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Cas Database |
| Name |
Copper,bromotris(triphenylphosphine)-, (T-4)- |
EINECS | N/A |
| CAS No. | 15709-74-7 | Density | N/A |
| PSA | 40.77000 | LogP | 11.17750 |
| Solubility | N/A | Melting Point |
168-170 °C(lit.) |
| Formula | C54H45BrCuP3 | Boiling Point | 360 °C at 760 mmHg |
| Molecular Weight | 930.323 | Flash Point | 181.7 °C |
| Transport Information | N/A | Appearance | N/A |
| Safety | 22-24/25 | Risk Codes | N/A |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Copper,bromotris(triphenylphosphine)- (7CI,8CI);Bromotris(triphenylphosphine)copper;Bromocopper-triphenylphosphane (1:3);Bromotris(triphenylphosphine)copper(I); |
Article Data | 17 |
Copper,bromotris(triphenylphosphine)-, (T-4)- Synthetic route
- 603-35-0
triphenylphosphine
- 7789-45-9
copper(ll) bromide
- 15709-74-7
bromotris(triphenylphosphine)copper(I)
| Conditions | Yield |
|---|---|
| In methanol for 0.5h; Heating / reflux; | 93% |
| In methanol for 0.5h; Heating / reflux; | 93% |
| In acetone to soln. of bromide in hot acetone soln. of triphenylphosphine in hot acetone added dropwise with stirring, refluxed for several h; filterd, washed with petroleum ether, dried for several h in vac.; elem.anal.; | 34% |
- 603-35-0
triphenylphosphine
- 7787-70-4
copper(I) bromide
- 15709-74-7
bromotris(triphenylphosphine)copper(I)
| Conditions | Yield |
|---|---|
| In methanol for 4 - 5h; | 90% |
| In methanol for 0.5h; Reflux; | 87% |
| In acetonitrile at 80℃; for 1h; Inert atmosphere; | 71% |
| In chloroform pptd. from CHCl3 soln. of stoich. amt. of CuBr and PPh3; according to P.F. Barron et al., J. Chem. Soc., Dalton Trans., 1987, 1099 and G. Costa , E. Reisenhofer and L. Stefani, J. Inorg. Nucl. Chem., 1965, 27, 2581; | |
| In methanol at 60℃; for 0.166667h; | 1.18 g |
- 15709-74-7
bromotris(triphenylphosphine)copper(I)
| Conditions | Yield |
|---|---|
| With triphenylphosphine In methanol copper halogenide : triphenylphosphine = 1 : 3.5, intensive stirring; suction and drying in high vac., elem. anal.; |
- 7787-70-4
copper(I) bromide
- 15709-74-7
bromotris(triphenylphosphine)copper(I)
| Conditions | Yield |
|---|---|
| With triphenylphosphine In dichloromethane stoich. amts. Ph3P and CuBr mixed in small volume methylene chloride; pentane, hexane or cyclohexane added until ppt. began to form, soln. cooled in ice bath and allowed to stand for a few minutes and filtered; | |
| With triphenyl phosphine In chloroform Stoicheiometric quantities of reagents were refluxed for 2-4 h in CHCl3;; the hot soln. was filtered, slow cooling and evapd.;; |
- 15709-74-7
bromotris(triphenylphosphine)copper(I)
- 2010-15-3
3-phenyl-2-thioxoimidazolidin-4-one
- 144886-62-4
{Cu(P(C6H5)3)2(C6H5NC(O)CH2NHC(S))Br}
| Conditions | Yield |
|---|---|
| In benzene byproducts: triphenylphosphine; addn. of ligand to Cu complex soln.; refluxing, 2h; cooling; filtration; evapn. to half the volume; addn. of petroleum ether; standing, 2-3h; pptn.; centrifuging; washing (petroleum ether); drying (vac.); elem. anal.; | 96% |
