINAL: NECROTIC GHANGES
Intensive Care Medicine. Vol. 20, Pg. 145, 1994.

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