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Demeton-S-methyl

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Name

Demeton-S-methyl

EINECS N/A
CAS No. 919-86-8 Density 1.197g/cm3
PSA 95.94000 LogP 2.87360
Solubility 22,000 mg-1 (20 °C) Melting Point <25℃
Formula C6H15 O3 P S2 Boiling Point 287.4oC at 760 mmHg
Molecular Weight 230.289 Flash Point 2oC
Transport Information N/A Appearance N/A
Safety Poison by ingestion, inhalation, skin contact, intraperitoneal, and intravenous routes. Mutation data reported. An insecticide. When heated to decomposition it emits very toxic fumes of POx and SOx. See also DEMETON-O + DEMETON-S and DEMETON; DEMETON-O-METHYL; DEMETON-O-METHYL SULFOXIDE; DEMETON-S; DEMETON-S-METHYL-SULPHONE. Risk Codes 24/25-51/53-36-20/21/22-11
Molecular Structure Molecular Structure of 919-86-8 (DEMETON-S-METHYL) Hazard Symbols T,N,Xn,F
Synonyms

Phosphorothioicacid, S-[2-(ethylthio)ethyl] O,O-di-Me ester (6CI); Demeton-S-methyl; Metaisoseptox;Metaisosystox; Metasystox 55; Metasystox I; Metasystox J; Methyl demetonthioester; Methyl isosystox; Methylthionodemeton; O,O-DimethylS-2-(ethylthio)ethyl phosphorothioate; S-[2-(Ethylthio)ethyl] O,O-dimethylphosphorothioate; S-[2-(Ethylthio)ethyl] O,O-dimethyl thiophosphate; Thiometonoxon

Article Data 40

Demeton-S-methyl Chemical Properties

Product Name: Demeton-S-methyl (CAS NO.919-86-8)


Molecular Formula: C6H15O3PS2
Molecular Weight: g/mol
Mol File: 919-86-8.mol
Einecs: 213-052-6
Boiling point: 287.4 °C at 760 mmHg
Storage Temperature: -18°C
Flash Point: 127.6 °C
Density: 1.197 g/cm3
Water Solubility: 0.33 g/100 ml (20 °C)
Surface Tension: 39.9 dyne/cm
Enthalpy of Vaporization: 50.55 kJ/mol
Vapour Pressure: 0.00429 mmHg at 25°C
XLogP3-AA: 1
H-Bond Donor: 0
H-Bond Acceptor: 3
Structure Descriptors of Demeton-S-methyl (CAS NO.919-86-8):
  IUPAC Name: 1-dimethoxyphosphorylsulfanyl-2-ethylsulfanylethane
  Canonical SMILES: CCSCCSP(=O)(OC)OC
  InChI: InChI=1S/C6H15O3PS2/c1-4-11-5-6-12-10(7,8-2)9-3/h4-6H2,1-3H3 
  InChIKey: WEBQKRLKWNIYKK-UHFFFAOYSA-N

Demeton-S-methyl Uses

 Demeton-S-methyl (CAS NO.919-86-8) is used as an acaricide and insecticide; more specifically it is an organothiophosphate acaricide and an aliphatic organothiophosphate insecticide, respectively.

Demeton-S-methyl Toxicity Data With Reference

1.    

mmo-sat 5 µL/plate

    MUREAV    Mutation Research. 28 (1975),405.
2.    

sln-dmg-orl 80 ppm

    MUREAV    Mutation Research. 28 (1975),405.
3.    

orl-rat LD50:30 mg/kg

    FMCHA2    Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.: )1991,C197.
4.    

ihl-rat LC50:500 mg/m3/4H

    85DPAN    Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel Werner Perkow,Berlin, Germany.: Verlag Paul Parey,1971/76.
5.    

skn-rat LD50:85 mg/kg

    PHJOAV    Pharmaceutical Journal. 185 (1960),361.
6.    

ipr-rat LD50:7500 µg/kg

    TXAPA9    Toxicology and Applied Pharmacology. 4 (1962),621.
7.    

ivn-rat LDLo:54 mg/kg

    BCPCA6    Biochemical Pharmacology. 6 (1961),244.
8.    

orl-gpg LD50:110 mg/kg

    TXAPA9    Toxicology and Applied Pharmacology. 4 (1962),621.
9.    

ipr-gpg LD50:12,500 µg/kg

    TXAPA9    Toxicology and Applied Pharmacology. 4 (1962),621.

Demeton-S-methyl Consensus Reports

Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List.

Demeton-S-methyl Safety Profile

Poison by ingestion, inhalation, skin contact, intraperitoneal, and intravenous routes. Mutation data reported. An insecticide. When heated to decomposition it emits very toxic fumes of POx and SOx. See also DEMETON-O + DEMETON-S and DEMETON; DEMETON-O-METHYL; DEMETON-O-METHYL SULFOXIDE; DEMETON-S; DEMETON-S-METHYL-SULPHONE.
Safety Information of Demeton-S-methyl (CAS NO.919-86-8):
Hazard Codes: TToxic,NDangerous,XnHarmful,FFlammable
Risk Statements:  24/25-51/53-36-20/21/22-11 
11:  Highly Flammable
20:  Harmful by inhalation 
21:  Harmful in contact with skin 
22:  Harmful if swallowed 
24:  Toxic in contact with skin 
25:  Toxic if swallowed 
36:  Irritating to the eyes 
51:  Toxic to aquatic organisms  
53:  May cause long-term adverse effects in the aquatic environment 
Safety Statements: 28-36/37-45-61-26
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
28:  After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 
36:  Wear suitable protective clothing  
37:  Wear suitable gloves 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
61:  Avoid release to the environment. Refer to special instructions safety data sheet 

Demeton-S-methyl Standards and Recommendations

ACGIH TLV: TWA 0.05 ppm (skin)(sensitizer); Not Classifiable as a Human Carcinogen

Demeton-S-methyl Specification

 Demeton-S-methyl ,its CAS NO. is 919-86-8,the synonyms is 2-Ethylthioethyl dimethyl phosphorothioate ; Demeton-S-metile ; Demetox ; Dimethyl S-(2-eththioethyl)thiophosphate ; EINECS 213-052-6 ; Ethanethiol, 2-(ethylthio)-, S-ester with O,O-dimethyl  Metaisosystox ; Methyl demeton thioester ; Methyl isosystox ; Methyl thionodemeton ; Methyl-mercaptofos teolovy (USSR) ; Methylmercaptofostiol (USSR) ; Mifatox ; O,O-Dimethyl 2-ethylmercaptoethyl thiophosphate, thiolo isomer ; O,O-Dimethyl S-(2-(ethylthio)ethyl)phosphorothioate ; O,O-Dimethyl-S-(2-aethylthio-aethyl)-monothiophosphat ; Phosphorothioic acid, O,O-dimethyl S-(2-(ethylthio)ethyl) ester ; S-(2-(Ethylthio)ethyl) O,O-dimethyl phosphorothioate ; S-(2-(Ethylthio)ethyl) O,O-dimethyl thiophosphate ; Thiometon oxon ; Thiophosphate de O,O-dimethyle et de S-2-ethylthio-ethyle .

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