- 15709-74-7
bromotris(triphenylphosphine)copper(I)
- 63400-51-1
bis(1,2,4-triazol-1-yl)methane
- 166662-57-3
[(P(C6H5)3)Cu(C5H6N6)Br]
| Conditions | Yield |
|---|---|
| In acetone byproducts: Ph3P; stirring; elem. anal.; | 96% |
- 15093-54-6
N-phenyl-1-morpholinethiocarbamide
- 15709-74-7
bromotris(triphenylphosphine)copper(I)
- 144886-68-0
{Cu(P(C6H5)3)2(C6H5NHC(S)N(CH2CH2)2O)Br}
| Conditions | Yield |
|---|---|
| In benzene byproducts: triphenylphosphine; addn. of ligand to Cu complex soln.; refluxing, 2h; cooling; filtration; evapn. to half the volume; addn. of petroleum ether; standing, 2-3h; pptn.; centrifuging; washing (petroleum ether); drying (vac.); elem. anal.; | 90% |
- 66-71-7
1,10-Phenanthroline
- 15709-74-7
bromotris(triphenylphosphine)copper(I)
- 25753-84-8
(1,10-phenanthroline)(triphenylphosphine)CuBr
| Conditions | Yield |
|---|---|
| In chloroform | 90% |
| In chloroform at 20℃; for 0.166667h; | 90% |
| In chloroform at 20℃; for 0.5h; | 75% |
| In chloroform at 20℃; for 0.5h; | 75% |
| In dichloromethane for 2h; Inert atmosphere; |
| Conditions | Yield |
|---|---|
| In chloroform | 89% |
- 288-13-1
NH-pyrazole
- 15709-74-7
bromotris(triphenylphosphine)copper(I)
- 166662-78-8
[(P(C6H5)3)2Cu(C3H4N2)Br]
| Conditions | Yield |
|---|---|
| In diethyl ether byproducts: Ph3P; stirring (6 h); elem. anal.; | 88% |
Copper,bromotris(triphenylphosphine)-, (T-4)- Specification
The Copper,bromotris(triphenylphosphine)-, (T-4)- with CAS registry number of 15709-74-7 is also known as Bromotris(triphenylphosphine)copper(I). The systematic name is Bromocopper-triphenylphosphane (1:3). It belongs to product categories of Catalysis and Inorganic Chemistry; Chemical Synthesis; CopperMicro/Nanoelectronics; Electronic Chemicals; Others. In addition, the formula is C54H45BrCuP3 and the molecular weight is 930.31. During using it, do not breathe dust and avoid contact with skin and eyes. What's more, it should be sealed in cool, dry place away from oxides and air.
Physical properties about Copper,bromotris(triphenylphosphine)-, (T-4)- are: (1)ACD/LogP: 5.69; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 5.69; (4)ACD/LogD (pH 7.4): 5.69; (5)ACD/BCF (pH 5.5): 12427.96; (6)ACD/BCF (pH 7.4): 12427.96; (7)ACD/KOC (pH 5.5): 29672.91; (8)ACD/KOC (pH 7.4): 29672.91; (9)#Freely Rotating Bonds: 3; (10)Flash Point: 181.7 °C; (11)Enthalpy of Vaporization: 58.18 kJ/mol; (12)Boiling Point: 360 °C at 760 mmHg; (13)Vapour Pressure: 4.74E-05 mmHg at 25 °C.
You can still convert the following datas into molecular structure:
1. SMILES: Br[Cu].c3c(P(c1ccccc1)c2ccccc2)cccc3.c1ccccc1P(c2ccccc2)c3ccccc3.c1ccccc1P(c2ccccc2)c3ccccc3
2. InChI: InChI=1/3C18H15P.BrH.Cu/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
3. InChIKey: QXLPGKOIQZWUPL-REWHXWOFAV
4. Std. InChI: InChI=1S/3C18H15P.BrH.Cu/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
5. Std. InChIKey: QXLPGKOIQZWUPL-UHFFFAOYSA-M
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